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Angewandte Chemie International Edition, ISSN 1433-7851, 03/2010, Volume 49, Issue 11, pp. 2041 - 2044
Attack with π electrons: Reduction of a chloroborole coordinated by an N‐heterocyclic carbene results in the formation of a carbene‐stabilized borole monoanion... 
nucleophilicity | carbenes | reduction | heterocycles | boron | Heterocycles | Boron | Reduction | Carbenes | Nucleophilicity
Journal Article
2010, 1. Aufl., ISBN 9783527324118, xvii, 447
This unique and long-awaited handbook on this important topic in the hot field of stereoselective organic synthesis covers several types of nucleophiles. Top... 
Asymmetric synthesis | Catalysis | Nucleophilic reactions | Bioconjugates | Enantioselective catalysis | Naturvetenskap | Natural Sciences | Organisk kemi | Kemi | Chemical Sciences | Organic Chemistry
Book
Tetrahedron Letters, ISSN 0040-4039, 04/2012, Volume 53, Issue 14, pp. 1830 - 1832
The relationship of the nucleophilicity of alkylamines to their basicity is explored with emphasis on steric hindrance to solvation. The equation = 1.43(−Σ + )... 
Amine basicity | Amine nucleophilicity | Physical organic chemistry | Basicity–nucleophilicity correlation | Basicity-nucleophilicity correlation | AMINES | CHEMISTRY, ORGANIC | BASE STRENGTHS | AMINOLYSIS | Ammonia | Correlation | Solvation | Mathematical analysis | Constants | Alkylamines | Basicity
Journal Article
Synthetic Communications, ISSN 0039-7911, 01/2016, Volume 46, Issue 1, pp. 63 - 72
A practical, mild, and high-yielding synthetic approach for the synthesis of unknown tetrahydropyrimidinyl substituted 3-coumarins as hybrid scaffolds,... 
13 | Catalyst-free | C NMR and nucleophilicity | MCR | Mannich reaction | tetrahydropyrimidinyl-coumarins | tetrahydropyrimidinylcoumarins | C NMRand nucleophilicity | DESIGN | C-13 NMR and nucleophilicity | CHEMISTRY, ORGANIC | INHIBITORS | MODEL | DERIVATIVES | DISCOVERY | COUMARINS
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 10/2018, Volume 57, Issue 42, pp. 13693 - 13693
The relative reactivity of a series of alkane C−H bonds towards silver, copper, and rhodium carbene complexes acting as electrophiles has been studied. In... 
nucleophilicity | metal carbene complexes | alkanes | C−H bond functionalization | electrophilicity
Journal Article
Journal of Physical Organic Chemistry, ISSN 0894-3230, 07/2008, Volume 21, Issue 7‐8, pp. 584 - 595
Journal Article
Wuli Huaxue Xuebao/ Acta Physico - Chimica Sinica, ISSN 1000-6818, 10/2014, Volume 30, Issue 11, pp. 2055 - 2062
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 04/2011, Volume 50, Issue 16, pp. 3612 - 3618
Simple and unambiguous: In the equation log k=s(E+N), the nucleophilicity N is obtained through the intercepts on the abscissa of linear log k versus E... 
nucleophilicity | solvent effects | kinetics | electrophilicity | linear free‐energy relationships | NUCLEOPHILICITY PARAMETERS | CHEMISTRY, MULTIDISCIPLINARY | DIARYLCARBENIUM IONS | REACTIVITIES | PLUS N) EQUATION | SCALE | PI-NUCLEOPHILES | linear free-energy relationships | WATER
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 10/2012, Volume 51, Issue 40, pp. 10164 - 10168
Weak nucleophiles for strong activation: The reversible activation of dihydrogen by an electron‐deficient phosphine, (C6F5)PPh2, in combination with the Lewis... 
olefin | alkenes | phosphanes | hydrogenation | frustrated Lewis pairs | HETEROLYTIC DIHYDROGEN ACTIVATION | IMINES | HYDROSILYLATION | REACTIVITY | H-2 ACTIVATION | CHEMISTRY, MULTIDISCIPLINARY | REDUCTION | SCALES | CHEMISTRY | NUCLEOPHILICITY | SILYL
Journal Article
Angewandte Chemie - International Edition, ISSN 1433-7851, 04/2011, Volume 50, Issue 16, pp. 3612 - 3618
Journal Article
Computational and Theoretical Chemistry, ISSN 2210-271X, 2012, Volume 980, pp. 49 - 55
► Nucleophilicty of 32 nitrogen nucleophiles have been calculated. ► DFT/B3LYP/6-31G (d, p) level of theory and nucleophilicity index introduced by Domingo et... 
DFT | Nucleophilicity index | Philicity | Nucleophilicity | N-nucleophiles | BAYLIS-HILLMAN REACTION | CHEMISTRY, PHYSICAL | DBU | GAS-PHASE | ELECTROPHILICITY INDEX | CHEMICAL-REACTIVITY | PI-NUCLEOPHILICITY | DENSITY-FUNCTIONAL THEORY | CATALYSTS | PARAMETER
Journal Article
Journal of Catalysis, ISSN 0021-9517, 12/2019, Volume 380, pp. 9 - 20
Renewable arenes and aromatic alcohols can be derived from lignocellulose by biorefineries, which has been considered as a sustainable alternative to replace... 
Beta zeolite | Shape selectivity | Benzylation reaction | Solid-state NMR spectroscopy | Reactant nucleophilicity
Journal Article
CHEMICAL COMMUNICATIONS, ISSN 1359-7345, 10/2019, Volume 55, Issue 78, pp. 11766 - 11769
Here we show trapping of chiral enolates with carbenium ions, Michael acceptors, and bromine. Silyl ketene aminals, disilyl acetals, and aza-enolates were... 
REACTIVITY | SCALES | NUCLEOPHILICITY | ASYMMETRIC-SYNTHESIS | CHEMISTRY, MULTIDISCIPLINARY | ALKYLATION
Journal Article
Applied Catalysis A: General, ISSN 0926-860X, 10/2015, Volume 506, pp. 126 - 133
Synthesis of formamides from the catalytic carbonylation of amines with CO is of great interest due to their wide applications of formamides as synthetic... 
Carbonylation | Amines | K 3 PO 4 | Formamides | Nucleophilicity
Journal Article
Chemical Physics Letters, ISSN 0009-2614, 2005, Volume 415, Issue 1, pp. 131 - 136
Ionic liquids are often contaminated by colored impurities. These impurities can be problematic for spectroscopic studies or for monitoring organic reactions... 
SOLVENTS | HEXAFLUOROPHOSPHATE | LUMINESCENCE | MOLTEN-SALTS | PHYSICS, ATOMIC, MOLECULAR & CHEMICAL | CHEMISTRY, PHYSICAL | NUCLEOPHILICITY | PRECURSORS | EFFICIENT | WATER
Journal Article
Angewandte Chemie International Edition in English, ISSN 0570-0833, 05/1994, Volume 33, Issue 9, pp. 938 - 957
Contrary to widely held opinion, for many reactions in organic and organometallic chemistry it is possible to define nucleophilicity and electrophilicity... 
Carbocations | Electrophilicity | Reaction mechanisms | Nucleophilicity
Journal Article
Synlett, ISSN 0936-5214, 10/2019, Volume 30, Issue 17, pp. 1971 - 1976
Abstract The origins and recent applications of acetal metathesis are discussed in the context of synthesizing polyacetals via acetal metathesis polymerization... 
cluster | acid catalysis | nucleophilicity | BIORENEWABLE DIOLS | POLYACETALS | acetal | metathesis | CHEMISTRY, ORGANIC | kinetic study | POLYMERIZATION | transacetalization | polyacetal
Journal Article
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