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Journal of the American Chemical Society, ISSN 0002-7863, 10/2006, Volume 128, Issue 41, pp. 13368 - 13369
We describe an efficient and highly enantioselective conjugate transfer hydrogenation of α,β-unsaturated ketones that is catalyzed by a salt made from... 
ASYMMETRIC TRANSFER HYDROGENATION | CONJUGATE REDUCTION | DIELS-ALDER REACTION | ALPHA-ACYLOXYACROLEINS | COMPLEXES | ENONES | CHIRAL BRONSTED ACID | ALDEHYDES | CHEMISTRY, MULTIDISCIPLINARY | METAL-FREE | CATALYSTS
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 12/2010, Volume 49, Issue 49, pp. 9475 - 9478
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 11/2014, Volume 136, Issue 45, pp. 15809 - 15812
Hydrogenation of alkyl and aryl ketones using H2 is catalytically achieved in 18 examples using 5 mol % B­(C6F5)3 in an ethereal solvent. In these cases the... 
HOMOGENEOUS HYDROGENATION | HETEROLYTIC DIHYDROGEN ACTIVATION | ASYMMETRIC TRANSFER HYDROGENATION | SELECTIVE HYDROGENATION | REDUCTION | CO2 | CARBONYL | METAL-FREE HYDROGENATION | ALDEHYDES | CATIONIC RHODIUM COMPLEXES | CHEMISTRY, MULTIDISCIPLINARY | Chemical properties | Ketones | Hydrogenation | Carbon compounds | Analysis
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 09/2018, Volume 57, Issue 38, pp. 12356 - 12359
Journal Article
Journal Article
Organic Letters, ISSN 1523-7060, 08/2005, Volume 7, Issue 17, pp. 3781 - 3783
The first enantioselective Brønsted acid catalyzed reduction of imines has been developed. This new organocatalytic transfer hydrogenation of ketimines with... 
CARBONYL | CHEMISTRY, ORGANIC | ASYMMETRIC-SYNTHESIS | MANNICH REACTIONS | METAL-FREE | HYDROSILYLATION
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 10/2018, Volume 57, Issue 42, pp. 13800 - 13804
Designing heterogeneous metal‐free catalysts for hydrogenation is a long‐standing challenge in catalysis. Nanodiamond‐based carbon materials were prepared that... 
Lewis pairs | metal-free catalysis | heterogeneous catalysis | nanocarbons | hydrogenation | ACTIVATION | SOLID-STATE NMR | PYRROLE | CHEMISTRY, MULTIDISCIPLINARY | SITES | SURFACE | NANOTUBES | TRIMETHYLPHOSPHINE | IONIC LIQUIDS | PROBE MOLECULE | Boron nitride | Heterogeneous catalysis | Hydrogenation | Lewis acid | Catalysts | Metals | Base pairs | Diamonds | Nanostructure | Acidity | Carbon | Substrates | Boron | Catalysis | Basicity | Graphitic structure | Electrons
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 05/2016, Volume 22, Issue 22, pp. 7422 - 7426
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 12/2017, Volume 23, Issue 72, pp. 18193 - 18202
As an extension of the reaction mechanism describing the base‐catalyzed hydrogenation of ketones according to Berkessel et al., we use a standard methodology... 
Lewis acids | metal-free catalysis | proton shuttles | carbonyl compounds | hydrogenation | Lewis bases | Amino acids | Catalysis | Ketones | Hydrogen | Hydrogenation | Protons | Carbonyl compounds | Hydrogen storage | Oxygen | Catalysts | Carboxylic acids | Aldehydes | Carbon | Substrates | Hydrogen bonds | Mathematical analysis | Protonation | Cleavage | Reaction mechanisms | Carbonyls
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 1900, Volume 137, Issue 32, pp. 10018 - 10032
The articulation of the notion of “frustrated Lewis pairs” (FLPs), which emerged from the discovery that H2 can be reversibly activated by combinations of... 
HOMOGENEOUS HYDROGENATION | NITROUS-OXIDE | N-HETEROCYCLIC CARBENE | HETEROLYTIC DIHYDROGEN ACTIVATION | SMALL-MOLECULE ACTIVATION | FREE CATALYTIC-HYDROGENATION | METAL-FREE HYDROGENATION | BOND ACTIVATION | ASYMMETRIC HYDROGENATION | CARBON-DIOXIDE | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
ACS Catalysis, ISSN 2155-5435, 09/2015, Volume 5, Issue 9, pp. 5540 - 5544
Despite rapid advances in the field of metal-free, “frustrated Lewis pair” (FLP)-catalyzed hydrogenation, the need for strictly anhydrous reaction conditions... 
catalytic hydrogenation | solvent effects | water tolerance | "frustrated Lewis pairs" | metal-free | HIGHLY ENANTIOSELECTIVE HYDROGENATION | ETHERS | CHEMISTRY, PHYSICAL | frustrated Lewis pairs | ACIDITY | Letter
Journal Article