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chemistry, multidisciplinary (36) 36
co-based metalloradical catalysis (30) 30
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FEBS Letters, ISSN 0014-5793, 05/2014, Volume 588, Issue 9, pp. 1827 - 1831
We report the trapping of two metalloradical intermediates corresponding to the transitions S to S and S to S of the oxygen evolving complex (OEC) of... 
Metalloradical | Photosystem II
Journal Article
CHEMISTRY-A EUROPEAN JOURNAL, ISSN 0947-6539, 04/2018, Volume 24, Issue 20, pp. 5253 - 5258
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 01/2018, Volume 57, Issue 1, p. n/a
Medium‐Ring Compounds In their Communication on page 140 ff., B. de Bruin et al. show that a cobalt(II) catalyst enables the synthesis of a series of unique... 
dibenzocyclooctenes | metalloradicals | cobalt | carbene radicals | ortho-quinodimethanes | Cobalt | Hydrazones | Catalysis | Cobalt compounds | Chemical synthesis | Cyclic compounds | Intermediates
Journal Article
FEBS Letters, ISSN 0014-5793, 05/2014, Volume 588, Issue 9, pp. 1827 - 1831
•The S2TyrZ intermediate is trapped on the onset of the S2 to S3 transition.•An intermediate trapped at 250K in the S3 to S0 transition is ascribed to... 
Metalloradical | Photosystem II | formula omitted
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 08/2017, Volume 56, Issue 32, pp. 9626 - 9626
A T‐shaped nickel(I) metalloradical species that is prepared by using a rigid acridane‐based PNP pincer ligand displays novel open‐shell reactivity. In their... 
metalloradicals | nickel | C−C bond activation | radicals | Carbon-carbon composites | Nickel | Species | T shape
Journal Article
ACS CATALYSIS, ISSN 2155-5435, 04/2019, Volume 9, Issue 4, pp. 3604 - 3617
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 10/2019, Volume 58, Issue 43, pp. 15504 - 15511
We report the characterization of an S=1/2 iron π‐complex, [Fe(η6‐IndH)(depe)]+ (Ind=Indenide (C9H7−), depe=1,2‐bis(diethylphosphino)ethane), which results via... 
HYSCORE | metalloradicals | weak C−H bonds | PCET reactivity | pulse EPR | Recombination | Indene | Precursors | Computer applications | Electron transfer | Bonding strength | Cations | Iron | Hydrides | Ethane
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 08/2017, Volume 56, Issue 32, pp. 9502 - 9506
A T‐shaped NiI complex was synthesized using a rigid acridane‐based pincer ligand to prepare a metalloradical center. Structural data displays a nickel ion is... 
metalloradicals | nickel | C−C bond activation | radicals | Nickel | Carbon-carbon composites | Ligands | Embedded structures | T shape
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 01/2018, Volume 57, Issue 1, pp. 140 - 145
The metalloradical activation of ortho‐benzallylaryl N‐tosyl hydrazones with [Co(TPP)] (TPP=tetraphenylporphyrin) as the catalyst enabled the controlled... 
dibenzocyclooctenes | metalloradicals | cobalt | carbene radicals | ortho-quinodimethanes | REAGENTS | 8-MEMBERED RINGS | CYCLOPROPANATION | CHEMISTRY, MULTIDISCIPLINARY | N-TOSYLHYDRAZONES | VERSATILE | CONSTRUCTION | CYCLIZATION | Hydrogen | Cobalt | Catalysis | Hydrazones | Reaction mechanisms | Base metal | Chemical synthesis | Intermediates | Exploitation | Communications | Communication
Journal Article
ACS CATALYSIS, ISSN 2155-5435, 08/2019, Volume 9, Issue 8, pp. 7596 - 7596
Redox noninnocent ligands are a promising tool to moderate electron transfer processes within base-metal catalysts. This report introduces... 
hydrides | MECHANISM | CHEMISTRY, PHYSICAL | cobalt | hydrogenation | ELECTRONIC-STRUCTURES | NANOPARTICLES | reaction mechanism | LIGANDS | REDUCTION | metalloradicals | redox-active ligands | IRON COMPLEXES | CHEMISTRY | HOMOGENEOUS CATALYSIS | METAL | ATOM TRANSFER
Journal Article
Chemical Communications, ISSN 1359-7345, 2017, Volume 53, Issue 81, pp. 11173 - 11176
A chemoselectiveCo(II)-catalyzed effective synthesis of sulfonylamidyl amide and 3-imine indole derivatives by using isocyanides and sulfonyl azides has been... 
ALKENES | ACTIVATION | BONDS | CYCLOPROPANATION | CHEMISTRY | OLEFIN AZIRIDINATION | GENERATION | CO(II)-BASED METALLORADICAL CATALYSIS | CHEMISTRY, MULTIDISCIPLINARY | C-H AMINATION
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 10/2017, Volume 53, Issue 81, pp. 11173 - 11176
A chemoselective Co(ii)-catalyzed effective synthesis of sulfonylamidyl amide and 3-imine indole derivatives by using isocyanides and sulfonyl azides has been... 
Journal Article
Organic Letters, ISSN 1523-7060, 08/2018, Volume 20, Issue 16, pp. 4828 - 4832
A new strategy for the sequential formation of aryl and amidyl C–N bonds is reported. Using trichloroethoxysulfonyl azide as a bifunctional nitrogen source,... 
TRACELESS STAUDINGER LIGATION | AMINATION | ACTIVATION | ARENES | CHEMISTRY, ORGANIC | BOND FORMATION | ACYL AZIDES | ORGANIC AZIDES | METALLORADICAL CATALYSIS | CARBOXYLIC-ACIDS | AMIDATING REAGENT
Journal Article
European Journal of Inorganic Chemistry, ISSN 1434-1948, 04/2019, Volume 2019, Issue 15, pp. 2140 - 2145
The reactivity of bimetallic nickel(–I)/group 13 complexes towards carbon dioxide is presented. Reaction of the anionic [NiML]– complexes, where M is Al or Ga,... 
Lewis acids | Redox chemistry | Disproportionation | Group 13 elements | Metalloradicals | Carbon dioxide | COORDINATION CHEMISTRY | ELECTROCATALYTIC REDUCTION | HYDROGENATION | CONVERSION | CLEAVAGE | CHEMISTRY, INORGANIC & NUCLEAR | ZERO-VALENT NICKEL | TRANSITION-METAL | LITHIUM | CARBON-DIOXIDE | CATALYSTS | Bimetals | Carbon monoxide | Adducts | Carbonyls
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 06/2019, Volume 58, Issue 24, pp. 8129 - 8133
In this work, a pincer‐type complex [Cp*Ir‐(SNPh)(SNHPh)(C2B10H9)] (2) was synthesized and its reactivity studied in detail. Interestingly, molecular hydrogen... 
iridium | metalloradicals | structure elucidation | boron | carboranes | CAGE | COMPLEXES | CENTERS | CHEMISTRY, MULTIDISCIPLINARY | H ACTIVATION | CLOSO-DODECABORATE ANIONS | CHEMISTRY | PAIR RADICAL-CATION | CHARGE | Hydrogen | Transformation | Oxidation | Carborane
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 05/2017, Volume 53, Issue 44, pp. 5993 - 5996
An unprecedented coupling reaction between aromatic amines and diazo compounds was well developed, which afforded a bridge connecting between radical chemistry... 
Journal Article
CHEMISTRY-A EUROPEAN JOURNAL, ISSN 0947-6539, 09/2017, Volume 23, Issue 52, pp. 12709 - 12713
The tripodal, tetradentate tris(1-(diphenylphosphanyl)- 3-methyl-1H-indol-2-yl)phosphane PP3-ligand 1 stabilizes Ru in the Ru-II, Ru-I, and Ru-0 oxidation... 
ELECTRON | PHOSPHINE | HYDROGEN-ATOM TRANSFER | CYCLOPROPANATION | CARBENE RADICALS | CHEMISTRY, MULTIDISCIPLINARY | ruthenium | dinitrogen complexes | IR-II(ETHENE) | metalloradicals | RUTHENIUM COMPLEXES | ETHENE | DERIVATIVES | chloride atom abstraction | METAL-COMPLEXES | tripodal ligands
Journal Article