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Angewandte Chemie International Edition, ISSN 1433-7851, 08/2017, Volume 56, Issue 35, pp. 10577 - 10581
Hexakis(2,6‐diisopropylphenylisocyanide)tantalum is the first isocyanide analogue of the highly unstable Ta(CO)6 and represents the only well‐defined... 
metalloradical | 17-electron complex | tantalum | disproportionation | isocyanide ligands | Tantalum | Disproportionation | Analogue | Benzene | Metals | Oxidation | Laboratory methods | Ethane | Carbonyls
Journal Article
Journal Article
European Journal of Inorganic Chemistry, ISSN 1434-1948, 02/2018, Volume 2018, Issue 5, pp. 617 - 626
Journal Article
Journal of Catalysis, ISSN 0021-9517, 05/2018, Volume 361, pp. 347 - 360
[Display omitted] •Insight into why the [Co(MeTAA)] catalyst is faster than [Co(TPP)].•Good agreement between experimental kinetic data and DFT data.•Proof for... 
Cyclopropanation | RPKA | DFT | Mechanistic investigations | Metalloradical | Kinetics | Open-shell catalysis | COMPLEXES | PORPHYRINS | CHEMISTRY, PHYSICAL | ENANTIOSELECTIVE CYCLOPROPANATION | CARBENE RADICALS | ENGINEERING, CHEMICAL | PRODUCTS | ASYMMETRIC CYCLOPROPANATION | OLEFINS | LIGAND | OFT | COBALT | TOOL
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 12/2018, Volume 57, Issue 52, pp. 17215 - 17219
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 05/2017, Volume 82, Issue 9, pp. 4677 - 4688
The rearrangement of sulfamoyl azides under thermal conditions to form a C–C bond while breaking two C–N bonds is reported. Mechanistic study shows that this... 
TRIPLET SULFONYLNITRENES INSERTION | C(SP)-H BONDS | RADICAL AMINATION | DECOMPOSITION | CHEMISTRY, ORGANIC | PHOTOCHEMISTRY | CURTIUS | ORGANIC AZIDES | CO(II)-BASED METALLORADICAL CATALYSIS | EFFICIENT | C-H AMINATION | Thermal properties | Azides | Sulfur compounds | Chemical properties | Research | Chemical reaction, Rate of
Journal Article
Green Chemistry, ISSN 1463-9262, 2018, Volume 20, Issue 6, pp. 1362 - 1366
An effective and operationally simple protocol is reported for the synthesis of versatile carbazoles. With water as a co-solvent, visible-light rather than... 
ORGANIC-SYNTHESIS | GREEN & SUSTAINABLE SCIENCE & TECHNOLOGY | AROMATIC AZIDES | TRANSITION-METAL-COMPLEXES | 1ST TOTAL-SYNTHESIS | SINGLET PHENYLNITRENE | AMBIENT-TEMPERATURE | N BOND FORMATION | ARYL AZIDES | RH-2(II)-CATALYZED SYNTHESIS | METALLORADICAL CATALYSIS | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Green Chemistry, ISSN 1463-9262, 01/2018, Volume 20, Issue 6, pp. 1362 - 1366
An effective and operationally simple protocol is reported for the synthesis of versatile carbazoles. With water as a co-solvent, visible-light rather than... 
Alkaloids | Carbazoles | Amination | Buffer solutions | Chemical synthesis | Metals
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 12/2008, Volume 14, Issue 35, pp. 10985 - 10998
Reactions of the methoxo complexes [{M(μ‐OMe)(cod)}2] (cod=1,5‐cyclooctadiene, M=Rh, Ir) with 2,2‐dimethylaziridine (Haz) give the mixed‐bridged complexes... 
iridium | metalloradicals | aminyl radicals | CH activation | rhodium | Aminyl radicals | C-H activation | Iridium | Rhodium | Metalloradicals
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 06/2015, Volume 56, Issue 23, pp. 3431 - 3434
[Display omitted] Aryloxysulfonyl azides can be effectively activated by commercially available cobalt(II) complex of meso-tetraphenylporphyrin ([Co(TPP)]) at... 
Metalloradical | Azide | Aziridination | Porphyrin | Radical | Cobalt | ENANTIOSELECTIVE AZIRIDINATION | MECHANISM | COMPLEXES | CYCLOPROPANATION | COBALT(II) | CHEMISTRY, ORGANIC | OLEFIN AZIRIDINATION | ORGANIC AZIDES | ARYL AZIDES | C-H AMINATION | DIPHENYLPHOSPHORYL AZIDE | Olefins | Catalysis
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 06/2017, Volume 2017, Issue 23, pp. 3302 - 3310
Journal Article
by Yoo, C and Lee, Y
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, ISSN 1433-7851, 08/2017, Volume 56, Issue 32, pp. 9502 - 9506
A T-shaped Ni-I complex was synthesized using a rigid acridane-based pincer ligand to prepare a metalloradical center. Structural data displays a nickel ion is... 
nickel | ACTIVATION | C-C bond activation | radicals | AMMONIA | COMPLEXES | REACTIVITY | CARBON BOND-CLEAVAGE | CHEMISTRY, MULTIDISCIPLINARY | 3-COORDINATE | N-2 | REDUCTION | metalloradicals | CHEMISTRY | LIGAND
Journal Article