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1. Full Text Metal-Free Carbon Materials for CO 2 Electrochemical Reduction
by Duan, Xiaochuan and Xu, Jiantie and Wei, Zengxi and Ma, Jianmin and Guo, Shaojun and Wang, Shuangyin and Liu, Huakun and Dou, Shixue
Advanced Materials, ISSN 0935-9648, 11/2017, Volume 29, Issue 41
The rapid increase of the CO concentration in the Earth's atmosphere has resulted in numerous environmental issues, such as global warming, ocean... 
carbon materials | metal-free catalysts | heteroatom doping | reduction
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2. Full Text PhI(OAc)2-mediated oxidative trifluoromethylation of arenes with CF3SiMe3 under metal-free conditions
by Wu, Xinyue and Chu, Lingling and Qing, Feng-Ling
Tetrahedron Letters, ISSN 0040-4039, 01/2013, Volume 54, Issue 3, pp. 249 - 251
A PhI(OAc) -mediated oxidative trifluoromethylation of arenes with CF SiMe under metal-free conditions has been described. This protocol precludes the need of... 
Trifluoromethylation | Hypervalent iodine | Metal-free
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3. Full Text Nitrogen-Doped Porous Carbon Nanosheets Templated from g-C3N4as Metal-Free Electrocatalysts for Efficient Oxygen Reduction Reaction
by Yu, Huijun and Shang, Lu and Bian, Tong and Shi, Run and Waterhouse, Geoffrey I. N and Zhao, Yufei and Zhou, Chao and Wu, Li-Zhu and Tung, Chen-Ho and Zhang, Tierui
Advanced Materials, ISSN 0935-9648, 2016, Volume 28, Issue 25, pp. 5080 - 5086
porous carbon | carbon nitride | oxygen reduction reaction | metal-free | nitrogen doping
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4. Full Text Recent Applications of Organic Dyes as Photoredox Catalysts in Organic Synthesis
by Nicewicz, David A and Nguyen, Tien M
ACS Catalysis, ISSN 2155-5435, 01/2014, Volume 4, Issue 1, pp. 355 - 360
SYSTEM | ALKENES | STYRENES | ENERGY | BENZENE | VISIBLE-LIGHT PHOTOCATALYSIS | OXYGENATION | CYCLOADDITIONS | 9-MESITYL-10-METHYLACRIDINIUM | CHEMISTRY, PHYSICAL | METAL-FREE
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5. Full Text About Underappreciated Yet Active Conformations of Thiourea Organocatalysts
by Supady, Adriana and Hecht, Stefan and Baldauf, Carsten
Organic Letters, ISSN 1523-7060, 08/2017, Volume 19, Issue 16, pp. 4199 - 4202
Conformational dynamics can define the function of organocatalysts. While the accepted mechanism of Schreiner’s catalyst features a double hydrogen bond to the... 
CHEMISTRY, ORGANIC | CATALYSIS | ENERGIES | METAL-FREE
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6. Full Text Electrocatalytic Aziridination of Alkenes Mediated by n‑Bu4NI: A Radical Pathway
by Chen, Jie and Yan, Wei-Qing and Lam, Chiu Marco and Zeng, Cheng-Chu and Hu, Li-Ming and Little, R. Daniel
Organic Letters, ISSN 1523-7060, 02/2015, Volume 17, Issue 4, pp. 986 - 989
Efficient electrocatalytic aziridination of alkenes has been achieved for the first time. A structurally broad range of aziridines was easily accessed using an... 
CATALYZED AZIRIDINATION | CHEMISTRY, ORGANIC | CHLORAMINE-T | METAL-FREE AZIRIDINATION | OLEFINS | IODINE
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7. Full Text Transition metal-free strategies for the stereoselective construction of spirocyclopropyl oxindoles
by Bacher, Emily P and Ashfeld, Brandon L
Tetrahedron, ISSN 0040-4020, 10/2019, p. 130692
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8. Full Text A New and stable Mo-Mo 2 C modified g-C 3 N 4 photocatalyst for efficient visible light photocatalytic H 2 production
by Dong, Jie and Shi, Ying and Huang, Cunping and Wu, Qiang and Zeng, Tao and Yao, Weifeng
Applied Catalysis B: Environmental, ISSN 0926-3373, 04/2019, Volume 243, pp. 27 - 35
Design and preparation of highly efficient and stable cocatalysts are critical to the improvement of photocatalyst performance. A traditional cocatalyst... 
Photocatalysis | Noble-metal-free cocatalyst | Hydrogen production
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9. Full Text Aggregation-enhanced adsorption and optoelectronic performance of metal-free organic dye on anatase (1 0 1) toward water-splitting purpose: A first-principles investigation
by Zhang, Lei and Xu, Kun
Applied Surface Science, ISSN 0169-4332, 02/2020, Volume 502, p. 144139
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10. Full Text Transition-metal-free direct cross-dehydrogenative coupling reactions of quinolinones with ethers
by Wang, Gang and Wang, Jun-Tao and Zhao, Bing and Chen, Huan and Zhang, Pan-Ke and Han, Shu-Lei
Tetrahedron Letters, ISSN 0040-4039, 11/2019, p. 151426
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11. Full Text Transition-metal-free PhI(OAc)2-mediated oxidative S S and C N bond formation: Regioselective synthesis of 3H-1,2,4-dithiazol-3-imines
by Nagaraju, Tumula and Radha Krishna, Palakodety
Tetrahedron Letters, ISSN 0040-4039, 11/2019, p. 151424
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12. Full Text Synthesis of C2‐Phosphorylated Indoles via Metal‐Free 1,2‐Phosphorylation of 3‐Indolylmethanols with P(O)‐H Species
by Zou, Yun‐Xiang and Liu, Xiao‐Yan and Zhang, Jing and Yang, Hong‐Li and Yang, Xin‐Yue and Liu, Xiao‐Ling and Chu, Yi‐Wen and Chen, Long
Advanced Synthesis & Catalysis, ISSN 1615-4150, 12/2019, Volume 361, Issue 23, pp. 5311 - 5316
An efficient and practical method for synthesis of C2‐phosphorylated indoles has been disclosed via a metal‐free 1,2‐phosphorylation of 3‐indolylmethanols with... 
1,2-addition | Phosphorylation | Phosphorylated indoles | Metal-free | 3-Indolylmethanols
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13. Full Text Facile access to oxazolidin-2-imine, thiazolidin-2-imine and imidazolidin-2-imine derivatives bearing an exocyclic haloalkyliene via direct halocyclization between propargylamines, heterocumulenes and I2 (NBS)
by Huang, Shujian and Shao, Yinlin and Liu, Ruiting and Zhou, Xigeng
Tetrahedron, ISSN 0040-4020, 06/2015, Volume 71, Issue 24, pp. 4219 - 4226
A simple, cheap, efficient, and metal-free method for one-step synthesis of a library of 1,3-diheteroatom five-membered heterocycles with exocyclic C N and C C... 
Heterocycles | Metal-free | Iodocyclization | Propargylamines
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14. Full Text Low temperature solvent-free allylic oxidation of cyclohexene using graphitic oxide catalysts
by Pattisson, Samuel and Rogers, Owen and Whiston, Keith and Taylor, Stuart H and Hutchings, Graham J
Catalysis Today, ISSN 0920-5861, 2019
A range of graphitic oxides have been utilised as metal free carbocatalysts for the low temperature oxidation of cyclohexene. The activity of the catalysts was... 
Carbocatalysis | Oxidation | Metal-free | Cyclohexene | Allylic
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15. Full Text Inside Back Cover: Metal‐Free Radical Borylation of Alkyl and Aryl Iodides (Angew. Chem. Int. Ed. 51/2018)
by Cheng, Ying and Mück‐Lichtenfeld, Christian and Studer, Armido
Angewandte Chemie International Edition, ISSN 1433-7851, 12/2018, Volume 57, Issue 51, pp. 16907 - 16907
Boronic esters are highly valuable compounds in organic synthesis. In their Communication on page 16832 ff., A. Studer and co‐workers report... 
metal-free synthesis | radical process | iodides | borylation
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16. Full Text Mesoporous hybrid material composed of Mn3O4 nanoparticles on nitrogen-doped graphene for highly efficient oxygen reduction reaction
by Duan, Jingjing and Zheng, Yao and Chen, Sheng and Tang, Youhong and Jaroniec, Mietek and Qiao, Shizhang
Chemical Communications, ISSN 1359-7345, 09/2013, Volume 49, Issue 70, pp. 7705 - 7707
The hybrid material composed of Mn3O4 nanoparticles on nitrogen-doped graphene was prepared via a solvothermal process and investigated for the first time as a... 
CELLS | FACILE SYNTHESIS | CARBON | COBALT OXIDE | NANOCRYSTALS | SHEETS | CHEMISTRY, MULTIDISCIPLINARY | CATALYSTS | METAL-FREE ELECTROCATALYSTS
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17. Full Text In situ construction of g-C3N4/g-C3N 4 metal-free heterojunction for enhanced visible-light photocatalysis
by Dong, Fan and Zhao, Zaiwang and Xiong, Ting and Ni, Zilin and Zhang, Wendong and Sun, Yanjuan and Ho, Wing-Kei
ACS Applied Materials and Interfaces, ISSN 1944-8244, 11/2013, Volume 5, Issue 21, pp. 11392 - 11401
photoelectrochemical | band offset | carbon nitride | molecular composite precursors | visible light photocatalysis | charge separation and transfer | metal free heterojunction
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18. Full Text Metal-free oxidation/C(sp3)iH functionalization of unactivated alkynes using pyridine-N-oxide as the external oxidant
by Chen, Dian-Feng and Han, Zhi-Yong and He, Yu-Ping and Yu, Jie and Gong, Liu-Zhu
Angewandte Chemie - International Edition, ISSN 1433-7851, 12/2012, Volume 51, Issue 49, pp. 12307 - 12310
CiH functionalization | hydride transfer | metal-free reactions | Brønsted acid | oxidation
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19. Full Text Lactamization of sp2C−H Bonds with CO2: Transition-Metal-Free and Redox-Neutral
by Zhang, Zhen and Liao, Li-Li and Yan, Si-Shun and Wang, Lei and He, Yun-Qi and Ye, Jian-Heng and Li, Jing and Zhi, Yong-Gang and Yu, Da-Gang
Angewandte Chemie - International Edition, ISSN 1433-7851, 2016, Volume 55, Issue 25, pp. 7068 - 7072
2-quinolinones | carbon dioxide | transition-metal-free reactions | C−H transformation | lactamization
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20. Full Text Cobalt nanoparticle-embedded carbon nanotube/porous carbon hybrid derived from MOF-encapsulated Co3O4 for oxygen electrocatalysis
by Dou, Shuo and Li, Xingyue and Tao, Li and Huo, Jia and Wang, Shuangyin
Chemical Communications, ISSN 1359-7345, 2016, Volume 52, Issue 62, pp. 9727 - 9730
We successfully obtained a novel bi-functional electrocatalyst towards the ORR and OER: Co nanoparticle-embedded N-doped carbon nano tube (CNT)/porous carbon... 
CONVERSION | REDUCTION REACTION | PERFORMANCE | WATER-OXIDATION | NANOCRYSTALS | GRAPHENE | NITROGEN | CATALYST | SHEETS | CHEMISTRY, MULTIDISCIPLINARY | METAL-FREE ELECTROCATALYSTS
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