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1. Full Text Asymmetric Organocatalytic Direct C(sp2)H/C(sp3)H Oxidative Cross‐Coupling by Chiral Iodine Reagents
by Wu, Hua and He, Yu‐Ping and Xu, Lue and Zhang, Dong‐Yang and Gong, Liu‐Zhu
Angewandte Chemie International Edition, ISSN 1433-7851, 03/2014, Volume 53, Issue 13, pp. 3466 - 3469
An asymmetric organocatalytic direct CH/CH oxidative coupling reaction of N 1 , N 3 ‐diphenylmalonamides has been well established by using chiral... 
asymmetric catalysis | chirality | CH functionalization | cross‐coupling | organoiodine | cross-coupling | C-H functionalization | BOND FORMATION SYNTHESIS | CATALYSIS | ACTIVATION | IODOARENES | ENANTIOSELECTIVE SYNTHESIS | IN-SITU GENERATION | CHEMISTRY, MULTIDISCIPLINARY | FUNCTIONALIZATION | M-CHLOROPERBENZOIC ACID | CH functionalization | DEAROMATIZATION | OXYLACTONIZATION | Joining | Level (quantity) | Catalysis | Asymmetry | Catalysts | Iodine
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2. Full Text Nickel Catalysis Enables Oxidative C(sp2)–H/C(sp2)–H Cross‐Coupling Reactions between Two Heteroarenes
by Cheng, Yangyang and Wu, Yimin and Tan, Guangyin and You, Jingsong
Angewandte Chemie International Edition, ISSN 1433-7851, 09/2016, Volume 55, Issue 40, pp. 12275 - 12279
Nickel can be used to promote oxidative C(sp 2 )−H/C(sp 2 )−H cross‐coupling between two heteroarenes. The reaction scope can be extended to aromatic... 
heteroarenes | nickel | oxidative cross-coupling | homogeneous catalysis | synthetic methods | DIRECTING GROUP | AZOLES | ARYLATION | C-H ACTIVATION | CHEMISTRY, MULTIDISCIPLINARY | INDOLES | FUNCTIONALIZATION | BONDS | DERIVATIVES | ACCESS | COBALT | Silver | Costs | Cross coupling | Functional anatomy | Chemical reactions | Nickel | Catalysis | Coupling | Compatibility | Cost engineering
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3. Full Text Recent Advances of Oxidative Radical Cross‐Coupling Reactions: Direct α‐C(sp3)–H Bond Functionalization of Ethers and Alcohols
by Guo, Sheng‐rong and Kumar, Pailla Santhosh and Yang, Minghua
Advanced Synthesis & Catalysis, ISSN 1615-4150, 01/2017, Volume 359, Issue 1, pp. 2 - 25
Oxygen‐containing heterocycles are an important class of compounds with diverse biological activities. In recent years, direct α‐C–H functionalization of... 
H bond functionalization | ethers | alcohols | radical oxidative coupling | single eletron transfer (SET) | C(sp | C(sp)-H bond functionalization | C(SP)-H BONDS | ORGANIC-SYNTHESIS | METAL-FREE CONDITIONS | CHEMISTRY, ORGANIC | CATALYZED DIRECT THIOLATION | C-H BONDS | ACTIVATED ALKENES | ALPHA-OXOCARBOXYLIC ACIDS | OXYGEN-ATOMS | CYCLIC ETHERS | CHEMISTRY, APPLIED | CARBOXYLIC-ACIDS | Carbon-carbon composites | Chemical reactions | Strategy | Coupling | Ethers | Bonding | Radicals | Alcohols
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4. Full Text Direct Cross‐Coupling of Allylic C(sp3)−H Bonds with Aryl‐ and Vinylbromides by Combined Nickel and Visible‐Light Catalysis
by Huang, Long and Rueping, Magnus
Angewandte Chemie International Edition, ISSN 1433-7851, 08/2018, Volume 57, Issue 32, pp. 10333 - 10337
An efficient protocol for the direct allylic C(sp 3 )−H bond activation of unactivated tri‐ and tetrasubstituted alkenes and their functionalization with aryl‐... 
nickel | C−H activation | alkenes | photocatalysis | allylic compounds | HALIDES | ROOM-TEMPERATURE | PALLADIUM | ARYLATION | PHOTOREDOX/NICKEL DUAL CATALYSIS | 9-MESITYL-10-METHYLACRIDINIUM | OXIDATIVE ADDITION | BROMIDES | CHEMISTRY, MULTIDISCIPLINARY | C-H activation | ACETATES | DERIVATIVES | Olefins | Nickel | Catalysis | Alkenes | Regioselectivity | Hydrogen bonds | Aromatic compounds
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5. Full Text Organotrifluoroborates and monocoordinated palladium complexes as catalysts - A perfect combination for Suzuki-Miyaura coupling
by Molander, Gary A and Canturk, Belgin
Angewandte Chemie - International Edition, ISSN 1433-7851, 11/2009, Volume 48, Issue 49, pp. 9240 - 9261
Monocoordinated palladium catalysts derived from sterically hindered, electron-rich phosphines or N-heterocyclic carbenes have revolutionized the... 
Suzuki-Miyaura coupling | Cross-coupling | N-heterocycliccarbenes | Phosphines | Organotrifluoroborates | phosphines | HIGHLY EFFICIENT CATALYST | ROOM-TEMPERATURE | N-HETEROCYCLIC CARBENE | GENERATED IN-SITU | HINDERED ARYL CHLORIDES | CHEMISTRY, MULTIDISCIPLINARY | ARYLBORONIC ACIDS | CROSS-COUPLINGS | cross-coupling | OXIDATIVE-ADDITION | CARBON-CARBON | HETEROARYL BORONIC ACIDS | organotrifluoroborates | Phosphines - chemistry | Organic Chemicals - chemistry | Ligands | Molecular Structure | Catalysis | Borates - chemistry | Fluorine Compounds - chemistry | Palladium - chemistry | Suzuki–Miyaura coupling
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6. Full Text Nickel-catalysed Suzuki-Miyaura coupling of amides
by Weires, Nicholas A and Baker, Emma L and Garg, Neil K
Nature Chemistry, ISSN 1755-4330, 01/2016, Volume 8, Issue 1, pp. 75 - 79
The Suzuki-Miyaura coupling has become one of the most important and prevalent methods for the construction of C-C bonds. Although palladium catalysis has... 
ACTIVATION | CLEAVAGE | CHEMISTRY, MULTIDISCIPLINARY | ESTERS | Nickel - chemistry | Ketones - chemical synthesis | Ketones - chemistry | Oxidative Coupling | Amides - chemistry | Molecular Structure | Catalysis
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7. Full Text Metal‐Free Formal Oxidative C−C Coupling by In Situ Generation of an Enolonium Species
by Kaiser, Daniel and de la Torre, Aurélien and Shaaban, Saad and Maulide, Nuno
Angewandte Chemie International Edition, ISSN 1433-7851, 05/2017, Volume 56, Issue 21, pp. 5921 - 5925
Much contemporary organic synthesis relies on transformations that are driven by the intrinsic, so‐called “natural”, polarity of chemical bonds and reactive... 
oxidative C−C coupling | chemoselectivity | keteniminium ions | amide activation | umpolung | ELECTROPHILIC ACTIVATION | PYRIDINE-DERIVATIVES | BOND FUNCTIONALIZATION | ANION RELAY CHEMISTRY | CHEMOSELECTIVE SYNTHESIS | TRIFLIC ANHYDRIDE | CHEMISTRY, MULTIDISCIPLINARY | ORGANOCATALYTIC SOMO REACTIONS | SECONDARY AMIDES | DIRECT TRANSFORMATION | oxidative C-C coupling | HYPERVALENT IODINE REAGENTS
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8. Full Text Visible light-mediated gold-catalysed carbon(sp2)-carbon(sp) cross-coupling
by Kim, Suhong and Rojas-Martin, Jaime and Toste, F. Dean
Chemical Science, ISSN 2041-6520, 01/2016, Volume 7, Issue 1, pp. 85 - 88
A dual photoredox and gold-catalysed cross-coupling reaction of alkynyltrimethylsilanes and aryldiazonium tetrafluoroborates is described. The reaction... 
ARYLDIAZONIUM SALTS | ARENEDIAZONIUM SALTS | SONOGASHIRA | ARYL IODIDES | SINGLE-ELECTRON TRANSMETALATION | OXIDATIVE ADDITION | REDUCTIVE ELIMINATION | NONACTIVATED ARENES | DIRECT ALKYNYLATION | CHEMISTRY, MULTIDISCIPLINARY | PHOTOREDOX CATALYSIS | Chemical reactions | Cross coupling | Selectivity | Terminals | Alkynes
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9. Full Text A Regio‐ and Diastereoselective Anodic Aryl–Aryl Coupling in the Biomimetic Total Synthesis of (−)‐Thebaine
by Lipp, Alexander and Ferenc, Dorota and Gütz, Christoph and Geffe, Mario and Vierengel, Nina and Schollmeyer, Dieter and Schäfer, Hans J and Waldvogel, Siegfried R and Opatz, Till
Angewandte Chemie International Edition, ISSN 1433-7851, 08/2018, Volume 57, Issue 34, pp. 11055 - 11059
The biosynthesis of thebaine is based on the regioselective, intramolecular, oxidative coupling of ( R )‐reticuline. For decades, chemists have sought to mimic... 
electrochemistry | thebaine | biomimetic synthesis | alkaloids | morphine | DEPROTONATED ALPHA-AMINONITRILE | PRACTICAL SYNTHESIS | ENANTIOSELECTIVE SYNTHESIS | FORMAL TOTAL-SYNTHESIS | CHEMISTRY, MULTIDISCIPLINARY | MORPHINANDIENONE ALKALOIDS | PHENOL OXIDATION | OPIUM-ALKALOIDS | ELECTROOXIDATIVE CYCLIZATION | MORPHINE ALKALOIDS | HETEROCYCLIC-COMPOUNDS | Electrochemistry | Electrochemical reactions | Morphine | Synthesis | Biomimetics | Organic compounds | Stereoselectivity | Organic chemistry | Oxidants | Aromatic compounds | Oxidizing agents | Chemists | Biosynthesis | Coupling
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10. Full Text Recent Advances in Functionalization of α‐C(sp3)–H Centres in Inactivated Ethers through Cross Dehydrogenative Coupling
by Batra, Aanchal and Singh, Paramjit and Singh, Kamal Nain
European Journal of Organic Chemistry, ISSN 1434-193X, 07/2017, Volume 2017, Issue 26, pp. 3739 - 3762
Carbon–carbon and carbon–heteroatom bond construction through oxidative carbon–hydrogen bond activation has attracted much attention in synthetic organic... 
C–H activation | C–C, C–X bond formation | Radical reactions | Cross‐coupling | C–H activation/functionalization | Cross dehydrogenative coupling | Reaction mechanisms | Saturated cyclic and acyclic ethers | Cross-coupling | C-H activation/ functionalization | C(SP)-H BONDS | METAL-FREE CONDITIONS | MINISCI REACTION | OXIDATIVE ACTIVATION | CHEMISTRY, ORGANIC | DIRECT ACCESS | N-OXIDES | C-H BONDS | CINNAMIC-ACIDS | C-H activation | C-C, C-X bond formation | CYCLIC ETHERS | DIRECT ALPHA-ARYLATION
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