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nitrene (163) 163
chemistry, multidisciplinary (142) 142
nitrenes (141) 141
chemistry, organic (111) 111
catalysis (78) 78
amination (75) 75
insertion (62) 62
aziridination (54) 54
azides (53) 53
c-h amination (52) 52
nitrene insertion (51) 51
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chemistry (47) 47
index medicus (46) 46
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organic chemistry (35) 35
activation (34) 34
chemistry, physical (34) 34
functionalization (34) 34
azid (32) 32
ligands (32) 32
rhodium (31) 31
aminierung (29) 29
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amines (26) 26
aryl azides (25) 25
c-h bonds (25) 25
ligand (25) 25
photolysis (25) 25
chemical properties (24) 24
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organic compounds (23) 23
oxidation (23) 23
bonds (22) 22
chemistry, inorganic & nuclear (22) 22
photochemistry (22) 22
analysis (21) 21
nitrogen (21) 21
copper (20) 20
cyclization (20) 20
iron (20) 20
reagents (20) 20
ruthenium (19) 19
substrates (19) 19
c-h activation (18) 18
hydrogen (18) 18
molecular structure (18) 18
alkene aziridination (17) 17
chemical reactions (17) 17
chemical sciences (17) 17
heterocycles (17) 17
hydrogen bonds (17) 17
synthesis (17) 17
chemical synthesis (16) 16
carbene (15) 15
insertions (15) 15
organic-synthesis (15) 15
aromatic compounds (14) 14
carben (14) 14
intermolecular amination (14) 14
metals (14) 14
nitrogen-atom-transfer (14) 14
palladium (14) 14
porphyrins (14) 14
selectivity (14) 14
asymmetric aziridination (13) 13
chemical bonds (13) 13
chemisches reaktionsvermögen (13) 13
electronic-structure (13) 13
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mechanistic insights (13) 13
olefin aziridination (13) 13
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chemistry, applied (12) 12
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enantioselective aziridination (11) 11
funktionalisierung (11) 11
gold (11) 11
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imines - chemistry (11) 11
laser flash-photolysis (11) 11
nitrene transfer-reactions (11) 11
amin (10) 10
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Synthesis, ISSN 0039-7881, 08/2013, Volume 45, Issue 15, pp. 2079 - 2087
...–H insertion of a chiral nitrene is reported. The reaction involves a chiral rhodium... 
practical synthetic procedures | amines | C-H amination | nitrene | asymmetric catalysis | rhodium | ORGANIC-SYNTHESIS | ACID | HYDROCARBONS | CHEMISTRY, ORGANIC | INSERTIONS | FUNCTIONALIZATION | LIGANDS | NITROGEN | Organic chemistry | Chemical Sciences
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 06/2008, Volume 47, Issue 27, pp. 5056 - 5059
Azides to indoles: Dirhodium(II)‐catalyzed decomposition of aryl azides was developed as a mild, functional group tolerant method for the synthesis of indoles... 
CH amination | indoles | azides | rhodium | Azides | C-H amination | Indoles | Rhodium | CATALYZED AZIRIDINATION | NITRENE TRANSFER | ROUTE | INSERTION | TRANSITION-METAL-COMPLEXES | AZIDOACRYLATES | ORGANIC AZIDES | CHEMISTRY, MULTIDISCIPLINARY | FUNCTIONALIZATION | BONDS
Journal Article
Journal of Non-Crystalline Solids, ISSN 0022-3093, 03/2014, Volume 387, pp. 148 - 154
Arylazide derivatives have been used for the surface functionalization of chalcogenide glasses. These compounds are photografted by a deposition step followed... 
Chalcogenide glass | Surface modification | Azide photochemistry | FTIR-ATR detection | PHENYLNITRENE | INSERTION | ATR DEVICES | REAGENTS | MATERIALS SCIENCE, MULTIDISCIPLINARY | PERFLUOROPHENYL AZIDES | MATERIALS SCIENCE, CERAMICS | FUNCTIONALIZATION | FIBERS | BIOSENSOR | NITRENE | Benzoic acid | X-ray spectroscopy | Mass spectrometry | Analysis
Journal Article
by Xiao, XS and Hou, C and Zhang, ZH and Ke, ZF and Lan, JY and Jiang, HF and Zeng, W
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, ISSN 1433-7851, 09/2016, Volume 55, Issue 39, pp. 11897 - 11901
...)-H bond has been achieved using IrIII catalysts. The introduced N,N'-bichelating ligand plays a crucial role in enabling iridium-nitrene insertion into a secondary Csp(3... 
C-SP3-H BONDS | C(SP)-H BONDS | ACTIVATION | tosyl azides | COMPLEXES | iridium catalysis | COPPER | CHEMISTRY, MULTIDISCIPLINARY | sulfonylamidation | nitrene insertion | C(sp)-H activation | NITROGEN-SOURCE | C-H AMINATION | CATALYZED INTRAMOLECULAR AMINATION | INSIGHTS
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 2010, Volume 49, Issue 52, pp. 10192 - 10196
... amination of abundant CH bonds on the basis of a metal‐mediated nitrene‐insertion pathway is one of the most general and direct methods for installing nitrogen... 
CH amination | sulfamoyl azides | nitrene transfer | cobalt porphyrins | 1,3‐diamines | C-H amination | 1,3-diamines | INSERTION | DESIGN | TRANSITION-METAL-COMPLEXES | AMIDATION | ORGANIC AZIDES | CHEMISTRY, MULTIDISCIPLINARY | FUNCTIONALIZATION | AMINES | AZIRIDINATION | BONDS | EFFICIENT
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 07/2006, Volume 45, Issue 28, pp. 4641 - 4644
Successful matchmaking: The combination of a chiral nitrene precursor with a chiral rhodium(II) catalyst is the key factor that allows efficient intermolecular... 
hypervalent iodine | amination | CH insertion | nitrenes | rhodium | Nitrenes | Amination | Rhodium | Hypervalent iodine | C-H insertion | ACTIVATION | DIRHODIUM(II) | NITROGEN-ATOM-TRANSFER | ENANTIOSELECTIVE INTRAMOLECULAR AMIDATION | SULFAMATE ESTERS | RUTHENIUM | CHEMISTRY, MULTIDISCIPLINARY | HIGHLY EFFICIENT | FUNCTIONALIZATION | AZIRIDINATION | N BOND FORMATION | Organic chemistry | Chemical Sciences
Journal Article
Chem, ISSN 2451-9294, 2019, Volume 5, Issue 1, pp. 227 - 236
Discoveries of chemical reactions with potential energy surfaces with post-transition-state bifurcations are increasing in frequency. Although such potential... 
selectivity | nitrene | bifurcation | dynamics | asynchrony | SDG12: Responsible consumption and production | SDG7: Affordable and clean energy | potential energy surface | SDG9: Industry, innovation, and infrastructure
Journal Article
ACS Catalysis, ISSN 2155-5435, 12/2016, Volume 6, Issue 12, pp. 8162 - 8165
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 12/2013, Volume 54, Issue 49, pp. 6764 - 6767
...) and 2-methyl-5,5-diphenyl-4-phenylamino-2,5-dihydrooxazole (10) as products derived from nitrene insertion to the ether α-C–H bond. 
1H-Diazirines | Imidoylnitrenes | 3H-Diazirines | Nitrene C–H insertion | Nitrene C-H insertion | REARRANGEMENT | CHEMISTRY, ORGANIC | MATRIX-ISOLATION | Diethyl ether | Tetrahedrons | Insertion | Bromides | Cyanides | Formations | Ethers | Bonding
Journal Article
Chemical Communications, ISSN 1359-7345, 09/2015, Volume 51, Issue 91, pp. 16312 - 16315
.... Furthermore, from readily available substrates, Pd-catalyzed coupling with a tandem amine insertion cascade to obtain unsymmetric trisubstituted guanidines... 
MILD | NITRENE TRANSFER | COMPLEX CATALYSTS | NITROGEN-SOURCE | C-H AMIDATION | SYNTHETIC REACTIONS | ARYL AZIDES | ORGANIC AZIDES | EFFICIENT | CHEMISTRY, MULTIDISCIPLINARY | CARBODIIMIDES | Amines | Aromatic compounds | Cascades | Insertion | Chemical reactions | Joining | Palladium | Carbodiimides
Journal Article
Organic letters, ISSN 1523-7060, 01/2019, Volume 21, Issue 1, pp. 185 - 189
A Rh­(I)-catalyzed intermolecular cyclization between isocyanates and benzocyclobutenols leading to isoquinolin-1­(2H)-ones through selective cleavage of a C–C... 
NITRENE TRANSFER | ACTIVATION TOTAL-SYNTHESIS | O BOND | INTERNAL OXIDANT | BIOLOGICAL EVALUATION | REGIOSELECTIVE SYNTHESIS | CHEMISTRY, ORGANIC | SITE-SELECTIVITY | CATALYZED OXIDATIVE COUPLING/CYCLIZATION | DENITROGENATIVE ALKYNE INSERTION | H/N-H ACTIVATION
Journal Article
ACS catalysis, ISSN 2155-5435, 04/2019, Volume 9, Issue 4, pp. 3604 - 3617
Direct C–H bond functionalization to form C–N bonds via nitrenoid insertion is one of the most effective strategies to construct N-functionalized molecules of importance... 
C-H amination | RUTHENIUM PORPHYRINS | NITROGEN-ATOM-TRANSFER | MANGANESE PORPHYRINS | CHEMISTRY, PHYSICAL | NITRENE TRANSFER-REACTIONS | metalloradical catalysis | INTRAMOLECULAR AMIDATION | TRIAZOLE OXINDOLE TROX-1 | nitrene insertion | RADICAL AMINATION | C(SP)-H AMINATION | ARYL AZIDES | N-scaffolds | CO(II)-BASED METALLORADICAL CATALYSIS | metalloporphyrin
Journal Article
ACS Catalysis, ISSN 2155-5435, 09/2018, Volume 8, Issue 9, pp. 8369 - 8375
.... The reaction proceeds via nitrene (outer sphere pathway) C­(sp2)–H insertion to yield benzoxazolones under external-oxidant-free conditions at ambient temperature... 
iron-catalysis | nitrene insertion | chemoselective | DFT calculations | benzoxazolone | C-H amidation | NITRENE TRANSFER | ACTIVATION | REAGENTS | CHEMISTRY, PHYSICAL | ELECTROPHILIC AMINATION | HETEROARENES | AZIRIDINATION | C(SP)-H AMINATION | INTERMEDIATE | N BOND FORMATION | ARYL AZIDES
Journal Article
Chemistry – An Asian Journal, ISSN 1861-4728, 09/2007, Volume 2, Issue 9, pp. 1101 - 1108
The potential‐energy surfaces of the reactions of dirhodium tetracarboxylate (Rh2II,II) catalyzed nitrene (NR) insertion into CH bonds were examined by a DFT computational study... 
amidation | reaction mechanisms | density functional calculations | nitrene insertion | rhodium | Nitrene insertion | Density functional calculations | Rhodium | Reaction mechanisms | Amidation
Journal Article
European journal of organic chemistry, ISSN 1434-193X, 2019, Volume 2019, Issue 6, pp. 1261 - 1267
An enantioselective synthesis of the β‐amino acid moiety of fijiolide A is described. Starting from eugenol, two sulfamates could be obtained on gram scale as... 
Nitrene insertion | Amino acids | Fijiolide A | C–H Amination | CHEMISTRY, ORGANIC | C-H Amination
Journal Article
ORGANIC & BIOMOLECULAR CHEMISTRY, ISSN 1477-0520, 2015, Volume 13, Issue 7, pp. 2129 - 2133
A simple method for direct metal-free C-H amination of unactivated hydrocarbons using easy-handling diacetoxy-lambda(3)-bromane and triflylamide or sulfamate... 
OXIDATION | INTERMOLECULAR AMINATION | NITRENE INSERTION | BONDS | CHEMISTRY, ORGANIC | SULFONAMIDES
Journal Article
Chemical communications (Cambridge, England), ISSN 1364-548X, 2010, Volume 46, Issue 37, pp. 6926 - 6928
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 04/2015, Volume 51, Issue 30, pp. 6515 - 6517
Herein we demonstrate redox switchable emission from a sensitised, europium-ferrocene containing, molecular film assembled by a novel nitrene-based strategy.... 
Journal Article
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