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hexacarbonyldicobalt (16) 16
chemistry, inorganic & nuclear (10) 10
chemistry, organic (7) 7
chemistry (4) 4
molecular-structures (4) 4
reactivity (4) 4
alkinyl (3) 3
alkyne complexes (3) 3
carbosiloxane (3) 3
cobalt (3) 3
coordination ability (3) 3
dendrimer (3) 3
linear carbosiloxane dendrimers (3) 3
pauson-khand reaction (3) 3
propargyloxy (3) 3
propargyloxy unit (3) 3
1-allenylcyclopropanol (2) 2
2-cyclopenten-1-one (2) 2
acetylene (2) 2
alkyne-hexacarbonyldicobalt complex (2) 2
alkynes (2) 2
alkynylphosphanes (2) 2
cations (2) 2
clusters (2) 2
cobalt complexes (2) 2
complexes (2) 2
coordination (2) 2
crystal (2) 2
crystal-structure (2) 2
derivatives (2) 2
fluoride (2) 2
general-route (2) 2
hydroquinone (2) 2
ligands (2) 2
octacarbonyldicobalt (2) 2
organometallic compounds (2) 2
osmium (2) 2
ray crystal-structure (2) 2
ruthenium (2) 2
silane dendrimers (2) 2
substitution (2) 2
thermolysis (2) 2
1,6-diazacyclodeca-3,8-diynes (1) 1
1- [o- phenyl] cyclopropanol (1) 1
1- cyclopropanol (1) 1
1- o-phenyl cyclopropanol (1) 1
1-[o-phenyl]cyclopropanol (1) 1
1-alkynylcyclopropanol (1) 1
1-cyclopropanol (1) 1
1-cyclopropanols (1) 1
2,5,8-trithia -ortho-benzenophane tt ob (1) 1
7-membered rings (1) 1
co2 (1) 1
acetylenes held proximate (1) 1
alcohols (1) 1
alkene complexes (1) 1
alkyne-alkyne interactions (1) 1
annulating reagents (1) 1
behavior (1) 1
bis complexes (1) 1
carbon allotropes (1) 1
carbon-monoxide (1) 1
carbonyl clusters (1) 1
carbonyl-complexes (1) 1
carboxylic acids (1) 1
carboxylic acids - chemistry (1) 1
chalcogen centers (1) 1
chalcogens (1) 1
chemical properties (1) 1
chemistry, multidisciplinary (1) 1
chemistry, technical (1) 1
cis-phosphinoacetylene complexes (1) 1
cleavage (1) 1
co-2 (1) 1
cobalt centers (1) 1
conformation (1) 1
conjugated pyridines (1) 1
crown thioether ligands (1) 1
crystal structures (1) 1
crystal-structures (1) 1
cyclic diynes (1) 1
cyclization (1) 1
cyclopentenones (1) 1
cyclotrimerization (1) 1
dimers (1) 1
dinuclear complexes (1) 1
diphosphine complexes (1) 1
electron-spin-resonance (1) 1
flash vacuum thermolysis (1) 1
heterocyclic diynes (1) 1
hydrocarbon-bridged complexes (1) 1
hydrogen - chemistry (1) 1
intramolecular nicholas (1) 1
khand reaction (1) 1
lactones (1) 1
lactones - chemistry (1) 1
metal complexes (1) 1
metal fullerene complexes (1) 1
molecular structure (1) 1
mu-diphenylethyne-hexacarbonyldicobalt (1) 1
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Journal of Organometallic Chemistry, ISSN 0022-328X, 2007, Volume 692, Issue 24, pp. 5474 - 5480
The bifunctional nature of Ph 2PC CPh has been exploited to prepare the fluoride-containing heterometallic clusters [MF 2(CO) 2(μ-η 1:η 2-PPh 2CCPh) 2{Co 2(CO)... 
Alkynylphosphanes | Ruthenium | Fluoride | Hexacarbonyldicobalt | Osmium | Thermolysis
Journal Article
Angewandte Chemie International Edition in English, ISSN 0570-0833, 09/1992, Volume 31, Issue 9, pp. 1101 - 1123
Life on earth is based on compounds that have carbon frames and backbones. Today, chemists have added to the world of biomolecules and biopolymers... 
Carbon allotropes | PLANAR PI-SYSTEMS | ORGANIC-CHEMISTRY | POLYCARBON SUPERCAGE CHEMISTRY | NUCLEAR-MAGNETIC-RESONANCE | CHEMISTRY | FLASH VACUUM THERMOLYSIS | PUSH-PULL-OLIGOACETYLENES | HYDROCARBON-BRIDGED COMPLEXES | METAL FULLERENE COMPLEXES | MU-DIPHENYLETHYNE-HEXACARBONYLDICOBALT | RAY CRYSTAL-STRUCTURE
Journal Article
Journal of Organometallic Chemistry, ISSN 0022-328X, 11/2007, Volume 692, Issue 24, pp. 5474 - 5480
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 10/2005, Volume 70, Issue 22, pp. 9088 - 9091
Journal Article
European Journal of Inorganic Chemistry, ISSN 1434-1948, 06/2004, Volume 2004, Issue 12, pp. 2585 - 2593
The bis(hexacarbonyldicobalt) complexes of cyclic diynes with sila‐, thia‐ and selena‐substituted acetylene units have been isolated. The structural features... 
Chalcogens | Pauson−Khand reaction | Cobalt | Alkynes | CHALCOGEN CENTERS | CRYSTAL-STRUCTURE | alkynes | CYCLIC DIYNES | cobalt | CHEMISTRY, INORGANIC & NUCLEAR | Pauson-Khand reaction | CARBONYL-COMPLEXES | ALKYNE COMPLEXES | GENERAL-ROUTE | HEXACARBONYLDICOBALT | COBALT COMPLEXES | MOLECULAR-STRUCTURES | SUPERCRITICAL ETHYLENE | chalcogens
Journal Article
Journal of Organometallic Chemistry, ISSN 0022-328X, 12/1999, Volume 592, Issue 1, pp. 147 - 152
The preparation of the first-generation dendrimers Si(OCH CH CH SiMe OCH C≡CH) (5) as well as Si(OCH CH -CH SiMe C≡CSiMe ) (7) from Si(OCH CH CH SiMe Cl) (4)... 
Propargyloxy | Hexacarbonyldicobalt | Alkinyl | Linear carbosiloxane dendrimers
Journal Article
Journal of Organometallic Chemistry, ISSN 0022-328X, 1999, Volume 592, Issue 1, pp. 147 - 152
The preparation of the first-generation dendrimers Si(OCH 2CH 2CH 2SiMe 2OCH 2CCH) 4 ( 5) as well as Si(OCH 2CH 2CH 2SiMe 2CCSiMe 3) 4 ( 7) from Si(OCH 2CH... 
Propargyloxy | Hexacarbonyldicobalt | Alkinyl | Linear carbosiloxane dendrimers
Journal Article
Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences, ISSN 0932-0776, 06/1999, Volume 54, Issue 6, pp. 751 - 756
Journal Article
Zeitschrift für Naturforschung B, ISSN 0932-0776, 06/1999, Volume 54, Issue 6, pp. 751 - 756
The preparation of the first and second generation carbosiloxane dendrimers Si[OCH - CH CH SiMe(OCH C=CH) (3) and Si{OCH CH SiMe[OCH CH CH SiMe(OCH - C=CH) (5)... 
Propargyloxy Unit | Dendrimer | Carbosiloxane | Hexacarbonyldicobalt | Coordination Ability
Journal Article
Journal of Organometallic Chemistry, ISSN 0022-328X, 1998, Volume 564, Issue 1, pp. 257 - 266
The alkyne entity in 4,4′-dipyridylbutadiyne (DPB), 1,4-bis(4′-pyridylethynyl)benzene (BPEB), (4-aminophenyl)-4′-pyridylacetylene (APPA),... 
Polynuclear | Metal complexes | Conjugated pyridines | metal complexes | ORGANOMETALLIC COMPOUNDS | CRYSTAL-STRUCTURE | BEHAVIOR | REACTIVITY | CHEMISTRY, ORGANIC | DIMERS | CHEMISTRY, INORGANIC & NUCLEAR | HEXACARBONYLDICOBALT | REDUCTION | CLUSTERS | polynuclear | conjugated pyridines | MULTIPLE BONDS | COBALT
Journal Article
Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry, ISSN 0037-9980, 1998, Volume 56, Issue 12, pp. 1058 - 1068
Journal Article
有機合成化学協会誌, ISSN 0037-9980, 1998, Volume 56, Issue 12, pp. 1058 - 1068
A novel rearrangement of 1- (1-alkynyl) cyclopropanols to 2-cyclopenten-1-ones proceeded on complexation of their alkynyl part with Co2 (CO) 8. In the case of... 
Hydroquinone | 1- (1-Alkynyl) cyclopropanol | 1-Allenylcyclopropanol | Alkyne-Hexacarbonyldicobalt complex | 1- [o- (1-Alkynyl) phenyl] cyclopropanol | Octacarbonyldicobalt | 2-Cyclopenten-1-one
Journal Article
JOURNAL OF ORGANOMETALLIC CHEMISTRY, ISSN 0022-328X, 06/2000, Volume 605, Issue 1, pp. 7 - 14
Photolysis of Co-2(CO)(6)(alkyne), where alkyne = H2C2 (I), (C2H5)(2)C-2 (II) (C6H5)(2)C-2 (III) and C6H5C2H (IV) in frozen Nujol at ca. 90 K results in loss... 
ALKYNE COMPLEXES | KHAND REACTION | CO-2(CO)(RCR') | LIGANDS | HEXACARBONYLDICOBALT | CHEMISTRY, ORGANIC | CRYSTAL | photochemical studies | CYCLOTRIMERIZATION | acetylene | phosphine derivatives | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
JOURNAL OF ORGANOMETALLIC CHEMISTRY, ISSN 0022-328X, 12/1999, Volume 592, Issue 1, pp. 147 - 152
The preparation of the first-generation dendrimers Si(OCH2CH2CH2SiMe2OCH2C=CH)(4) (5) as well as Si(OCH2CH2- CH2SiMe2C=CSiMe3)(4) (7) from... 
hexacarbonyldicobalt | propargyloxy | alkinyl | SILANE DENDRIMERS | COMPLEXES | linear carbosiloxane dendrimers | REACTIVITY | CHEMISTRY | CHEMISTRY, ORGANIC | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Journal of the Chemical Society, Dalton Transactions, ISSN 1470-479X, 2002, Issue 10, pp. 2219 - 2226
The bis(hexacarbonyldicobalt) complexes of nine ten- to fourteen-membered cyclic diynes (1-3, 5, 6, 8 and 10-12) have been isolated. The structural parameters... 
PAUSON-KHAND REACTION | ALKYNE COMPLEXES | GENERAL-ROUTE | HEXACARBONYLDICOBALT | 1,6-DIAZACYCLODECA-3,8-DIYNES | MOLECULAR-STRUCTURES | REGIOCHEMISTRY | DERIVATIVES | HETEROCYCLIC DIYNES | COBALT | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, ISSN 0932-0776, 06/1999, Volume 54, Issue 6, pp. 751 - 756
The preparation of the first and second generation carbosiloxane dendrimers Si[OCH2CH2CH2SiMe(OCH2C drop CH)(2)](4) (3) and... 
hexacarbonyldicobalt | SILANE DENDRIMERS | dendrimer | propargyloxy unit | COMPLEXES | REACTIVITY | CHEMISTRY, ORGANIC | COORDINATION | carbosiloxane | coordination ability | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, ISSN 0300-9246, 09/1993, Issue 18, pp. 2765 - 2773
The reactions of bis(2-mercaptoethyl) sulfide or bis(2-mercaptoethyl) ether with (Co2(mu-HOCH2C= CCH2OH)(CO)6] in the presence of HBF4.OEt2 afford... 
HEXACARBONYLDICOBALT | CROWN THIOETHER LIGANDS | 2,5,8-TRITHIA -ORTHO-BENZENOPHANE TT OB | SILVER(I) COMPLEXES | COORDINATION | CONFORMATION | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, ISSN 0300-9246, 02/1992, Issue 4, pp. 655 - 662
The complexes [Co2(CO)2(mu-RC2R)(mu-dppm)2] 1 (R = Me, Ph or CO2Me; dppm = Ph2PCH2PPh2) undergo reversible one-electron oxidation at a platinum-bead electrode... 
SUBSTITUTION | ELECTRON-SPIN-RESONANCE | R2C2CO2(CO)6 | POLYDENTATE LIGANDS | CLUSTERS | HEXACARBONYLDICOBALT | PARAMAGNETIC ORGANOMETALLIC MOLECULES | CO2(CO)6 | CRYSTAL | CLEAVAGE | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
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