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1. Full Text Sulfur‐replaced Fenton systems: can sulfate radical substitute hydroxyl radical for advanced oxidation technologies?
by Zhou, Danna and Zhang, Hui and Chen, Long
Journal of Chemical Technology & Biotechnology, ISSN 0268-2575, 05/2015, Volume 90, Issue 5, pp. 775 - 779
Sulfate radicals (SO4•−) and hydroxy radicals (HO•) are the major radicals used in advanced oxidation technologies (AOTs) for the removal of contaminants.... 
advanced oxidation technologies | mineralization | Fenton process | hydroxy radical | sulfate radical | Advanced oxidation technologies | Sulfate radical | Hydroxy radical | Mineralization | CHEMISTRY, MULTIDISCIPLINARY | ENGINEERING, CHEMICAL | PILOT | REMOVAL | ENGINEERING, ENVIRONMENTAL | BIOTECHNOLOGY & APPLIED MICROBIOLOGY | WASTE-WATER | DEGRADATION | GENERATION | ORGANIC CONTAMINANTS | PERSULFATE | Chemical industry | Herbicides | Pesticides industry | Oxidation-reduction reaction | Hydroxides | Sulfates | Economics | Strontium | Contaminants | Hydroxyl radicals | Air pollution | Oxidation | Radicals
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2. Full Text Radicals in transition metal catalyzed reactions? transition metal catalyzed radical reactions? a fruitful interplay anyway: Part 1. Radical catalysis by group 4 to group 7 elements
by Jahn, Ullrich
Topics in Current Chemistry, ISSN 0340-1022, 2012, Volume 320, pp. 121 - 189
This review summarizes the current status of radical-based transition metal catalyzed reactions in organic chemistry. The underlying features of radical... 
Addition | Transition metals | Cross-coupling | Cyclization | Electron transfer | Catalysis | Radicals | C-BOND FORMATION | ALPHA-HYDROXY KETONES | CARBON-CARBON BONDS | CHEMISTRY, MULTIDISCIPLINARY | CATIONIC AMINYL RADICALS | ALKYL-HALIDES | CROSS-COUPLING REACTIONS | DUAL ACTIVATION MECHANISM | ALLYL 2-IODOPHENYL ETHER | MN-III CATALYST | CENTER-DOT TRANSFER | Transition Elements - chemistry | Organometallic Compounds - chemistry | Kinetics | Free Radicals - chemistry
Conference Proceeding
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3. Full Text Oxidative beta-Csp(3)-H Functionalization of tBuOH: A Selective Radical/Radical Cross-Coupling Access to beta-Hydroxy Thioethers
by Li, YX and Liu, D and Liu, C and Lei, AW
CHEMISTRY-AN ASIAN JOURNAL, ISSN 1861-4728, 08/2016, Volume 11, Issue 16, pp. 2246 - 2249
An oxidative beta b-Csp(3)-H functionalization of tert-butanol (tBuOH) for the construction of C S bonds through an iodine-catalyzed Csp(3)-H/S-H coupling was... 
CARBON | ESTERIFICATION | BOND FORMATION | C-H FUNCTIONALIZATION | ALKYL IODIDES | CHEMISTRY, MULTIDISCIPLINARY | PRIMARY ALCOHOLS | mercaptans | beta-hydroxy thioethers | radical oxidative coupling | iodine | DERIVATIVES | RADICAL REACTIONS | CONJUGATE ADDITION
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4. Full Text Oxidative β‐Csp3−H Functionalization of tBuOH: A Selective Radical/Radical Cross‐Coupling Access to β‐Hydroxy Thioethers
by Li, Yuxiu and Liu, Dong and Liu, Chao and Lei, Aiwen
Chemistry – An Asian Journal, ISSN 1861-4728, 08/2016, Volume 11, Issue 16, pp. 2246 - 2249
An oxidative β‐Csp3−H functionalization of tert‐butanol (tBuOH) for the construction of C−S bonds through an iodine‐catalyzed Csp3−H/S−H coupling was... 
mercaptans | iodine | radical oxidative coupling | β-hydroxy thioethers
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5. Full Text Probing the Reactivity of Photoinitiators for Free Radical Polymerization:  Time-Resolved Infrared Spectroscopic Study of Benzoyl Radicals
by Colley, Christopher S and Grills, David C and Besley, Nicholas A and Jockusch, Steffen and Matousek, Pavel and Parker, Anthony W and Towrie, Michael and Turro, Nicholas J and Gill, Peter M. W and George, Michael W
Journal of the American Chemical Society, ISSN 0002-7863, 12/2002, Volume 124, Issue 50, pp. 14952 - 14958
A series of substituted benzoyl radicals has been generated by laser flash photolysis of α-hydroxy ketones, α-amino ketones, and acyl and bis(acyl)phosphine... 
LASER FLASH-PHOTOLYSIS | ACYLPHOSPHINE OXIDES | ESR | RATE CONSTANTS | ACYL RADICALS | PHOTOPHYSICS | ALPHA-HYDROXY | PHOTOCHEMISTRY | PHOTOFRAGMENTATION | HYDROXY ALKYLPHENONES | CHEMISTRY, MULTIDISCIPLINARY | Polymerization | Infrared spectroscopy | Usage | Addition polymerization | Research | Radicals (Chemistry)
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6. Full Text Atmospheric reactivity of nitrate radicals: Reaction with peroxy radicals
by Kalalian, C and Roth, E and Chakir, A
Atmospheric Environment, ISSN 1352-2310, 10/2018, Volume 190, pp. 308 - 316
The rate constants of the reaction of nitrate and methoxymethyl peroxy, acetonyl peroxy and β-hydroxy (methyl)propylperoxy radicals were measured using laser... 
Arrhenius expressions | Atmospheric fate | Methoxymethyl peroxy | Nitrate radical NO3 | Acetonyl peroxy and β-hydroxy(methyl)propylperoxy | Laser photolysis | Peroxy radicals RO2 | Peroxy radicals RO | Nitrate radical NO | PHOTOCHEMICAL DATA | SELF-REACTION | CH3C(O)CH2O2 RADICALS | DIMETHYL ETHER | ULTRAVIOLET-ABSORPTION | HYDROPEROXY RADICALS | ENVIRONMENTAL SCIENCES | Acetonyl peroxy and beta-hydroxy(methyl)propylperoxy | REACTION-KINETICS | UV ABSORPTION-SPECTRA | METEOROLOGY & ATMOSPHERIC SCIENCES | GAS-PHASE REACTIONS | VOLATILE ORGANIC-COMPOUNDS | Photolysis | Spectrum analysis | Detectors
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7. Full Text Star‐shaped Polymers through Simple Wavelength‐Selective Free‐Radical Photopolymerization
by Eibel, Anna and Fast, David E and Sattelkow, Jürgen and Zalibera, Michal and Wang, Jieping and Huber, Alex and Müller, Georgina and Neshchadin, Dmytro and Dietliker, Kurt and Plank, Harald and Grützmacher, Hansjörg and Gescheidt, Georg
Angewandte Chemie International Edition, ISSN 1433-7851, 11/2017, Volume 56, Issue 45, pp. 14306 - 14309
Star‐shaped polymers represent highly desired materials in nanotechnology and life sciences, including biomedical applications (e.g., diagnostic imaging,... 
star polymers | photopolymerization | bisacylphosphane oxides | free-radical polymerization | wavelength selectivity | ACTIVATION | ALKYLATION | BONDS | ADJACENT | HYDROAMINOALKYLATION | CHEMISTRY, MULTIDISCIPLINARY | Drugs | Drug delivery systems | Tissue engineering | Polymerization | Oxides | Polymer industry | Polymers | Nanotechnology | Vehicles | Free radicals | Photoinitiators | Initiators | Feasibility studies | Drug delivery | Wavelength | Biomedical materials | Wavelengths | Photopolymerization | Diagnostic software | Diagnostic systems | Chemical synthesis | Photochemistry | Biomedical engineering
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8. Full Text Radical additions of acyclic and cyclic ethers to alkenes via an allyl transfer reaction involving phthalimido-N-oxyl radical
by Patil, Shradha V and Tanko, James M
Tetrahedron, ISSN 0040-4020, 12/2016, Volume 72, Issue 48, pp. 7849 - 7858
Direct functionalization of rudimentary and cheap starting materials to yield complex value added products is of great interest to synthetic chemists.... 
C–H bond | Phthalimido-N-oxyl radicals | Chain reaction | Allyl transfer | Ether functionalization | INSERTION | ACTIVATION | DIMETHYLZINC | GAMMA-HYDROXY | TRISUBSTITUTED VINYL TRIFLONES | CHEMISTRY, ORGANIC | ALDEHYDES | C-H BONDS | C-H bond | ALCOHOLS | CHEMISTRY | ACETYLENIC TRIFLONES | Olefins
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9. Full Text Photoredox-promoted alkyl radical addition/semipinacol rearrangement sequences of alkenylcyclobutanols: rapid access to cyclic ketones
by Yao, Sheng and Zhang, Kai and Zhou, Quan-Quan and Zhao, Yu and Shi, De-Qing and Xiao, Wen-Jing
Chemical communications (Cambridge, England), ISSN 1359-7345, 07/2018, Volume 54, Issue 58, pp. 8096 - 8099
Two photo-catalytic tandem alkyl radical addition/semipinacol rearrangement reactions of cycloalkanol-substituted styrenes with N-acyloxyphthalimides and... 
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10. Full Text Photoredox-promoted alkyl radical addition/semipinacol rearrangement sequences of alkenylcyclobutanols: rapid access to cyclic ketones
by Yao, Sheng and Zhang, Kai and Zhou, Quan-Quan and Zhao, Yu and Shi, De-Qing and Xiao, Wen-Jing
Chemical Communications, ISSN 1359-7345, 2018, Volume 54, Issue 58, pp. 8096 - 8099
Two photo-catalytic tandem alkyl radical addition/semipinacol rearrangement reactions of cycloalkanol-substituted styrenes with N-acyloxyphthalimides and... 
SEMIPINACOL REARRANGEMENTS | ADDITION CASCADE | SEMI-PINACOL REARRANGEMENT | C BOND-CLEAVAGE | VISIBLE-LIGHT PHOTOCATALYSIS | CATALYZED DECARBOXYLATIVE ALKYLATION | SILYL ENOL ETHERS | STEREOSELECTIVE CONSTRUCTION | CHEMISTRY, MULTIDISCIPLINARY | METAL-FREE | ALPHA-HYDROXY EPOXIDES | Oximes | Light irradiation | Ketones | Styrenes | Catalysis | Cascade chemical reactions | Functional groups | Substrates
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11. Full Text Coupling Reaction of Cu-Based Carbene and Nitroso Radical: A Tandem Reaction To Construct Isoxazolines
by Chen, Rongxiang and Zhao, Yanwei and Fang, Shangwen and Long, Wenhao and Sun, Hongmei and Wan, Xiaobing
Organic Letters, ISSN 1523-7060, 11/2017, Volume 19, Issue 21, pp. 5896 - 5899
In this letter, an unprecedented cross-coupling reaction between copper carbene and nitroso radical has been developed. This radical-carbene coupling reaction... 
H FUNCTIONALIZATION | FACILE SYNTHESIS | GAMMA-AMINO KETONES | DIRECT CONVERSION | CHEMISTRY, ORGANIC | BOND FORMATION | DIAZO-COMPOUNDS | BETA-HYDROXY KETONES | TERT-BUTYL NITRITE | CO(II)-BASED METALLORADICAL CATALYSIS | UNACTIVATED ALKENES
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12. Full Text Effect of statin use on biochemical outcome following radical prostatectomy
by Ritch, Chad R and Hruby, Greg and Badani, Ketan K and Benson, Mitchell C and McKiernan, James M
BJU International, ISSN 1464-4096, 10/2011, Volume 108, Issue 8b, pp. E211 - E216
Study Type – Prognosis (retrospective cohort) Level of Evidence 2b What’s known on the subject? and What does the study add? Statin use may reduce the risk of... 
radical prostatectomy | statin | 3‐hydroxy‐3‐methyl‐glutaryl coenzyme A (HMG CoA) reductase inhibitors | biochemical recurrence | PSA | 3-hydroxy-3-methyl-glutaryl coenzyme A (HMG CoA) reductase inhibitors | SURVIVAL | OBESITY | IMPACT | HOSPITAL SEARCH DATABASE | ANTIGEN LEVELS | CHOLESTEROL-LOWERING DRUGS | CANCER-RISK | UROLOGY & NEPHROLOGY | BODY-MASS INDEX | COHORT | RECURRENCE | Prostatic Neoplasms - surgery | Humans | Hydroxymethylglutaryl-CoA Reductase Inhibitors - therapeutic use | Middle Aged | Prostatic Neoplasms - blood | Male | Prostatectomy | Neoplasm Recurrence, Local - epidemiology | Retrospective Studies | Neoplasm Recurrence, Local - blood | Prostate-Specific Antigen - blood | Prevention | Enzymes | Thiols | Oncology, Experimental | Analysis | Surgery | Development and progression | Research | Prostate cancer | Statins | Cancer | Drug therapy | Multivariate analysis | Older people
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13. Full Text Radical Approach to the Chiral Quaternary Center in Asperaculin A: Synthesis of 9‑Deoxyasperaculin A
by Das, Dipendu and Chakraborty, Tushar Kanti
Organic Letters, ISSN 1523-7060, 02/2017, Volume 19, Issue 3, pp. 682 - 685
Diastereoselective approaches toward the synthesis of a marine-derived sesquiterpenoid fungal metabolite, asperaculin A, are delineated, combining step economy... 
OXIDATION | CORE | ASYMMETRIC DIHYDROXYLATION | CHEMISTRY, ORGANIC | ALPHA-HYDROXY | ACCESS | CYCLIZATION | SKELETON
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14. Full Text ω‑Alkynyl Lipid Surrogates for Polyunsaturated Fatty Acids: Free Radical and Enzymatic Oxidations
by Beavers, William N and Serwa, Remigiusz and Shimozu, Yuki and Tallman, Keri A and Vaught, Melissa and Dalvie, Esha D and Marnett, Lawrence J and Porter, Ned A
Journal of the American Chemical Society, ISSN 0002-7863, 08/2014, Volume 136, Issue 32, pp. 11529 - 11539
Lipid and lipid metabolite profiling are important parameters in understanding the pathogenesis of many diseases. Alkynylated polyunsaturated fatty acids are... 
Cell Line | Fatty Acids - chemistry | Free Radicals | Lipoxygenases - chemistry | Cyclooxygenase 2 - chemistry | Hydroxyeicosatetraenoic Acids - chemistry | Arachidonate 15-Lipoxygenase - chemistry | Linoleic Acid - chemistry | Chromatography, High Pressure Liquid | Spectrophotometry, Ultraviolet | Carbon - chemistry | Macromolecular Substances | Tandem Mass Spectrometry | Lipids - chemistry | Macrophages - metabolism | Animals | Fatty Acids, Unsaturated - chemistry | Soybeans - enzymology | Arachidonic Acid - chemistry | Oxygen - chemistry | Cyclooxygenase 1 - chemistry | Mice | Index Medicus
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15. Full Text Asymmetric Radical Addition of TEMPO to Titanium Enolates
by Mabe, Phillip J and Zakarian, Armen
Organic Letters, ISSN 1523-7060, 01/2014, Volume 16, Issue 2, pp. 516 - 519
A mild method for α-hydroxylation of N-acyl oxazolidinones by asymmetric radical addition of the 2,2,6,6-tetramethylpiperidine N-oxy (TEMPO) radical to... 
OXIDATION | ACID | HALOALKYLATION | ALPHA-HYDROXYLATION | OXYGENATION | N-ACYL OXAZOLIDINONES | HYDROXY CARBONYL-COMPOUNDS | ORGANOCATALYSIS | CHEMISTRY, ORGANIC | OXYAMINATION | GENERATION
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16. Full Text Sono-activated persulfate oxidation of diclofenac: Degradation, kinetics, pathway and contribution of the different radicals involved
by Monteagudo, J.M and El-taliawy, H and Durán, A and Caro, G and Bester, K
Journal of Hazardous Materials, ISSN 0304-3894, 09/2018, Volume 357, pp. 457 - 465
Degradation of a diclofenac aqueous solution was performed using persulfate anions activated by ultrasound. The objective of this study was to analyze... 
Ultrasound | Oxidation mechanisms | Pharmaceuticals | FENTON DEGRADATION | MECHANISM | DECOMPOSITION | CHEMICAL OXIDATION | AQUEOUS-SOLUTION | HYDROXYL RADICALS | ENVIRONMENTAL SCIENCES | PHOTOCATALYTIC DEGRADATION | ENGINEERING, ENVIRONMENTAL | SONOCHEMICAL DEGRADATION | DRUG DICLOFENAC | WATER | Hydroxides | Active oxygen | Analysis | Ultrasonic waves | Oxidation-reduction reaction | Superoxide | Nonsteroidal anti-inflammatory drugs | Sulfates
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17. Full Text Tyrosine−Lipid Peroxide Adducts from Radical Termination: Para Coupling and Intramolecular Diels−Alder Cyclization
by Shchepin, Roman and Möller, Matias N and Kim, Hye-young H and Hatch, Duane M and Bartesaghi, Silvina and Kalyanaraman, Balaraman and Radi, Rafael and Porter, Ned A
Journal of the American Chemical Society, ISSN 0002-7863, 12/2010, Volume 132, Issue 49, pp. 17490 - 17500
Free radical co-oxidation of polyunsaturated lipids with tyrosine or phenolic analogues of tyrosine gave rise to lipid peroxide−tyrosine (phenol) adducts in... 
MASS-SPECTROMETRIC QUANTIFICATION | ALZHEIMERS-DISEASE | ANTIOXIDANT MECHANISM | POLYUNSATURATED FATTY-ACIDS | DITYROSINE CROSS-LINKING | TERT-BUTYL ESTER | CHEMISTRY, MULTIDISCIPLINARY | HIGH-DENSITY-LIPOPROTEIN | APOLIPOPROTEIN-A-I | PARKINSONS-DISEASE | LATERAL DIFFUSION | Oxidation-Reduction | Free Radicals - chemistry | Peroxides - chemistry | Silver - chemistry | Chromatography, High Pressure Liquid | Phosphatidylcholines - chemistry | Cycloaddition Reaction | Tyrosine - analogs & derivatives | Cyclization | Lipid Peroxides - chemistry | Mass Spectrometry | Tyrosine - chemistry | Linoleic Acids - chemistry | Nuclear magnetic resonance spectroscopy | Usage | Spectra | Diels-Alder reaction | Organic solvents | Analysis | Intramolecular Diels-Alder cyclization | lipid peroxidation | para-hydroxy tyrosine | Tyrosine oxidation | lipid protein adduct
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18. Full Text Catalytic Reduction of a Tetrahydrobiopterin Radical within Nitric-oxide Synthase
by Chin-Chuan Wei and Zhi-Qiang Wang and Jesús Tejero and Ya-Ping Yang and Craig Hemann and Russ Hille and Dennis J. Stuehr
Journal of Biological Chemistry, ISSN 0021-9258, 04/2008, Volume 283, Issue 17, pp. 11734 - 11742
Nitric-oxide synthases (NOS) are catalytically self-sufficient flavo-heme enzymes that generate NO from arginine (Arg) and display a novel utilization of their... 
OXYGEN | CYTOCHROME-P450 | DOMAIN | PTERIN | ELECTRON-TRANSFER | BIOCHEMISTRY & MOLECULAR BIOLOGY | HEME-DIOXY REDUCTION | HYDROXY-L-ARGININE | OMEGA-HYDROXYARGININE | BINDING | NEURONAL NO SYNTHASE | Nitric Oxide Synthase - chemistry | Electron Spin Resonance Spectroscopy | Free Radicals | Nitric Oxide - chemistry | Oxidation-Reduction | Rats | Biopterin - analogs & derivatives | Arginine - chemistry | Crystallography, X-Ray - methods | Biopterin - chemistry | Animals | Flavins - chemistry | Nitric Oxide Synthase - metabolism | Pterins - chemistry | Catalysis | Kinetics | Enzyme Catalysis and Regulation
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19. Full Text Cyclic dipeptides exhibit potency for scavenging radicals
by Furukawa, Tadashi and Akutagawa, Takashi and Funatani, Hitomi and Uchida, Toshikazu and Hotta, Yoshihiro and Niwa, Masatake and Takaya, Yoshiaki
Bioorganic & Medicinal Chemistry, ISSN 0968-0896, 03/2012, Volume 20, Issue 6, pp. 2002 - 2009
Twenty kinds of cyclic dipeptides containing -leucine were synthesized, and their antioxidant activity against OH and was investigated. Compounds possessing... 
Cyclic dipeptide | Antioxidant | Hydroxy radical | ESR | Superoide radical | ANTIBIOTICS | METABOLITES | CHEMISTRY, MEDICINAL | ACID | PROTECTION | BIOCHEMISTRY & MOLECULAR BIOLOGY | FUNGUS EPICOCCUM-NIGRUM | CHEMISTRY, ORGANIC | STRUCTURE ELUCIDATION | ABSOLUTE-CONFIGURATION | RESIDUE | DIKETOPIPERAZINE | PEPTIDE-SYNTHESIS | Free Radical Scavengers - pharmacology | Amino Acid Sequence | Singlet Oxygen - metabolism | Leucine - pharmacology | Free Radical Scavengers - chemistry | Dipeptides - pharmacology | Peptides, Cyclic - pharmacology | Hydroxyl Radical - metabolism | Dipeptides - chemistry | Peptides, Cyclic - chemistry | Leucine - chemistry | Antioxidants | Exhibitions | Universities and colleges
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