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ketoimines (99) 99
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imines (46) 46
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by Chen, X and Xie, Y and Xiao, XS and Li, GQ and Deng, YF and Jiang, HF and Zeng, W
CHEMICAL COMMUNICATIONS, ISSN 1359-7345, 2015, Volume 51, Issue 83, pp. 15328 - 15331
A Rh(III)-catalyzed cross-coupling/cyclization cascade of alpha-imino Csp(3)-H bonds with donor/acceptor alpha-acyl diazocarbonyl compounds has been developed.... 
ONE-POT | INSERTION REACTIONS | CYCLOPROPANATION | KETOIMINES | ALDEHYDES | C-H FUNCTIONALIZATION | ALKYNES | DIAZOOXINDOLES | CHEMISTRY, MULTIDISCIPLINARY | CYCLIZATION | ACCESS
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 06/2017, Volume 53, Issue 49, pp. 6633 - 6636
A new organocatalytic enantioselective Strecker reaction of pyrazolone-derived ketimine electrophiles has been developed. Using pseudo-enantiomeric squaramide... 
Journal Article
Organic Letters, ISSN 1523-7060, 02/2018, Volume 20, Issue 3, pp. 518 - 521
Highly enantioselective synthesis of acyclic α-tertiary amines through asymmetric desymmetrization is reported. This approach is based on chiral phosphoric... 
MANZACIDIN | PHOSPHORIC-ACID | CATALYZED ASYMMETRIC ARYLATION | CHIRAL BRONSTED ACIDS | CONSTRUCTION | RESOLUTION | CHEMISTRY, ORGANIC | ALKYLAMINES | KETOIMINES | STEREOSELECTIVE-SYNTHESIS | CONJUGATE ADDITION
Journal Article
Organic Letters, ISSN 1523-7060, 06/2011, Volume 13, Issue 12, pp. 2977 - 2979
A rhodium-catalyzed asymmetric addition of readily available potassium organotrifluoroborates to both N-tosyl and N-nosyl ketimines has been developed. High... 
MANNICH REACTION | REAGENTS | CHIRAL DIENE LIGANDS | IMINES | ARYLATION | CHEMISTRY, ORGANIC | KETOIMINES | NUCLEOPHILIC-ADDITION | QUATERNARY CARBON CENTERS | ARYLBORONIC ACIDS | ENANTIOSELECTIVE STRECKER REACTION
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 07/2007, Volume 46, Issue 29, pp. 5565 - 5567
Journal Article
Organic Letters, ISSN 1523-7060, 01/2005, Volume 7, Issue 2, pp. 167 - 169
The catalytic construction of nitrogen-substituted quaternary stereocenters is an important and challenging task in asymmetric synthesis. In this paper, we... 
KETONES | ASYMMETRIC-SYNTHESIS | ALKYLATION | CONSTRUCTION | COMPLEXES | QUATERNARY STEREOCENTERS | CHEMISTRY, ORGANIC | KETOIMINES | ALDEHYDES | STRECKER REACTION | ALPHA,ALPHA-DIALKYL-ALPHA-AMINO ACIDS
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 09/2010, Volume 132, Issue 38, pp. 13168 - 13169
A rhodium-catalyzed addition of sodium tetraarylborates to N-tosyl ketimines is described. Highly efficient asymmetric catalysis has been achieved by employing... 
MANNICH REACTION | TOSYLARYLIMINES | STEERING LIGANDS | CHIRAL DIENE LIGANDS | KETOIMINES | 1,4-ADDITION | QUATERNARY CARBON CENTERS | CONJUGATE ADDITIONS | CHEMISTRY, MULTIDISCIPLINARY | ARYLBORONIC ACIDS | ENANTIOSELECTIVE STRECKER REACTION | Amines | Rhodium | Analysis | Alkadienes | Substitution reactions | Chemical properties | Catalysis | Structure | Organoboron compounds | Sodium compounds
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 02/2013, Volume 355, Issue 2‐3, pp. 548 - 558
Journal Article
Organic and Biomolecular Chemistry, ISSN 1477-0520, 2018, Volume 16, Issue 25, pp. 4633 - 4640
By employing an easily available, exceptionally simple sulfur-olefin ligand, a highly enantioselective rhodium-catalyzed arylation of cyclic N-sulfonyl... 
DESIGN | ALDIMINES | STEREOCENTERS | CONSTRUCTION | EFFICIENT SYNTHESIS | ALLYLIC ALKYLATION | CHEMISTRY, ORGANIC | KETOIMINES | OLEFIN LIGANDS | ARYLBORONIC ACIDS | ACCESS | Rhodium | Acids | Esters | Amino acids | Catalysis | Sulfur | Enantiomers | Chemical synthesis | Molecular chains
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 12/2006, Volume 128, Issue 50, pp. 16044 - 16045
A newly designed axially chiral guanidine is found to function as an effective platform for asymmetric induction at the α-carbon of unsymmetrically substituted... 
ASYMMETRIC ALPHA-AMINATION | AMINO-ACIDS | CYANOACETATES | ESTERS | ORGANOCATALYSIS | ALDEHYDES | KETOIMINES | BICYCLIC GUANIDINE | CHEMISTRY, MULTIDISCIPLINARY | STRECKER REACTION | BASE | Molecular Structure | Catalysis | Amination | Guanidine - chemistry | Stereoisomerism | Electrons | Nitrogen compounds | Carbonyl compounds | Chemical properties | Electrophiles | Guanidine
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 12/2017, Volume 56, Issue 51, pp. 16293 - 16296
A highly stereoselective synthesis of hitherto less accessible chiral α‐tertiary amines with multiple structurally similar linear carbon chains was achieved... 
amines | diastereoselective reactions | chiral auxiliaries | imines | nucleophilic addition | ACIDS | CATALYTIC ENANTIOSELECTIVE ALLYLATION | CHEMISTRY, MULTIDISCIPLINARY | ALCOHOLS | ORGANOMETALLIC REAGENTS | CONSTRUCTION | RECENT PROGRESS | KETOIMINES | STEREOSELECTIVE-SYNTHESIS | N-TOSYL KETIMINES
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 03/2004, Volume 43, Issue 14, pp. 1764 - 1766
Contrasting styles: The two catalysts shown are both effective for the cyanation of ketimines. The metal‐based catalyst 1, developed by a standard approach,... 
cyanation | imines | Strecker synthesis | homogeneous catalysis | amino acids | Amino acids | Cyanation | Imines | Homogeneous catalysis | CHEMISTRY, MULTIDISCIPLINARY | PEPTIDES | AMINO-ACIDS | CYANOSILYLATION | OPTIMIZATION | KETOIMINES | RICH | STRECKER REACTION
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 03/2006, Volume 128, Issue 8, pp. 2548 - 2549
The phase-transfer-catalyzed, highly enantioselective cyanation of aldimines using aqueous KCN has been realized based on the molecular design of chiral... 
HCN | ENANTIOSELECTIVE SYNTHESIS | IMINES | ALPHA-AMINO-ACIDS | CYANATION | KETOIMINES | KETIMINES | CHEMISTRY, MULTIDISCIPLINARY | Ammonium chloride | Ammonium compounds | Potassium compounds | Ammonium paratungstate | Aqueous solution reactions | Cyanides | Chemical properties | Research
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 10/2009, Volume 131, Issue 42, pp. 15118 - 15119
An aluminum complex was found to be high yielding and enantioselective for the addition of cyanide to aldimines and ketimines. Although catalytic asymmetric... 
HCN | ENANTIOSELECTIVE SYNTHESIS | NITRILES | IMINES | CONSTRUCTION | CYANATION | ALDEHYDES | KETOIMINES | CHEMISTRY, MULTIDISCIPLINARY | CYANIDE | Organometallic Compounds - chemistry | Molecular Structure | Catalysis | Cyanides - chemistry | Stereoisomerism | Imines - chemistry | Schiff bases | Aluminum | Analysis | Organometallic compounds | Quinoline | Cyanides | Chemical properties | Structure
Journal Article
Chemical Communications, ISSN 1359-7345, 12/2012, Volume 48, Issue 94, pp. 11552 - 11554
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 02/2008, Volume 47, Issue 7, pp. 1176 - 1178
Picking up the gauntlet: The challenge of developing highly effective catalyst systems for the enantioselective Strecker reaction to convert ketimine... 
asymmetric synthesis | ketimines | homogeneous catalysis | Strecker reaction | cyanides | Cyanides | Asymmetric synthesis | Ketimines | Homogeneous catalysis | ALDIMINES | IMINES | TMSCN | cyanides homogeneous | catalysis | CYANATION | CHEMISTRY, MULTIDISCIPLINARY | KETONES | RECENT PROGRESS | KETOIMINES | CYANIDE | Ketamine - chemistry | Titanium - chemistry | Catalysis
Journal Article
Chemical Communications, ISSN 1359-7345, 10/2013, Volume 49, Issue 83, pp. 9669 - 9671
Consecutive intramolecular desymmetrization and kinetic resolution of 2-substituted N-phenoxycarbonylserinols have been achieved in one-pot by a single chiral... 
ACIDS | BIS(OXAZOLINES) | ALKYLATION | COMPLEXES | KETOIMINES | QUATERNARY CARBON CENTERS | ENANTIOSELECTIVE CONSTRUCTION | CHEMISTRY, MULTIDISCIPLINARY | Formations | Asymmetry | Catalysts | Reaction kinetics
Journal Article
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