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Polyhedron, ISSN 0277-5387, 11/2019, Volume 172, pp. 45 - 57
Significant impact of ancillary ligands (2-phenylazopyridine (pap), 2,2′-bipyridyl (bpy), acetylacetonate (acac)) on the Ru-chelation assisted oxidative... 
Ruthenium complexes | Diketiminate | Redox non-innocence | Mechanism | Oxidative functionalization
Journal Article
Chemical Society Reviews, ISSN 0306-0012, 02/2013, Volume 42, Issue 4, pp. 1784 - 1795
This tutorial review discusses the structural and electronic consequences of the Jahn-Teller effect in transition metal complexes, focussing on copper(II)... 
6-COORDINATE COPPER(II) COMPLEX | COORDINATION CHEMISTRY | HIGH-PRESSURE | TUTTON SALT | AMMONIUM HEXAAQUACOPPER(II) SULFATE | REDOX NON-INNOCENCE | CRYSTAL-STRUCTURE | LOW-TEMPERATURE | CHEMISTRY, MULTIDISCIPLINARY | SOLID-STATE | ELECTRONIC-STRUCTURE
Journal Article
11/2012
Asymmetric catalysis is one of the most effective ways to control a target molecule’s stereochemistry. Through the development of a wide variety of chiral... 
Chiral Ligand | Hetero-Diels-Alder | Dithiolenes | 0488 | Asymmetric Catalysis | Platinum | Palladium | Ligand Non Innocence
Dissertation
Inorganica Chimica Acta, ISSN 0020-1693, 01/2020, Volume 499, p. 119193
The synthesis of Ru and Os complexes of the ligand, N, Ń-bis(2-pyridyl)benzene-1,2-diamine namely, [Ru (acac) (Py-bqdi)], ( ), [Ru (Ph-trpy)(Py-bqdi)Cl], ( )... 
Electrochemistry | Density functional calculation | Electron paramagnetic resonance | Molecular structure | Redox non-innocence
Journal Article
Chemical Society Reviews, ISSN 0306-0012, 01/2013, Volume 42, Issue 4, pp. 1784 - 1795
This tutorial reviewdiscusses the structural and electronic consequences of the Jahn-Teller effect in transition metal complexes, focussing on copper(ii)... 
Transition metals | Transition metal compounds | Lattices | Superconductivity | Electronics | Distortion | Ceramics | Jahn-Teller effect
Journal Article
by You, D and Yang, HF and Sen, S and Gabbai, FP
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, ISSN 0002-7863, 08/2018, Volume 140, Issue 30, pp. 9644 - 9651
In search of ligand platforms, which can be used to remotely control the catalytic activity of a transition metal, we have investigated the coordination... 
NON-INNOCENCE | DATIVE BONDS | ACTIVATION | BLOCK METALS | HYDROGENATION | PALLADIUM COMPLEXES | CONVERSION | ONLY LEWIS PAIRS | REDOX | CHEMISTRY, MULTIDISCIPLINARY | ACIDIC GROUP-13 METALLOLIGANDS
Journal Article
Dalton Transactions, ISSN 1477-9226, 08/2019, Volume 48, Issue 37, pp. 13981 - 13988
Group 13 complexes of the type [(PhNNC(p-tol)NNPh)ZPh2]2- (Z = B, Al) containing a highly reduced, trianionic formazanate-derived ligand were studied and the... 
NON-INNOCENCE | REDUCTION | HOMOLYSIS | VERSATILE | ANALOGS | REACTIVITY | CHEMISTRY | N-H BOND | COORDINATION | TOOL | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 05/2017, Volume 139, Issue 20, pp. 6843 - 6846
With the view of developing self-activating electrophilic catalysts, we are now investigating complexes with a Lewis acidic moiety in the immediate vicinity of... 
OXIDATION | ACTIVATION | C-C BOND | TRANSITION-METAL | REACTIVITY | CHEMISTRY | CHEMISTRY, MULTIDISCIPLINARY | COORDINATION NON-INNOCENCE | PAIRS | Platinum compounds | Antimony | Ligands | Chemical properties | Research | Catalysis | Coordination compounds
Journal Article
Chemical Communications, ISSN 1359-7345, 04/2015, Volume 51, Issue 29, pp. 6357 - 6360
A novel Schiff base probe exhibited strong 'turn-ON' fluorescence for Cu2+ at 345 nm, Al3+ at 445 nm, and Cu+ at 360 nm in the presence of Al3+ in organic... 
CHEMOSENSOR | EXCITED-STATE | REDOX NON-INNOCENCE | COMPLEXES | SENSOR | COPPER | LIGAND | CHEMISTRY, MULTIDISCIPLINARY | PROBES
Journal Article
Organometallics, ISSN 0276-7333, 11/2018, Volume 37, Issue 21, pp. 3854 - 3862
Five complexes of the general formula PdCl2(SbMe2Cl)(n) (n = 1-5) have been synthesized by combining [PdCl2(MeCN)(2)] and SbMe2Cl in different molar ratios in... 
PSEUDOPOTENTIALS | NON-INNOCENCE | ACTIVATION | ENERGY | APPROXIMATION | AB-INITIO | COMPLEXES | STEREOCHEMISTRY | CHEMISTRY, ORGANIC | BASIS-SETS | CRYSTAL | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
CHEMISTRY-A EUROPEAN JOURNAL, ISSN 0947-6539, 11/2017, Volume 23, Issue 61, pp. 15322 - 15326
A contracted doubly N-confused dioxohexaphyrin(1.1.1.1.1.0) complex consisting of two paramagnetic copper metals and open-shell pi-radical ligand was... 
FUSION | CORROLE | COMPLEXES | redox non-innocence | hexaphyrin | CHEMISTRY, MULTIDISCIPLINARY | PALLADIUM METALATION | METALS | metal complex | SPIN FRUSTRATION | copper | RADICALS | aromaticity
Journal Article
INORGANIC CHEMISTRY, ISSN 0020-1669, 03/2016, Volume 55, Issue 5, pp. 2460 - 2472
Electronic and photophysical characterization is presented for a series of bis-heteroleptic [Ru(bpy)(2)(R-CAQN)](+) complexes where CAQN is a bidentate... 
NON-INNOCENCE | PHOTOPHYSICS | BASIS-SET | EXCITED-STATES | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 01/2019, Volume 58, Issue 2, pp. 1627 - 1637
This work evaluated the switchable binding profile of the biochemically relevant and redox non-innocent C-organonitroso (ArNO) moiety with the selective... 
SUBSTITUTION | NON-INNOCENCE | EXCITATION-ENERGIES | LIGANDS | MOLECULAR-STRUCTURE | CRYSTAL-STRUCTURE | RUTHENIUM COMPLEXES | CHEMISTRY | DENSITY-FUNCTIONAL THEORY | ISOMER PREFERENCE | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 08/2018, Volume 57, Issue 15, pp. 9544 - 9553
Treatment of both [CoCl­( tBuPNP)] and [NiCl­( tBuPNP)] ( tBuPNP = anion of 2,5-bis­((di-tert-butylphosphino)­methyl)­pyrrole) with one equivalent of... 
NON-INNOCENCE | PNP | COUPLING REACTIONS | ZETA VALENCE QUALITY | NI COMPLEXES | ATOM-TRANSFER | BASIS-SETS | LATE TRANSITION-METALS | COMPLEXES BEARING | ELECTRONIC-STRUCTURE | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 12/2017, Volume 56, Issue 24, pp. 14900 - 14911
The impact of the {Ru­(acac)2} (acac– = acetylacetonate) framework on the transformations of C–H and C–H/C–C bonds of coordinated β-diketiminate and... 
NON-INNOCENCE | CYCLOADDITION REACTIONS | EXCITATION-ENERGIES | DIIMINE COMPLEXES | O-2 ACTIVATION | C-C BOND | SMALL-MOLECULE ACTIVATION | RUTHENIUM COMPLEXES | DENSITY-FUNCTIONAL THEORY | ELECTRONIC-STRUCTURE | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 11/2017, Volume 56, Issue 22, pp. 14084 - 14100
The new redox-noninnocent azoaromatic pincers 2-(arylazo)-1,10-phenanthroline (L1 ) and 2,9-bis­(phenyldiazo)-1,10-phenanthroline (L2 ) are reported. The... 
GALACTOSE-OXIDASE | SULFUR CLUSTERS | ALKENES SCOPE | ACTIVE TRIS(AMIDO) LIGAND | NON-INNOCENCE | TRANSITION-METAL-COMPLEXES | ANION-RADICAL COMPLEXES | ELECTRON-TRANSFER SERIES | AEROBIC OXIDATION | NICKEL(II) COMPLEXES | CHEMISTRY, INORGANIC & NUCLEAR | Usage | Iron compounds | Catalysis | Research | Chemical properties
Journal Article
Organometallics, ISSN 0276-7333, 2019, Volume 38, Issue 7, pp. 1502 - 1515
An attempt at transferring the imide of (dadi)Ti=NAd (2=NAd, dadi(2-), dadi(n) = [{-CH=N(1,2-C6H4)N(2,6-Pr-i(2)-C6H3)}(2)](n))to C2H4 led instead to low yields... 
ALKENES | NON-INNOCENCE | MECHANISM | C-C | REACTIVITY | CHEMISTRY, ORGANIC | ALPHA | IRON | METAL-COMPLEXES | DIIMINE LIGANDS | ALKYL-HALIDES | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 03/2016, Volume 55, Issue 6, pp. 3105 - 3116
Complexes of singly or doubly deprotonated indigo (H2Ind) with one or two [Ru­(pap)2]2+ fragments (pap = 2-phenylazopyridine) have been characterized... 
PSEUDOPOTENTIALS | NON-INNOCENCE | EXCITATION-ENERGIES | SPIN | DINUCLEAR RUTHENIUM | NINDIGO COMPLEXES | RUTHENIUM COMPLEXES | REDOX | DENSITY-FUNCTIONAL THEORY | METAL-COMPLEXES | CHEMISTRY, INORGANIC & NUCLEAR | Ligands | Usage | Ruthenium | Chemical properties | Electron paramagnetic resonance spectroscopy | Analysis
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 11/2014, Volume 53, Issue 21, pp. 11770 - 11777
Redox-active nitrogen donor ligands have exhibited broad utility in stabilizing transition metal complexes in unusual formal oxidation states and enabling... 
NEGISHI CROSS-COUPLINGS | NON-INNOCENCE | HOMOLOGOUS SERIES | METAL-METAL | NIFE HYDROGENASE | CHEMISTRY | CYCLOPENTADIENYL | ELECTRONIC-STRUCTURE | ALKYL-HALIDES | CHEMISTRY, INORGANIC & NUCLEAR | Nickel compounds | Ligands | Oxidation-reduction reaction | Chemical properties | Research | Electric properties
Journal Article
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