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fluoromethylation (34) 34
fluorine (14) 14
chemistry, multidisciplinary (12) 12
chemistry, organic (10) 10
trifluoromethylation (10) 10
index medicus (9) 9
monofluoromethylation (8) 8
fluorination (7) 7
chemistry, inorganic & nuclear (6) 6
fluorinated sulfones (5) 5
organic chemistry (5) 5
alcohols (4) 4
catalysis (4) 4
chemistry, medicinal (4) 4
difluoromethylation (4) 4
difunctionalization (4) 4
esters (4) 4
fluoroalkylation (4) 4
organofluorine compounds (4) 4
palladium (4) 4
pet (4) 4
synthesis (4) 4
[18f]fluoromethyl tosylate (3) 3
[f-18]fluoromethylation (3) 3
alkylation (3) 3
alpha,beta-unsaturated aldehydes (3) 3
biochemical research methods (3) 3
carbanions (3) 3
chemistry, analytical (3) 3
fluorine-18 (3) 3
fluorobismethane (3) 3
fluoroiodomethane (3) 3
intermediates (3) 3
medicinal chemistry (3) 3
molecular structure (3) 3
nucleophilic fluoroalkylation (3) 3
photoredox catalysis (3) 3
selective inhibitors (3) 3
synthetic methods (3) 3
1,2-migration (2) 2
[f-18]fluoromethyl tosylate (2) 2
acids (2) 2
agrochemicals (2) 2
alkenes (2) 2
allylic monofluoromethylation (2) 2
anions (2) 2
aromatic compounds (2) 2
aromatic-compounds (2) 2
aryl boronic acids (2) 2
asymmetric synthesis (2) 2
automated synthesis (2) 2
benzenesulfonates - chemical synthesis (2) 2
biological properties (2) 2
bonds (2) 2
boronic esters (2) 2
c-alkylation (2) 2
catalysts (2) 2
chemistry (2) 2
chemistry, physical (2) 2
chloromethylation (2) 2
conjugate addition (2) 2
convenient synthesis (2) 2
crystal structure (2) 2
crystallography, x-ray (2) 2
desulfonylation (2) 2
efficient synthesis (2) 2
electronegativity (2) 2
enolates (2) 2
f-18 (2) 2
f]fluoromethylation (2) 2
fluorine effect (2) 2
fluorine radioisotopes - chemistry (2) 2
fluoroalkylation reactions (2) 2
fluorocarbanions (2) 2
fluorometers (2) 2
formalin (2) 2
functional-group (2) 2
functionalisation (2) 2
functionalization (2) 2
funktionalisierung (2) 2
funktionelle gruppe (2) 2
ibuprofen (2) 2
katalyse (2) 2
kinetics (2) 2
linear free energy relationship (2) 2
mannich reaction (2) 2
multicomponent reactions (2) 2
nmr spectroscopy (2) 2
nucleophilic addition (2) 2
nucleophilicity (2) 2
o-alkylation (2) 2
olefins (2) 2
palladium catalysis (2) 2
pharmacology & pharmacy (2) 2
pronucleophiles (2) 2
radical reactions (2) 2
reagent (2) 2
reagents (2) 2
regioselectivity (2) 2
stability (2) 2
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Organic Letters, ISSN 1523-7060, 01/2019, Volume 21, Issue 2, pp. 584 - 588
An expeditious, high-yielding synthesis of rare alpha-fluoroepoxides and alpha-fluoroaziridines through the addition of the unkown fluoroiodomethyllithium... 
CARBENOIDS | STABILITY | FLUOROALKYLATION | EFFICIENT SYNTHESIS | CHEMISTRY, ORGANIC | FLUORINE | MONOFLUOROMETHYLATION | NUCLEOPHILIC FLUOROMETHYLATION | HOMOLOGATION | STRAIGHTFORWARD ACCESS | EPOXIDATION
Journal Article
by Huang, YB and Hong, HL and Zou, ZR and Liao, CS and Lu, JJ and Qin, YW and Li, YB and Chen, L
ORGANIC & BIOMOLECULAR CHEMISTRY, ISSN 1477-0520, 05/2019, Volume 17, Issue 20, pp. 5014 - 5020
A novel vicinal aminotrifluoromethylation of alkenes using CF3SO2Na as a trifluoromethyl precursor and acetonitrile as an N-nucleophile has been achieved by an... 
DIFUNCTIONALIZATION | REAGENT | STYRENES | FLUOROMETHYLATION | HYDROTRIFLUOROMETHYLATION | CATALYZED TRIFLUOROMETHYLATION | CHEMISTRY, ORGANIC | CF3SO2NA | OLEFINS | OXIDATIVE TRIFLUOROMETHYLATION | UNACTIVATED ALKENES
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 03/2017, Volume 23, Issue 14, pp. 3285 - 3290
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 03/2011, Volume 50, Issue 11, pp. 2588 - 2592
The tighter, the better! Fluorobis(phenylsulfonyl)methane reacts readily with aldehydes to give addition products in excellent yields (see scheme;... 
aldehydes | fluoromethylation | sulfones | nucleophilic addition | fluorine | ALPHA,BETA-UNSATURATED ALDEHYDES | FLUOROALKYLATION | CARBANIONS | ALKYNES | CHEMISTRY, MULTIDISCIPLINARY | ALCOHOLS | MONOFLUOROMETHYLATION | CONJUGATE ADDITION
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 07/2015, Volume 54, Issue 31, pp. 9079 - 9083
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 08/2019, Volume 25, Issue 44, pp. 10323 - 10327
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 10/2016, Volume 55, Issue 41, pp. 12845 - 12849
α‐Fluorocarbanions are key intermediates in nucleophilic fluoroalkylation reactions. Although frequently discussed, the origin of the fluorine effect on the... 
nucleophilicity | fluorine effect | fluoromethylation | carbanions | linear free energy relationship | Materials Chemistry | Theoretical Chemistry | Materialkemi | Oorganisk kemi | Inorganic Chemistry | Teoretisk kemi
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 01/2014, Volume 53, Issue 3, pp. 775 - 779
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 03/2013, Volume 19, Issue 11, pp. 3579 - 3583
No imines! A direct multicomponent protocol for the synthesis of highly diverse derivatives of β‐fluoro(phenylsulfonyl)ethylamine has been developed (see... 
multicomponent reactions | fluoromethylation | formalin | Mannich reaction | pronucleophiles | synthetic methods | desulfonylation | Amines - chemistry | Models, Molecular | Crystallography, X-Ray | Hydrocarbons, Fluorinated - chemistry | Molecular Structure | Ethylamines - chemistry | Aldehydes - chemistry
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 2009, Volume 50, Issue 52, pp. 7252 - 7255
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 05/2020, Volume 59, Issue 22, pp. 8502 - 8506
There is considerable interest in incorporating fluorine into agrochemicals and pharmaceuticals to improve their biological properties. Whilst a number of... 
fluoromethylation | stereospecificity | 1,2-migration | boronic esters | fluorocarbanions | Biological properties | Esters | Agrochemicals | Fluorine | Intermediates
Journal Article
ORGANIC LETTERS, ISSN 1523-7060, 02/2020, Volume 22, Issue 4, pp. 1345 - 1349
The commercially available fluoroiodomethane represents a valuable and effective electrophilic source for transferring the CH2F unit to a series of... 
ALCOHOLS | FLUOROMETHYLATION | PHARMACEUTICALS | METHYL | ARENES | ESTERS | CHEMISTRY | CHEMISTRY, ORGANIC | FLUORINE | ARYL
Journal Article