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ACS Catalysis, ISSN 2155-5435, 11/2017, Volume 7, Issue 11, pp. 7748 - 7752
Herein we report the metal-free diastereoselective frustrated Lewis pair (FLP)-catalyzed hydrogenation of aza-Morita–Baylis–Hillman (aza-MBH... 
metal-free hydrogenation | stereoselective | sequential catalysis | amino esters | frustrated Lewis pairs | ACTIVATION | DIHYDROGEN | SCOPE | CARBONYL | CHEMISTRY | CHEMISTRY, PHYSICAL | ALDEHYDES
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 03/2017, Volume 56, Issue 11, pp. 3094 - 3097
An Al/P‐based frustrated Lewis pair (FLP) reacted with PhMgCl by an unexpected transmetalation and formation of a phosphinylvinyl Grignard reagent... 
gold | indium | density functional calculations | gallium | frustrated Lewis pairs | Chemical tests and reagents | Atomic properties | Chelation | Gallium
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 05/2016, Volume 22, Issue 22, pp. 7422 - 7426
The autoinduced, frustrated Lewis pair (FLP)‐catalyzed hydrogenation of 16‐benzene‐ring substituted N‐benzylidene‐tert‐butylamines with B(2,6‐F2C6H3)3 and molecular hydrogen was investigated by kinetic analysis... 
imines | Hammett correlation | autoinduced catalysis | hydrogenation | frustrated Lewis pairs | ACIDITY SCALE | ACTIVATION | SUBSTITUENT CONSTANTS | CHEMISTRY, MULTIDISCIPLINARY | SCHIFF-BASES | ENANTIOSELECTIVE HYDROGENATION | GAS-PHASE | METAL-FREE HYDROGENATION | ASYMMETRIC HYDROGENATION | COSMO-RS | ACETONITRILE | Schiff bases | Catalysis | Hydrogen | Hydrogenation | Analysis | Kinetics | Protein kinase A | Hydrogen storage | Correlation | Amines | Rate constants | Molecular structure | Imines | Benzene | Catalysts
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 11/2018, Volume 24, Issue 62, pp. 16526 - 16531
For the first time have boron‐containing weak Lewis acids been demonstrated to be active components of Frustrated Lewis Pair (FLP... 
catalytic hydrogenation | hydrogen cleavage | frustrated Lewis Pair | ketones | metal-free | ACTIVATION | HYDROCARBONS | MECHANISM | CARBONYL-COMPOUNDS | ALDEHYDES | CHEMISTRY, MULTIDISCIPLINARY | HYDRIDE | DIHYDROGEN | ABILITIES | ASYMMETRIC HYDROGENATION | LIGAND | Ketones | Hydrogen | Hydrogenation
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 09/2018, Volume 57, Issue 38, pp. 12356 - 12359
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 05/2016, Volume 22, Issue 22, pp. 7302 - 7302
What makes an FLP a good catalyst? Thus far, a number of frustrated Lewis pairs (FLPs) are reported in the literature, but not all of them activate molecular hydrogen... 
imines | Hammett correlation | autoinduced catalysis | hydrogenation | frustrated Lewis pairs | Hydrogenation | Hydrogen storage | Molecular structure | Imines | Catalysts | Hydrogen | Paper | Catalysis | Lewis base
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 05/2019, Volume 58, Issue 20, pp. 6737 - 6741
... with the (Fmes)BH2 reagent gives the (μ‐H)2‐bridged frustrated P/BH Lewis pair. It reduces carbon monoxide to the formyl stage and carbon dioxide to the formaldehyde... 
CO reduction | carbon monoxide | carbon dioxide reduction | borane | frustrated Lewis pairs | ACTIVATION | HYDROBORATION | HYDROGENATION | CO2 | H-2 | CHEMISTRY, MULTIDISCIPLINARY | ORGANOBORANES | FRUSTRATED LEWIS PAIR | CHEMISTRY | METAL-FREE | BIS(PENTAFLUOROPHENYL)BORANE | Carbon monoxide | Chemical tests and reagents | Formaldehyde | Carbon dioxide | Valence | Benzene | Reagents | X-ray diffraction | Oxidation | Dimers
Journal Article
Dalton Transactions, ISSN 1477-9226, 2016, Volume 45, Issue 39, pp. 15303 - 15316
The carbene derived from (1R, 3S)-camphoric acid was used to prepare the borane adduct with Piers' borane 7. Subsequent hydride abstraction gave the borenium... 
TEMPERATURE | REDUCTION | ONE-POT SYNTHESIS | DIHYDROGEN ACTIVATION | IMINES | COMPLEXES | REACTIVITY | FRUSTRATED LEWIS PAIRS | ALKYNES | CATIONS | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Dalton transactions : an international journal of inorganic chemistry, ISSN 1477-9226, 04/2016, Volume 45, Issue 14, pp. 6124 - 6128
FLP-catalyzed hydrogenations of 15 substrates were compared using microwave irradiation and conventional heating... 
Journal Article
Dalton Transactions, ISSN 1477-9226, 3/2016, Volume 45, Issue 14, pp. 6124 - 6128
Journal Article
Zeitschrift für Kristallographie - Crystalline Materials, ISSN 2194-4946, 09/2018, Volume 233, Issue 9, pp. 723 - 731
The charge density distribution of the intramolecular frustrated Lewis pair (FLP) Mes PCH CH B(C ( ), the phosphinimine HNPMes CH CH B... 
experimental charge-density | frustrated Lewis pairs | FRUSTRATED LEWIS PAIR | DATIVE BONDS | COMPLEX | METAL-METAL | HYDROGEN ACTIVATION | CRYSTALLOGRAPHY | MAIN-GROUP COMPOUNDS | BORANE | ELECTRON-DENSITY | ARROWS
Journal Article
by Huo, Y and Xu, Y and Wang, ZH
Chemistry Letters, ISSN 0366-7022, 11/2017, Volume 46, Issue 11, pp. 1664 - 1667
Journal Article
Dalton transactions : an international journal of inorganic chemistry, ISSN 1477-9226, 2016, Volume 45, Issue 14, pp. 6129 - 6135
...)(1) was prepared and crystallized as a monomeric Frustrated Lewis Pair (FLP) displaying no apparent B–N interaction... 
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 05/2019, Volume 58, Issue 22, pp. 7420 - 7424
Journal Article
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, ISSN 1433-7851, 03/2017, Volume 56, Issue 11, pp. 3094 - 3097
An Al/P-based frustrated Lewis pair (FLP) reacted with PhMgCl by an unexpected transmetalation and formation of a phosphinylvinyl Grignard reagent... 
CATALYSIS | FREE HYDROGEN ACTIVATION | COMPLEXES | indium | CARBONYL-COMPOUNDS | COORDINATION | POLYMERIZATION | gallium | BORANE | CHEMISTRY, MULTIDISCIPLINARY | gold | density functional calculations | LIGAND | frustrated Lewis pairs
Journal Article