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1. Full Text Silver‐Catalyzed Oxidative C(sp3)−P Bond Formation through C−C and P−H Bond Cleavage
by Li, Lili and Huang, Wenbin and Chen, Lijin and Dong, Jiaxing and Ma, Xuebing and Peng, Yungui
Angewandte Chemie International Edition, ISSN 1433-7851, 08/2017, Volume 56, Issue 35, pp. 10539 - 10544
The silver‐catalyzed oxidative C(sp3)−H/P−H cross‐coupling of 1,3‐dicarbonyl compounds with H‐phosphonates, followed by a chemo‐ and regioselective... 
cross-coupling | silver | C(sp3)−P bond formation | 1,3-dicarbonyl compounds | C−C bond cleavage | P bond formation | C(sp | HYDROGEN EVOLUTION REACTION | MANGANESE OXIDE CATALYSTS | C(sp) | WATER OXIDATION | C-C bond cleavage | CHEMISTRY, MULTIDISCIPLINARY | ELECTROCATALYSTS | OXYGEN REDUCTION REACTIONS | IRON-SULFUR CLUSTERS | NICKEL | SITES | 2FE-2S CLUSTERS | COBALT | Chemotherapy | Phosphonates | Cancer | Carbon-carbon composites | Coupling (molecular) | Silver | Cross coupling | Cleavage | Selectivity
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2. Full Text Synthesis of Oxindoles by Iron‐Catalyzed Oxidative 1,2‐Alkylarylation of Activated Alkenes with an Aryl C(sp2)H Bond and a C(sp3)H Bond Adjacent to a Heteroatom
by Wei, Wen‐Ting and Zhou, Ming‐Bo and Fan, Jian‐Hong and Liu, Wei and Song, Ren‐Jie and Liu, Yu and Hu, Ming and Xie, Peng and Li, Jin‐Heng
Angewandte Chemie International Edition, ISSN 1433-7851, 03/2013, Volume 52, Issue 13, pp. 3638 - 3641
Difunctionalization: Inexpensive and environmentally benign FeCl3 catalyzes the oxidative 1,2‐alkylarylation of activated alkenes with an aryl C(sp2)H bond... 
oxindoles | ethers | difunctionalization | iron | alkenes | ROOM-TEMPERATURE | CARBENE LIGANDS | ALPHA-ARYLATION | EFFICIENT SYNTHESIS | HECK REACTIONS | FORMING PROCESS | CHEMISTRY, MULTIDISCIPLINARY | C-H BONDS | ASYMMETRIC INTRAMOLECULAR ARYLATION | RADICAL CYCLIZATION | INDOLE ALKALOIDS | Alkenes - chemistry | Quantum Theory | Oxidation-Reduction | Iron - chemistry | Indoles - chemical synthesis | Ethers - chemistry | Catalysis | Kinetics | Hydrogen - chemistry | Indoles - chemistry | Carbon - chemistry | Activated | Synthesis | Alkenes | Oxidants | Aromatic compounds | Strategy | Ligands | Bonding
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3. The chemical bond in inorganic chemistry
: the bond valence model
by Brown, I. David (Ian David)
2002, International Union of Crystallography monographs on crystallography, ISBN 9780198508700, Volume 12, x, 278
The bond valence model, which is derived from the ionic model, is expressed through a number of rules and equations that determines which acid-base bond... 
Chemical bonds | Mathematical models | Inorganic compounds | crystallography | Chemistry, Inorganic | Acid-base bond | Bond valence model | Inorganic structure | Coordination number | Bond valence sum | Steric strain | Structure prediction | Electronic anisotropy | Hydrogen bond
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4. The nature of the hydrogen bond
: outline of a comprehensive hydrogen bond theory
by Gilli, Gastone and Gilli, Paola
2009, IUCr monographs on crystallography, ISBN 9780199558964, Volume 23, xi, 317
Hydrogen bond (H-bond) effects are well known: it makes sea water liquid, joins cellulose microfibrils in sequoia trees, shapes DNA into chromosomes, and... 
Hydrogen bonding | crystallography | Transition-state h-bond theory | H-bond puzzle | Equalization principle | Structural databases | Functional h-bonds | Charge-assisted h-bond | Thermodynamic databases | Electrostatic-covalent h-bond model | Resonance-assisted h-bond | Chemical leitmotifs
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5. Full Text Amide bond formation via C(sp3)-H bond functionalization and CO insertion
by Liu, Huizhen and Laurenczy, Gabor and Yan, Ning and Dyson, Paul J
Chemical Communications, ISSN 1359-7345, 01/2014, Volume 50, Issue 3, pp. 341 - 343
An efficient method for the synthesis of amides via Pd-catalyzed oxidative carbonylation of C(sp(3))-H bonds with CO and amines is described. The route... 
PEPTIDES | CATALYZED OXIDATIVE CARBONYLATION | ACIDS | ARYL HALIDES | ANILINE | AMIDATION | H BONDS | AMINOCARBONYLATION | CHEMISTRY, MULTIDISCIPLINARY | Quantum Theory | Oxidation-Reduction | Amides - chemical synthesis | Hydrogen | Ketones - chemistry | Amides - chemistry | Aniline Compounds - chemistry | Catalysis | Alkanes - chemistry | Palladium - chemistry | Carbon - chemistry | Alkanes
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6. Full Text Metal‐Free Oxidative CC Bond Formation through CH Bond Functionalization
by Narayan, Rishikesh and Matcha, Kiran and Antonchick, Andrey P
Chemistry – A European Journal, ISSN 0947-6539, 10/2015, Volume 21, Issue 42, pp. 14678 - 14693
The formation of CC bonds embodies the core of organic chemistry because of its fundamental application in generation of molecular diversity and complexity.... 
hypervalent iodine | oxidative coupling | CH activation | metal‐free | CC coupling | C-C coupling | C-H activation | metal-free | ORGANIC-SYNTHESIS | N-ARYL ENAMINES | TERTIARY-AMINES | NUCLEOPHILIC-SUBSTITUTION | CATALYTIC AMOUNTS | CARBON-HYDROGEN BONDS | PHENYLIODINE(III) BIS(TRIFLUOROACETATE) | CHEMISTRY, MULTIDISCIPLINARY | AEROBIC CONDITIONS | BIARYL COUPLING REACTION | HYPERVALENT IODINE(III) REAGENT | Coupling (molecular) | Organic chemistry | State of the art | Synthesis | Formations | Reaction mechanisms | Bonding | Complexity
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7. Full Text Cobalt‐Catalyzed, Aminoquinoline‐Directed C(sp2)H Bond Alkenylation by Alkynes
by Grigorjeva, Liene and Daugulis, Olafs
Angewandte Chemie International Edition, ISSN 1433-7851, 09/2014, Volume 53, Issue 38, pp. 10209 - 10212
A method for cobalt‐catalyzed, aminoquinoline‐ and picolinamide‐directed C(sp2)H bond alkenylation by alkynes was developed. The method shows excellent... 
CH activation | cobalt | alkenes | cyclization | alkynes | C-H activation | ACTIVATION | C-H BOND | EFFICIENT SYNTHESIS | TERMINAL ALKYNES | CARBON-HYDROGEN BONDS | DIRECT ALKYNYLATION | CHEMISTRY, MULTIDISCIPLINARY | BIDENTATE-CHELATION ASSISTANCE | UNACTIVATED C(SP)-H BONDS | ACID-DERIVATIVES | AROMATIC AMIDES | Aminoquinolines - chemistry | Amides - chemistry | Picolinic Acids - chemistry | Organometallic Compounds - chemistry | Alkynes - chemistry | Molecular Structure | Catalysis | Alkylation | Cobalt - chemistry | Alkenes | Cyclization | Cobalt | Alkynes | Catalysts | Oxidants | Oxidizing agents | Joining | Tolerances | Terminals | Bonding
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8. Full Text Theoretical study of cooperativity between hydrogen bond‒hydrogen bond, halogen bond‒halogen bond and hydrogen bond‒halogen bond in ternary FX...diazine...XF (X = H and Cl) complexes
by Masoodi, Hamid Reza and Masoodi, Hamid Reza and Bagheri, Sotoodeh and Ranjbar, Mahdiyeh
Molecular Physics, ISSN 0026-8976, 12/2016, Volume 114, Issue 23, pp. 3464 - 3474
In the present work, the cooperativity between hydrogen bond‒hydrogen bond, halogen bond‒halogen bond and hydrogen bond‒halogen bond in ternary... 
halogen bond | ab initio | diazine | cooperativity | Hydrogen bond | Protons | Hydrogen bonds | Hydrogen | Mathematical analysis | Halogens | Bonding strength | Chemical bonds | Coupling | Bonding
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9. Full Text Buttressing Salicylaldehydes: A Multipurpose Directing Group for C(sp3)−H Bond Activation
by Yada, Akira and Liao, Wenqing and Sato, Yuta and Murakami, Masahiro
Angewandte Chemie International Edition, ISSN 1433-7851, 01/2017, Volume 56, Issue 4, pp. 1073 - 1076
A palladium‐catalyzed reaction of primary amines with iodoarenes produces γ‐arylated primary amines. A bulky salicylaldehyde, which is marked as easily... 
amines | reaction mechanisms | palladium | C−H activation | arylation | FUNCTIONALIZATION | PICOLINAMIDE | C-H activation | LIGANDS | COMPLEXES | PRIMARY AMINES | CHEMISTRY, MULTIDISCIPLINARY | Palladium | Buttresses | Amines | Hydrogen bonds
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10. Full Text Hemilabile N‑Xylyl‑N′‑methylperimidine Carbene Iridium Complexes as Catalysts for C–H Activation and Dehydrogenative Silylation: Dual Role of N‑Xylyl Moiety for ortho-C–H Bond Activation and Reductive Bond Cleavage
by Choi, Gyeongshin and Tsurugi, Hayato and Mashima, Kazushi
Journal of the American Chemical Society, ISSN 0002-7863, 09/2013, Volume 135, Issue 35, pp. 13149 - 13161
Direct dehydrogenative silylation of pyridyl and iminyl substrates with triethylsilane was achieved using (L)­Ir­(cod)­(X) (1) (L = a perimidine-based carbene... 
COORDINATION CHEMISTRY | ASYMMETRIC HYDROSILYLATION | DIRECT ARYLATION | TRANSITION-METAL-COMPLEXES | HETEROCYCLIC-CARBENE | X-RAY-STRUCTURE | TRANSFER HYDROGENATION | AROMATIC SUBSTITUTION | OXIDATIVE ADDITION | SECONDARY INTERACTIONS | CHEMISTRY, MULTIDISCIPLINARY | Measurement | Analysis | Methyl groups | Iridium | Chemical properties | Structure | Activation energy | Hydrogen bonding
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11. Full Text If CH Bonds Could Talk: Selective CH Bond Oxidation
by Newhouse, Timothy and Baran, Phil S
Angewandte Chemie International Edition, ISSN 1433-7851, 04/2011, Volume 50, Issue 15, pp. 3362 - 3374
CH oxidation has a long history and an ongoing presence in research at the forefront of chemistry and interrelated fields. As such, numerous highly useful... 
natural products | CH activation | synthesis design | synthetic methods | C-H activation | FREE-RADICAL SUBSTITUTION | GENERATED IN-SITU | DIRECT REMOTE OXIDATION | IRON ACTIVE-SITES | CARBON-HYDROGEN BONDS | FORMING REDUCTIVE ELIMINATION | ALCOHOLS REACTION DEVELOPMENT | TERT-BUTYL HYDROPEROXIDE | CHEMISTRY, MULTIDISCIPLINARY | RUTHENIUM TETROXIDE OXIDATION | INSERTION REACTIONS | Oxidation-Reduction | Hydrogen - chemistry | Carbon - chemistry | C–H Activation | Synthetic Methods | Natural Products | Synthesis Design
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