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chemistry, multidisciplinary (37) 37
co-based metalloradical catalysis (31) 31
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Organometallics, ISSN 0276-7333, 08/2015, Volume 34, Issue 16, pp. 4051 - 4057
Alkylation of rhodium porphyrins was achieved in moderate to high yields in the presence of air and water. With this facile alkylation method, various alkyl... 
SUBSTITUTION | MECHANISM | REDUCTION | COMPLEXES | REACTIVITY | CHEMISTRY | CHEMISTRY, ORGANIC | H BONDS | METALLORADICAL ACTIVATION | CLEAVAGE | HYDROGEN BOND ACTIVATION | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, ISSN 0002-7863, 02/1992, Volume 114, Issue 5, pp. 1673 - 1681
Reactions for a series of rhodium(II) porphyrins with CO are used in illustrating the use of ligand steric effects in both promoting and inhibiting CO coupling... 
RHODIUM OCTAETHYLPORPHYRIN DIMER | SINGLE-CRYSTAL | METAL-CARBONYLS | RES SPECTRUM | CARBON-MONOXIDE | ELECTRON-PARAMAGNETIC RESONANCE | MOLECULAR STEREOCHEMISTRY | CHEMISTRY | METALLORADICAL ACTIVATION | OXIDATIVE ADDITION | STRUCTURAL CHARACTERIZATION
Journal Article
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, ISSN 0002-7863, 08/1994, Volume 116, Issue 17, pp. 7897 - 7898
Journal Article
ORGANOMETALLICS, ISSN 0276-7333, 09/1994, Volume 13, Issue 9, pp. 3390 - 3392
A benzene soluble dimeric rhodium(II) salen derivative, [(ttbs)Rh](2), with a weak Rh-Rh bond (13 kcal mol(-1)) reacts with H-2 and CO to produce hydride,... 
INSERTION | HYDROGENATION | METHANE | GAS SHIFT REACTION | CARBON-MONOXIDE | OCTAETHYLPORPHYRIN DIMER | CHEMISTRY, ORGANIC | HOMOGENEOUS CATALYSIS | RUTHENIUM | METALLORADICAL ACTIVATION | PORPHYRIN COMPLEXES | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Coordination Chemistry Reviews, ISSN 0010-8545, 1996, Volume 147, pp. 209 - 246
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 08/1997, Volume 119, Issue 34, pp. 7938 - 7944
A rhodium(II) porphyrin bimetalloradical complex, •Rh(CH2)6Rh• (1) reacts with CO and ethene to form an ethanedionyl reductive coupling product,... 
INSERTION | GAS SHIFT REACTION | REDUCTION | CARBON-MONOXIDE | OCTAETHYLPORPHYRIN DIMER | CHEMISTRY | HOMOGENEOUS CATALYSIS | K DY CHEMISTRY | METALLORADICAL ACTIVATION | OXIDATIVE ADDITION | BOND | HYDRIDE | Synthesis | Rhodium | Analysis | Porphyrins | Organic compounds
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 11/2000, Volume 39, Issue 23, pp. 5318 - 5325
A series of sterically demanding diporphyrins H2(por)−X−(por)H2 ligands that contain spacers (X) with different degrees of flexibility were synthesized from... 
CARBON HYDROGEN-BONDS | METHANE | ARTIFICIAL ALLOSTERIC SYSTEMS | IRIDIUM COMPLEXES | REACTIVITY | HOMOGENEOUS SOLUTION | METALLORADICAL ACTIVATION | COFACIAL DIPORPHYRIN | BINDING | GABLE PORPHYRIN | CHEMISTRY, INORGANIC & NUCLEAR | Chemical properties | Rhodium | Hydrogen | Porphyrins
Journal Article
Journal of Porphyrins and Phthalocyanines, ISSN 1088-4246, 02/2004, Volume 8, Issue 2, pp. 103 - 110
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 09/2005, Volume 44, Issue 19, pp. 6512 - 6514
We have found efficient electrocatalytic removal of CO by rhodium octaethylporphyrin on carbon black at a wide potential range. Using carbon-supported rhodium... 
OXIDATION | METHANE | COMPLEXES | PLATINUM | ELECTROOXIDATION | H BONDS | PORPHYRIN | METALLORADICAL ACTIVATION | CHEMISTRY, INORGANIC & NUCLEAR | Electrochemistry | Carbon Monoxide - chemistry | Adsorption | Porphyrins - chemistry | Carbon - chemistry | Rhodium - chemistry | Electrochemical analysis | Carbon monoxide | Chemical properties | Rhodium
Journal Article
BIOCHEMISTRY, ISSN 0006-2960, 12/2007, Volume 46, Issue 50, pp. 14335 - 14341
Tyr Z of photosystem II mediates electron transfer from the water splitting site, a Mn4Ca cluster, to the specialized chlorophyll assembly P-680. Due to its... 
OXYGEN-EVOLVING COMPLEX | METALLORADICAL INTERMEDIATE | ELECTRON-PARAMAGNETIC-RESONANCE | CRYSTAL-STRUCTURE | BIOCHEMISTRY & MOLECULAR BIOLOGY | TYROSINE-Z | NITRIC-OXIDE | SIGNALS | LIQUID-HELIUM TEMPERATURES | OXIDIZING COMPLEX | S-3 STATE
Journal Article
Journal Article
BIOCHEMISTRY, ISSN 0006-2960, 06/2008, Volume 47, Issue 24, pp. 6292 - 6300
The O-2-evolving complex of photosystem II, Mn4Ca, cycles through five oxidation states, S-0,..., S-4, during its catalytic function, which involves the... 
OXYGEN-EVOLVING COMPLEX | MANGANESE CLUSTER | ELECTRON-TRANSFER | METALLORADICAL INTERMEDIATE | BIOCHEMISTRY & MOLECULAR BIOLOGY | Y-Z | WATER-OXIDIZING COMPLEX | LIQUID-HELIUM TEMPERATURES | PARAMAGNETIC-RESONANCE SIGNALS | S-3 STATE | PROTON-TRANSFER
Journal Article
Organometallics, ISSN 0276-7333, 07/2008, Volume 27, Issue 13, pp. 3043 - 3055
K2CO3 and NaOPh promoted the rate of benzylic carbon−hydrogen bond activation (BnCHA) of toluenes with iridium(III) porphyrin carbonyl chloride (Ir(ttp)Cl(CO))... 
RHODIUM OCTAETHYLPORPHYRIN DIMER | MECHANISM | INSERTION REACTIONS | X-RAY | CHEMISTRY, ORGANIC | OXIDATIVE ADDITION | INTERMOLECULAR ACTIVATION | METALLORADICAL ACTIVATION | C-H ACTIVATION | CATIONIC PLATINUM(II) COMPLEXES | METAL-COMPLEXES | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 12/2008, Volume 14, Issue 35, pp. 10985 - 10998
Reactions of the methoxo complexes [{M(μ‐OMe)(cod)}2] (cod=1,5‐cyclooctadiene, M=Rh, Ir) with 2,2‐dimethylaziridine (Haz) give the mixed‐bridged complexes... 
iridium | metalloradicals | aminyl radicals | CH activation | rhodium | Aminyl radicals | C-H activation | Iridium | Rhodium | Metalloradicals
Journal Article
BBA - Bioenergetics, ISSN 0005-2728, 2010, Volume 1797, Issue 3, pp. 339 - 346
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 06/2010, Volume 49, Issue 24, pp. 4088 - 4091
Journal Article
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