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1. Full Text Direct Acylation of C(sp3)−H Bonds Enabled by Nickel and Photoredox Catalysis
by Joe, Candice L and Doyle, Abigail G
Angewandte Chemie International Edition, ISSN 1433-7851, 03/2016, Volume 55, Issue 12, pp. 4040 - 4043
Using nickel and photoredox catalysis, the direct functionalization of C(sp3)−H bonds of N‐aryl amines by acyl electrophiles is described. The method affords a... 
cross-coupling | nickel | C−H activation | photochemistry | acylation | C-H activation | C-H BOND | MERGING PHOTOREDOX | DIRECT ARYLATION | VISIBLE-LIGHT PHOTOCATALYSIS | NATURAL-PRODUCTS | CARBONYL-COMPOUNDS | SINGLE-ELECTRON TRANSMETALATION | CHEMISTRY, MULTIDISCIPLINARY | ARYL HALIDES | SYNTHETIC APPLICATIONS | DUAL CATALYSIS | Catalysis | Hydrogen Bonding | Nickel - chemistry | Oxidation-Reduction | Acylation | Photochemical Processes | Nickel | Aromatic amines | Temperature | Cross coupling | Amines | Ketones | Metals | Activation | Radicals | Aromatic compounds | Temperature effects | Chelation | Oxidation | Coupling | Bonding | C–H activation
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2. Full Text Auxiliary‐Directed C(sp3)−H Arylation by Synergistic Photoredox and Palladium Catalysis
by Czyz, Milena L and Lupton, David W and Polyzos, Anastasios
Chemistry – A European Journal, ISSN 0947-6539, 10/2017, Volume 23, Issue 58, pp. 14450 - 14453
Herein we describe the auxiliary‐directed arylation of unactivated C(sp3)−H bonds with aryldiazonium salts, which proceeds under synergistic photoredox and... 
palladium | C−H activation | photoredox | metallaphotoredox | arylation | AMIDATION | CARBON-HYDROGEN BONDS | SINGLE-ELECTRON TRANSMETALATION | CHEMISTRY, MULTIDISCIPLINARY | ALIPHATIC AMIDES | C-H activation | C-H ARYLATION | NICKEL | ARYL HALIDES | OXIDATIVE CYCLIZATION | C(SP)-H | DUAL CATALYSIS | Amides | Palladium | Catalysis | Salts | Quaternary | Selectivity | Aliphatic compounds
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3. Full Text Direct Cross‐Coupling of Allylic C(sp3)−H Bonds with Aryl‐ and Vinylbromides by Combined Nickel and Visible‐Light Catalysis
by Huang, Long and Rueping, Magnus
Angewandte Chemie International Edition, ISSN 1433-7851, 08/2018, Volume 57, Issue 32, pp. 10333 - 10337
An efficient protocol for the direct allylic C(sp3)−H bond activation of unactivated tri‐ and tetrasubstituted alkenes and their functionalization with aryl‐... 
nickel | C−H activation | alkenes | photocatalysis | allylic compounds | HALIDES | ROOM-TEMPERATURE | PALLADIUM | ARYLATION | PHOTOREDOX/NICKEL DUAL CATALYSIS | 9-MESITYL-10-METHYLACRIDINIUM | OXIDATIVE ADDITION | BROMIDES | CHEMISTRY, MULTIDISCIPLINARY | C-H activation | ACETATES | DERIVATIVES | Olefins | Nickel | Catalysis | Alkenes | Regioselectivity | Hydrogen bonds | Aromatic compounds
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4. Full Text Nickel Catalysis Enables Oxidative C(sp2)–H/C(sp2)–H Cross‐Coupling Reactions between Two Heteroarenes
by Cheng, Yangyang and Wu, Yimin and Tan, Guangyin and You, Jingsong
Angewandte Chemie International Edition, ISSN 1433-7851, 09/2016, Volume 55, Issue 40, pp. 12275 - 12279
Nickel can be used to promote oxidative C(sp2)−H/C(sp2)−H cross‐coupling between two heteroarenes. The reaction scope can be extended to aromatic carboxamides... 
heteroarenes | nickel | oxidative cross-coupling | homogeneous catalysis | synthetic methods | DIRECTING GROUP | AZOLES | ARYLATION | C-H ACTIVATION | CHEMISTRY, MULTIDISCIPLINARY | INDOLES | FUNCTIONALIZATION | BONDS | DERIVATIVES | ACCESS | COBALT | Silver | Costs | Cross coupling | Functional anatomy | Chemical reactions | Nickel | Catalysis | Coupling | Compatibility | Cost engineering
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5. Full Text Room Temperature C-P Bond Formation Enabled by Merging Nickel Catalysis and Visible-Light-Induced Photoredox Catalysis
by Xuan, Jun and Zeng, Ting‐Ting and Chen, Jia‐Rong and Lu, Liang‐Qiu and Xiao, Wen‐Jing
Chemistry – A European Journal, ISSN 0947-6539, 03/2015, Volume 21, Issue 13, pp. 4962 - 4965
A novel and efficient CP bond formation reaction of diarylphosphine oxides with aryl iodides was achieved by combining nickel catalysis and... 
CP bond formation | nickel | dual catalysis | radicals | photochemistry | Dual catalysis | C-P bond formation | Nickel | Radicals | Photochemistry | GOLD | STRATEGY | PHOTOCATALYSIS | CHEMISTRY, MULTIDISCIPLINARY | ARYLBORONIC ACIDS | H ARYLATION | FUNCTIONALIZATION | CHEMISTRY | PHOSPHINE OXIDES | METAL-FREE | Iodides | Methodology | Aromatic compounds | Oxides | Tolerances | Catalysis | Bonding
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6. Full Text Breaking Amides using Nickel Catalysis
by Dander, Jacob E and Garg, Neil K
ACS Catalysis, ISSN 2155-5435, 02/2017, Volume 7, Issue 2, pp. 1413 - 1423
Amides have been widely studied for decades, but their synthetic utility has remained limited in reactions that proceed with rupture of the amide C–N bond.... 
cross-coupling | nickel | nonprecious metal | catalysis | amides | STEREOSPECIFIC FORMATION | MERGING PHOTOREDOX | CHEMISTRY, PHYSICAL | ORGANOZINC REAGENTS | CROSS-COUPLING REACTIONS | KETONE SYNTHESIS | CARBON-NITROGEN BOND | N-C CLEAVAGE | METAL CATALYSIS | ARYL CHLORIDES | CARBOXYLIC-ACIDS
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7. Full Text Photoredox/Nickel Dual Catalysis for the C(sp3)–C(sp3) Cross‐Coupling of Alkylsilicates with Alkyl Halides
by Lévêque, Christophe and Corcé, Vincent and Chenneberg, Ludwig and Ollivier, Cyril and Fensterbank, Louis
European Journal of Organic Chemistry, ISSN 1434-193X, 04/2017, Volume 2017, Issue 15, pp. 2118 - 2121
Alkylsilicates were engaged under photoredox/nickel dual catalysis conditions with alkyl halides for the first time. The C(sp3)–C(sp3) cross‐coupling products... 
Photoredox catalysis | C–C coupling | Nickel | Radical reactions | Cross‐coupling | Cross-coupling | C-C coupling | OXIDATION | ACTIVATION | REAGENTS | CARBON | NICKEL CATALYSIS | CHEMISTRY, ORGANIC | SINGLE-ELECTRON TRANSMETALATION | ARYL BROMIDES | SILICATES | ESTERS | VISIBLE-LIGHT-PHOTOREDOX | Organic chemistry | Chemical Sciences | Catalysis
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8. Full Text para‐Selective C−H Borylation of (Hetero)Arenes by Cooperative Iridium/Aluminum Catalysis
by Yang, Lichen and Semba, Kazuhiko and Nakao, Yoshiaki
Angewandte Chemie International Edition, ISSN 1433-7851, 04/2017, Volume 56, Issue 17, pp. 4853 - 4857
para‐Selective C−H borylation of benzamides and pyridines has been achieved by cooperative iridium/aluminum catalysis. A combination of iridium catalysts... 
iridium | regioselectivity | Lewis acids | C-H activation | boronate esters | ROOM-TEMPERATURE | ARYLATION | BOND FUNCTIONALIZATION | NICKEL/LEWIS ACID CATALYSIS | CHEMISTRY, MULTIDISCIPLINARY | MONOSUBSTITUTED ARENES | PHENOLS | LIGAND | ELECTRON-RICH ARENES | DERIVATIVES | Synthesis | Pyridine | Catalysis | Organic compounds | Aluminum | Lewis acid | Pyridines | Catalysts | Regioselectivity | Aromatic compounds | Iridium | Intermediates
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9. Full Text Recent advances in homogeneous nickel catalysis
by Tasker, Sarah Z and Standley, Eric A and Jamison, Timothy F
Nature, ISSN 0028-0836, 2014, Volume 509, Issue 7500, pp. 299 - 309
Tremendous advances have been made in nickel catalysis over the past decade. Several key properties of nickel, such as facile oxidative addition and ready... 
BIDENTATE-CHELATION ASSISTANCE | BORONIC ACIDS | ORGANOZINC REAGENTS | ARYL GRIGNARD-REAGENTS | CROSS-COUPLING REACTIONS | STEREOSPECIFIC FORMATION | C-O BOND | MULTIDISCIPLINARY SCIENCES | OXIDATIVE-ADDITION | HECK REACTIONS | SECONDARY ALKYL-HALIDES | Chemistry Techniques, Synthetic | Chemistry, Organic | Catalysis | Nickel - chemistry | Oxidation-Reduction | Chemical research | Chemical reactions | Nickel | Research | Properties | Methods | Studies | Chemistry | Catalysts | Phenols | Ligands
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10. Full Text Merging Visible‐Light Photocatalysis and Palladium Catalysis for C−H Acylation of Azo‐ and Azoxybenzenes with α‐Keto Acids
by Xu, Ning and Li, Pinhua and Xie, Zuguang and Wang, Lei
Chemistry – A European Journal, ISSN 0947-6539, 02/2016, Volume 22, Issue 7, pp. 2236 - 2242
An efficient C−H acylation of azo‐ and azoxybenzenes with α‐keto acids has been developed by a combination of palladium catalysis and visible‐light photoredox... 
palladium | acylation | visible-light photocatalysis | azo compounds | blue LED | TRANSITION-METAL CATALYSIS | NICKEL CATALYSIS | ANTI-MARKOVNIKOV HYDROAMINATION | OXOCARBOXYLIC ACIDS | DIRECT ACCESS | CHEMISTRY, MULTIDISCIPLINARY | ORGANIC PHOTOREDOX SYSTEM | ARYL DIAZONIUM SALTS | BENZOPHENONE RELATED-COMPOUNDS | DECARBOXYLATIVE ORTHO-ACYLATION | CARBOXYLIC-ACIDS | Ketones | Acids | Aromatic compounds | Azo | Irradiation | Light emitting diodes | Palladium | Catalysis | Acylation | Merging | Photocatalysis
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11. Full Text Metal–Metal Bonds in Catalysis
by Powers, Ian G and Uyeda, Christopher
ACS Catalysis, ISSN 2155-5435, 02/2017, Volume 7, Issue 2, pp. 936 - 958
Transition metals can assemble to form multinuclear complexes by engaging in direct metal-to-metal interactions. Metal–metal covalent bonds provide a large... 
metal-metal bonds | catalysis | cooperativity effects | organometallic chemistry | multinuclear complexes | PAUSON-KHAND REACTION | C-H BOND | CRYSTAL-STRUCTURE | PROPARGYLIC SUBSTITUTION-REACTIONS | CHEMISTRY, PHYSICAL | REDOX-ACTIVE LIGANDS | FORMING REDUCTIVE ELIMINATION | CROSS-COUPLING REACTIONS | CARBON-MONOXIDE DEHYDROGENASE | DINUCLEAR NICKEL-COMPLEXES | OXIDATIVE-ADDITION-REACTIONS
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