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Journal of the American Chemical Society, ISSN 0002-7863, 03/2014, Volume 136, Issue 12, pp. 4484 - 4487
The magnetic relaxation dynamics of low-coordinate DyIII and ErIII complexes, namely three-coordinate ones with an equatorially coordinated triangle geometry... 
ELECTRONIC-STRUCTURES | MAGNETIZATION | MOLECULE MAGNETS | EASY-AXIS | COMPLEXES | F ELEMENTS | HIGHLY-SYMMETRICAL COMPOUNDS | RELAXATION | BLOCKING | ANISOTROPY | CHEMISTRY, MULTIDISCIPLINARY | Rare earth metals | Research
Journal Article
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, ISSN 0002-7863, 08/2015, Volume 137, Issue 31, pp. 9855 - 9860
The recently reported series of divalent lanthanide complex salts, namely [K(2.2.2-cryptand)][Cp'(3)Ln] (Ln = Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er,... 
WELL | MOLECULE MAGNETS | NANOMAGNETS | ORGANOMETALLIC COMPLEXES | EXCHANGE | BLOCKING | ADDUCT | F-ELEMENTS | ANISOTROPY | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Intermetallics, ISSN 0966-9795, 05/2019, Volume 108, pp. 32 - 38
Binary intermetallic compounds containing f-block elements (LaNi , DyFe and SmCo ) were easily obtained via electrospinning and a two-step treatment where the... 
f elements | Nanoparticles | Methanation | Carbon dioxide | Electrospinning | Intermetallic
Journal Article
Polyhedron, ISSN 0277-5387, 02/2016, Volume 105, pp. 35 - 41
Optical, magnetic properties and the low-energy region of the electronic spectra in the and fluoride complexes embedded in have been analyzed. The effect of... 
f elements | Spin-orbit | Magnetic properties
Journal Article
Coordination Chemistry Reviews, ISSN 0010-8545, 01/2013, Volume 257, Issue 2, pp. 394 - 406
► Extensive experimental evidence exists for covalency in f-element complexes. ► 5f and 6d as well as pseudo-core 6s and 6p orbitals can contribute to bonding... 
Spectroscopy | Actinides | f-Elements | Covalency | F-Elements | RAY-ABSORPTION SPECTROSCOPY | TRIS(ETA-5-CYCLOPENTADIENYL) ACTINIDE COMPLEXES | HARTREE-FOCK | CHEMISTRY, INORGANIC & NUCLEAR | VIBRATIONAL FREQUENCIES | MOSSBAUER-SPECTROSCOPY | VARIABLE PHOTON-ENERGY | DENSITY-FUNCTIONAL THEORY | URANYL-ION | ELECTRONIC-STRUCTURE | PHOTOELECTRON-SPECTROSCOPY
Journal Article
Inorganica Chimica Acta, ISSN 0020-1693, 02/2018, Volume 471, pp. 104 - 112
We present an extended series of lanthanide 2-sulfonatoterephthalates, [Ln(TPSO )(H O) ] . Structural trends correlate well to ionic radii, indicating that no... 
F-elements | Hydrothermal synthesis | Metal organic frameworks | Lanthanide contraction
Journal Article
by Chen, MC and Li, LH and Chen, YB and Chen, L
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, ISSN 0002-7863, 03/2011, Volume 133, Issue 12, pp. 4617 - 4624
New noncentrosymmetric rare-earth metal gallium thioantimonates, Ln(4)GaSbS(9) were synthesized from stoichiometric element mixtures at 950 degrees C by... 
AUGMENTED-WAVE METHOD | PHYSICAL-PROPERTIES | SINGLE-CRYSTAL | STRONG 2ND-HARMONIC GENERATION | HIGHLY-SYMMETRICAL COMPOUNDS | TOTAL-ENERGY CALCULATIONS | ALPHA-PBO | BASIS-SET | F-ELEMENTS | CHEMISTRY, MULTIDISCIPLINARY | ELECTRONIC-STRUCTURE
Journal Article
Dalton Transactions, ISSN 1477-9226, 1/2015, Volume 44, Issue 6, pp. 2517 - 2528
Actinide single-molecule magnetism has experienced steady growth over the last five years since the first discovery of slow magnetic relaxation in the... 
ELECTRONIC-STRUCTURES | STRONG EXCHANGE | HIGHLY SYMMETRICAL COMPOUNDS | PARAMETRIC ANALYSIS | OXIDATION-STATE | RELAXATION | URANIUM(III) COMPLEX | BLOCKING | F-ELEMENTS | ION MAGNET | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Dalton transactions (Cambridge, England : 2003), ISSN 1477-9226, 02/2015, Volume 44, Issue 6, pp. 2517 - 2528
Actinide single-molecule magnetism has experienced steady growth over the last five years since the first discovery of slow magnetic relaxation in the... 
Journal Article
Chemical Society Reviews, ISSN 0306-0012, 2007, Volume 36, Issue 2, pp. 367 - 377
In nuclear waste treatment processes there is a need for improved ligands for the separation of actinides (An(III)) and lanthanides (Ln(III)). Several research... 
TRIVALENT F-ELEMENTS | SELECTIVE EXTRACTION | LANTHANIDES | DONOR LIGANDS | ACTINIDES | COBALT BIS(DICARBOLLIDE) IONS | NUCLEAR WASTE SOLUTIONS | EXTRACTION PROPERTIES | WIDE RIM | SOLVENT-EXTRACTION | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 12/2014, Volume 50, Issue 98, pp. 15513 - 15516
Four low-coordinate SIMs have been studied to probe their relaxation dynamics using ab initio calculations. Our calculations reveal that both the symmetry and... 
Journal Article
Chemical Communications, ISSN 1359-7345, 12/2014, Volume 50, Issue 98, pp. 15513 - 15516
Four low-coordinate SIMs have been studied to probe their relaxation dynamics using ab initio calculations. Our calculations reveal that both the symmetry and... 
ELECTRONIC-STRUCTURES | FIELD | MOLECULE MAGNETS | SLOW RELAXATION | F ELEMENTS | CHEMISTRY | HIGHLY-SYMMETRICAL COMPOUNDS | URANIUM(III) COMPLEX | BLOCKING | ANISOTROPY BARRIER | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Chemical Communications, ISSN 1359-7345, 2018, Volume 54, Issue 75, pp. 10578 - 10581
Literature casts einsteinium as a departure from earlier transplutonium actinides, with a decrease in stability constants with aminopolycarboxylate ligands.... 
PLUTONIUM(III) | SEPARATIONS | DTPA | LIGANDS | KINETICS | ACETIC ACID | ACTINIDES | COVALENCY | DISSOCIATION-CONSTANTS | F-ELEMENTS | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Dalton transactions, ISSN 1477-9226, 2017, Volume 46, Issue 5, pp. 1431 - 1438
Three benzene-centered tripodal diglycolamides (Bz-T-DGAs) were synthesized and evaluated for actinide, lanthanide, and fission product ion extraction.... 
Inorganic Chemistry | DENSITY | PROMISING EXTRACTANTS | ATOMS LI | LIGANDS | ZETA VALENCE QUALITY | SOLVENT-EXTRACTION | F-ELEMENTS | COMPLEXATION | GAUSSIAN-BASIS SETS | NITRIC-ACID | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Physical Chemistry Chemical Physics, ISSN 1463-9076, 10/2013, Volume 15, Issue 39, pp. 16533 - 16541
The ionic liquids 1-hexyl-3-methylimidazolium bis(2-ethylhexyl)phosphate, [C(6)mim][DEHP], 1-hexyl-1methylpyrrolidinium bis(2-ethylhexyl)phosphate,... 
PHOSPHONIUM | RARE-EARTH IONS | DILUENTS | LANTHANIDES | PERMANENT-MAGNETS | BEHAVIOR | PHYSICS, ATOMIC, MOLECULAR & CHEMICAL | CHEMISTRY, PHYSICAL | SEPARATION | METAL-IONS | SOLVENT-EXTRACTION | F-ELEMENTS | Liquid-liquid extraction | Stripping | Rare earth metals | Ionic liquids | Nitrates | Cations | NMR spectroscopy
Journal Article
Inorganica Chimica Acta, ISSN 0020-1693, 10/2017, Volume 467, pp. 276 - 286
We present an extended series of lanthanide 2-nitroterephthalates, [Ln (TPNO ) (H O) ]·2H O. The correlation between structural trends and ionic radii... 
Hydrothermal synthesis | f-Elements | Metal organic frameworks | Thermogravimetric analysis | Lanthanide contraction
Journal Article
Dalton Transactions, ISSN 1477-9226, 11/2012, Volume 41, Issue 44, pp. 13572 - 13574
Lanthanide- and actinide-based single-molecule magnets are rapidly gaining prominence due to the unique properties of f-orbitals, yet no direct comparison of... 
ELECTRONIC-STRUCTURES | TETRANUCLEAR | SINGLE-MOLECULE-MAGNET | HIGHLY SYMMETRICAL COMPOUNDS | DYSPROSIUM(III) | PARAMETRIC ANALYSIS | CRYSTAL | EXCHANGE | F-ELEMENTS | CHEMISTRY, INORGANIC & NUCLEAR | Dynamic tests | Actinides | Magnetic relaxation | Dynamics | Congeners | Displays | Magnets | Magnetic properties
Journal Article
ORGANOMETALLICS, ISSN 0276-7333, 08/2019, Volume 38, Issue 16, pp. 3124 - 3131
Magnetic circular dichroism (MCD) spectroscopy has been utilized to evaluate the electronic structure of the tris(cyclopentadienyl) rare-earth complexes... 
MOLECULAR-COMPLEXES | RARE-EARTH | OXIDATION-STATE | ORGANOMETALLIC COMPLEXES | CHEMISTRY, ORGANIC | LIGAND | DENSITY-FUNCTIONAL THEORY | SPECTRA | F-ELEMENTS | LANTHANUM | ACTINYL IONS | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
INORGANIC CHEMISTRY, ISSN 0020-1669, 07/2017, Volume 56, Issue 14, pp. 7861 - 7869
Previous studies have identified the TPAEN ligand as a potentially appropriate complexing agent in solvent extraction processes for the separation of americium... 
SYNERGISTIC MIXTURE | COORDINATION MODES | CM(III) | THERMODYNAMICS | STRUCTURAL ASPECTS | EU(III) | PUREX RAFFINATE | SOLVENT-EXTRACTION | F-ELEMENTS | DEGREES-C | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
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