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Chemistry – A European Journal, ISSN 0947-6539, 01/2009, Volume 15, Issue 4, pp. 1011 - 1017
Second‐order rate constants have been measured spectrophotometrically for the reactions of O‐p‐nitrophenyl thionobenzoate (1, PNPTB) with HO−, butan‐2,3‐dione... 
electrophilic addition | polarizability | kinetics | medium effect | enthalpy of solution | Enthalpy of solution | Kinetics | Polarizability | Medium effect | Electrophilic addition | GENERAL ACID CATALYSIS | GROUND-STATE | RATE-DETERMINING STEP | METHYL TRANSFERS | OXIMATE ALPHA-NUCLEOPHILES | CHEMISTRY, MULTIDISCIPLINARY | SOLVENT | ORIGIN | PHASE S(N)2 REACTIONS | PHOSPHORUS CENTERS | DIMETHYL-SULFOXIDE
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 05/2014, Volume 53, Issue 19, pp. 4968 - 4971
Donor‐substituted diarylcarbenium ions Ar2CH+ react with ynamides to give 1‐amido‐substituted allyl cations (α,β‐unsaturated iminium ions). Kinetic studies... 
vinyl cations | kinetics | iminium ions | kinetic isotope effects | linear free energy relationships | ACETYLENES | CARBOCATIONS | IONS | ALKYNES | CHEMISTRY, MULTIDISCIPLINARY | ORGANOBORANES | ALKENES | HYDRIDE SHIFTS | SCALES | ELECTROPHILIC ADDITIONS | FORMING REACTIONS
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 06/2016, Volume 55, Issue 27, pp. 7702 - 7707
The reduction of [Cp′′′Ni(η3‐P3)] (1; Cp′′′=η5‐1,2,4‐tBu3C5H2) with potassium produces the complex anion [(Cp′′′Ni)2(μ,η2:2‐P8)]2− (2), which contains a... 
nickel | electrophilic reactivity | triple decker complexes | phosphorus | reduction chemistry | ANIONS | COORDINATION CHEMISTRY | TRANSITION-METAL-COMPLEXES | FERROCENE | STABILIZATION | P-4 ACTIVATION | CHEMISTRY, MULTIDISCIPLINARY | LIGANDS | PENTAPHOSPHAFERROCENE | CYCLO-TRIPHOSPHORUS
Journal Article
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 07/2016, Volume 52, Issue 57, pp. 8877 - 8880
The Ph2P-stabilized borenium reacts cleanly with PhNH2, NH3 and HNTf2 to give a variety of boron compounds, namely the amino-substituted borenium (substitution... 
Journal Article
Journal Article