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The Journal of Physical Chemistry A, ISSN 1089-5639, 03/2014, Volume 118, Issue 12, pp. 2360 - 2366
Ab initio MP2/aug′-cc-pVTZ calculations have been carried out in search of equilibrium structures with P···Cl pnicogen bonds or halogen bonds on the potential... 
Models, Chemical | Nitrogen - chemistry | Chlorine - chemistry | Chemical Phenomena | Phosphorus - chemistry | Halogens - chemistry | Hydrogen - chemistry | Fluorine - chemistry | Electrons | Chemical bonds | Research
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 01/2014, Volume 50, Issue 3, pp. 341 - 343
An efficient method for the synthesis of amides via Pd-catalyzed oxidative carbonylation of C(sp(3))-H bonds with CO and amines is described. The route... 
Quantum Theory | Oxidation-Reduction | Amides - chemical synthesis | Hydrogen | Ketones - chemistry | Amides - chemistry | Aniline Compounds - chemistry | Catalysis | Alkanes - chemistry | Palladium - chemistry | Carbon - chemistry
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 12/2017, Volume 56, Issue 50, pp. 16013 - 16017
A rhodium(II)‐ or copper(I)‐catalyzed formal intramolecular carbene insertion into vinylic C(sp2)−H bonds is reported herein. This method provides... 
metal carbenes | indenes | insertion | diazo compounds | N-tosylhydrazones | REAGENTS | METAL-CARBENE | EFFICIENT SYNTHESIS | DIAZO-COMPOUNDS | CHEMISTRY, MULTIDISCIPLINARY | C-H BONDS | FUNCTIONALIZATION | HYDROGEN | CROSS-COUPLING REACTIONS | CONSTRUCTION | Rhodium | Insertion | Copper
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 06/2012, Volume 134, Issue 24, pp. 9902 - 9905
A new strategy for generating benzylpalladium reactive species from toluenes via nondirected C(sp3)–H activation has been developed. This led to construction... 
HALIDES | PHENYLACETIC ACIDS | AMINATION | HYDROCARBONS | COUPLING REACTIONS | MONOXIDE | ARYL | CARBOXYLATION | CARBON-HYDROGEN BONDS | AROMATIC-COMPOUNDS | CHEMISTRY, MULTIDISCIPLINARY | Analysis | Carboxylation | Chemical bonds | Palladium | Chemical properties | Catalysis | Acetic acid | Structure
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 08/2018, Volume 57, Issue 32, pp. 10333 - 10337
An efficient protocol for the direct allylic C(sp3)−H bond activation of unactivated tri‐ and tetrasubstituted alkenes and their functionalization with aryl‐... 
nickel | C−H activation | alkenes | photocatalysis | allylic compounds | HALIDES | ROOM-TEMPERATURE | PALLADIUM | ARYLATION | PHOTOREDOX/NICKEL DUAL CATALYSIS | 9-MESITYL-10-METHYLACRIDINIUM | OXIDATIVE ADDITION | BROMIDES | CHEMISTRY, MULTIDISCIPLINARY | C-H activation | ACETATES | DERIVATIVES | Olefins | Nickel | Catalysis | Alkenes | Regioselectivity | Hydrogen bonds | Aromatic compounds
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 01/2014, Volume 136, Issue 3, pp. 898 - 901
The Ni-catalyzed, direct arylation of C(sp3)–H (methyl and methylene) bonds in aliphatic amides containing an 8-aminoquinoline moiety as a bidentate directing... 
C(SP)-H BONDS | ACID DERIVATIVES | PALLADIUM | C-H BOND | AROMATIC AMIDES | INTRAMOLECULAR AMINATION | NATURAL-PRODUCTS | UNACTIVATED C(SP)-H | CARBON-HYDROGEN BONDS | CHEMISTRY, MULTIDISCIPLINARY | ALKYL-HALIDES | Usage | Analysis | Chemical bonds | Amides | Chemical reactions | Nickel | Research
Journal Article
ORGANIC & BIOMOLECULAR CHEMISTRY, ISSN 1477-0520, 5/2019, Volume 17, Issue 2, pp. 4951 - 4963
Alkylated (hetero)arenes constitute one of the most fundamental skeletons in organic molecules, which prompts a growing number of research studies on the... 
FUNCTIONALIZATION | ALCOHOLS | CATALYSIS | ALKYLATION | STRATEGY | ARYLATION | CHEMISTRY, ORGANIC | GENERATION | CARBOXYLIC-ACIDS | N-HETEROARENES | TRIFLUOROMETHYLATION | Construction | Alkylating agents | Photochemicals | Alkylation | Coupling (molecular) | Organic chemistry | Hydrogen bonds | Aromatic compounds | Catalysis | Coupling | Chemical synthesis | Reaction mechanisms | Bonding agents
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 08/2016, Volume 138, Issue 34, pp. 10750 - 10753
Most chelation-assisted aliphatic C–H activation proceeds through a kinetically favored five-membered cyclometalated intermediate. Here, we report the first... 
UNACTIVATED C(SP)-H BONDS | C(SP)-H BONDS | PALLADIUM-CATALYZED ARYLATION | EFFICIENT SYNTHESIS | ALPHA-AMINO-ACIDS | CARBON-HYDROGEN BONDS | STEREOSELECTIVE-SYNTHESIS | C-H FUNCTIONALIZATION | DIRECTING-GROUP | BETA-ARYLATION | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
The Journal of Physical Chemistry A, ISSN 1089-5639, 11/2001, Volume 105, Issue 47, pp. 10739 - 10746
Different measures of H-bond strength based on X−H proton donating bond properties and on parameters of H···Y distance (Y−proton acceptor within X−H···Y H... 
DOT-H-B | SHIFT INTERACTION TENSORS | CRYSTAL-STRUCTURE | STATE NMR-SPECTROSCOPY | GAS-PHASE | DIHYDROGEN BONDS | CHEMISTRY, PHYSICAL | O-H | PROTON-TRANSFER | SOLID-STATE | ANION MODEL SYSTEM | Protons | Physiological aspects | Research | Chemistry, Physical and theoretical | Hydrogen bonding
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 01/2017, Volume 56, Issue 3, pp. 812 - 815
Herein, we introduce catalysts that operate with chalcogen bonds. Compared to conventional hydrogen bonds, chalcogen bonds are similar in strength but more... 
dithienothiophenes | chalcogen bonds | transfer hydrogenation | homogeneous catalysis | HALIDE | HALOGEN-BOND | ORGANOCATALYSIS | CHEMISTRY, MULTIDISCIPLINARY | SURFACES | Sulfur compounds | Catalysis | Hydrogen | Hydrogenation | Bonds | Force and energy
Journal Article
2007, 1st ed., ISBN 0444519572, xiii, 318
The Hydrogen Bond and the Water Molecule offers a synthesis of what is known and currently being researched on the topic of hydrogen bonds and water molecules.... 
Hydrogen bonding | Chemistry | Molecular association | Water chemistry
Book
The Journal of Organic Chemistry, ISSN 0022-3263, 11/2012, Volume 77, Issue 22, pp. 9959 - 9969
Journal Article