X
Search Filters
Format Format
Subjects Subjects
Subjects Subjects
X
Sort by Item Count (A-Z)
Filter by Count
phosphaalkenes (392) 392
chemistry, inorganic & nuclear (172) 172
chemistry (146) 146
phosphorus (132) 132
chemistry, organic (115) 115
phosphaalkene (111) 111
chemistry, multidisciplinary (106) 106
complexes (88) 88
reactivity (83) 83
coordinated phosphorus-compounds (55) 55
ligands (52) 52
crystal-structure (32) 32
heterocycles (32) 32
phosphorus-compounds (31) 31
iron (30) 30
phosphorus heterocycles (30) 30
phosphaalkynes (29) 29
tungsten (29) 29
coordination chemistry (28) 28
bond (27) 27
derivatives (27) 27
bonds (25) 25
carbenes (25) 25
chemical sciences (23) 23
isomerization (23) 23
organophosphorus compounds (22) 22
phosphor (22) 22
crystal structure (21) 21
palladium (21) 21
density functional calculations (20) 20
diphosphenes (20) 20
natural sciences (20) 20
naturvetenskap (20) 20
polymers (20) 20
gold (19) 19
multiple bonds (19) 19
coordination (18) 18
ligand (18) 18
arsaalkenes (17) 17
bearing diphosphinidenecyclobutene ligands (17) 17
kemi (17) 17
adducts (16) 16
double-bond (16) 16
molybdenum (16) 16
systems (16) 16
complex (14) 14
conjugated polymers (14) 14
insertion (14) 14
organic chemistry (14) 14
phosphines (14) 14
alkenes (13) 13
conjugation (13) 13
main-group elements (13) 13
phosphorus ylides (13) 13
route (13) 13
spectroscopy (13) 13
aromaticity (12) 12
carbon (12) 12
catalysis (12) 12
diphosphene (12) 12
inorganic chemistry (12) 12
molecules (12) 12
platinum (12) 12
ylides (12) 12
alkylidenephosphines (11) 11
behavior (11) 11
cycloaddition (11) 11
mathematical analysis (11) 11
nmr spectra (11) 11
p=c bond (11) 11
phosphaalkyne (11) 11
x-ray (11) 11
x-ray crystallography (11) 11
x-ray diffraction (11) 11
analysis (10) 10
chemical properties (10) 10
chemistry, physical (10) 10
crystallography (10) 10
elements (10) 10
highly-active catalysts (10) 10
n-heterocyclic carbenes (10) 10
p pi-systems (10) 10
phosphinidene (10) 10
sulfur (10) 10
ab initio calculations (9) 9
alkynes (9) 9
carben (9) 9
e = cpi-systems (9) 9
main group elements (9) 9
molecular structure (9) 9
molecular-structure (9) 9
alkylation (8) 8
anionic-polymerization (8) 8
chromium (8) 8
cycloadditions (8) 8
density (8) 8
dft calculations (8) 8
diphosphanes (8) 8
ethylene polymerization (8) 8
oligomers (8) 8
more...
Language Language
Publication Date Publication Date
Click on a bar to filter by decade
Slide to change publication date range


Heteroatom Chemistry, ISSN 1042-7163, 12/2018, Volume 29, Issue 5-6
Journal Article
Chemical Communications, ISSN 1359-7345, 2017, Volume 53, Issue 54, pp. 7620 - 7623
The parent phosphinidene SIMesPH (1) (SIMes = 1,3-bis(2,4,6-trimethylphenyl) imidazolin-2-ylidene) was treated with benzyl potassium to form the metalated... 
PHOSPHAALKENES | CHEMISTRY, MULTIDISCIPLINARY | NMR CHEMICAL-SHIFTS
Journal Article
Phosphorus, Sulfur and Silicon and the Related Elements, ISSN 1042-6507, 03/2016, Volume 191, Issue 3, pp. 430 - 437
Journal Article
European Journal of Inorganic Chemistry, ISSN 1434-1948, 2016, Volume 2016, Issue 26, pp. 4144 - 4151
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 07/2002, Volume 41, Issue 13, pp. 2389 - 2392
An unprecedented yellow polymer with low‐coordinate phosphorus atoms in the backbone has been prepared. The material is soluble in polar organic solvents, and... 
silicon | phosphaalkenes | polymers | conjugation | phosphorus | Phosphorus | Phosphaalkenes | Silicon | Conjugation | Polymers
Journal Article
European Journal of Inorganic Chemistry, ISSN 1434-1948, 03/2004, Volume 2004, Issue 5, pp. 998 - 1006
Sterically‐encumbered ligands tethered to conjugated segments have been developed and employed in concert with existing bulky ligands to prepare a series of... 
Oligomers | Phosphorus | Phosphaalkenes
Journal Article
European Journal of Inorganic Chemistry, ISSN 1434-1948, 02/2016, Volume 2016, Issue 5, pp. 685 - 690
The reaction of Li/Cl phosphinidenoid tungsten(0) complex 2 [R = CH(SiMe3)(2)] with 1,3,4,5-tetramethylimidazol-2-yl-idene (3) yielded the zwitterionic... 
Phosphorus | Phosphaalkenes | Density functional calculations | Carbenes | Tungsten | DESIGN | INVERSELY POLARIZED PHOSPHAALKENES | BEHAVIOR | SCF THEORY | CHEMISTRY, INORGANIC & NUCLEAR | ELEMENTS | AROMATICITY | CHEMISTRY | BOND ORDER | VALENCE | INDEPENDENT CHEMICAL-SHIFTS
Journal Article
Phosphorus, Sulfur, and Silicon and the Related Elements, ISSN 1042-6507, 03/2016, Volume 191, Issue 3, pp. 430 - 437
The dehydrochlorination of the dichlorophosphane (iPrMe 2 Si) 2 C(H)PCl 2 (2) with 1,4-diazabicyclo[2.2.2]octane (DBO) provides the P-chlorophosphaalkene... 
X-ray crystallography | P-halogeno phosphaalkenes | P-NMR | P-seleno phosphaalkenes | P-cyano phosphaalkenes | ALKENES | P-31-NMR | BONDS | CHEMISTRY, ORGANIC | METAL | SPECTRUM | ACYL | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Chemical Communications: Chem Comm, ISSN 1359-7345, 07/2017, Volume 53, Issue 54, pp. 7620 - 7623
The parent phosphinidene SIMesPH (1) (SIMes = 1,3-bis(2,4,6-trimethylphenyl)imidazolin-2-ylidene) was treated with benzyl potassium to form the metalated... 
Cage compounds | Potassium | Parents
Journal Article
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, ISSN 1434-1948, 09/2007, Issue 26, pp. 4095 - 4117
Phosphinidenes (phosphanylidenes) (RP) are electronically and coordinatively unsaturated phosphorus compounds, which, as six-electron species, are formally... 
R-AS=C(NME2) R | CARBON DOUBLE-BOND | phosphinidene | INVERSELY POLARIZED PHOSPHAALKENES | METAL-SUBSTITUTED PHOSPHAALKENES | PHOSPHORUS ANALOGS | TERMINAL-PHOSPHINIDENE | phosphaalkenes | WITTIG REAGENTS | TUNGSTEN COMPLEXES | RP=C(NME2) R | RAY CRYSTAL-STRUCTURE | CHEMISTRY, INORGANIC & NUCLEAR | arsinidene | arsaalkenes
Journal Article
ChemPlusChem, ISSN 2192-6506, 11/2019, Volume 84, Issue 11, pp. 1761 - 1766
Butadiene is the simplest neutral acyclic closed‐shell π‐conjugated system and is typically sufficiently stable enough to avoid electrocyclization to... 
steric effects | phosphaalkenes | electrocyclic reactions | cyclobutenes | density functional theory
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 06/2017, Volume 53, Issue 45, pp. 6069 - 6072
N-Heterocyclic carbene adducts of the parent arsinidene (AsH) were prepared by two different synthetic routes, either by reaction of As(SiMe ) with... 
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 07/2013, Volume 52, Issue 27, pp. 6967 - 6970
Unique pathway: The radical‐initiated addition polymerization of MesP=CPh2 propagates through the ortho‐bound CH3 group of the Mes moiety after CH bond... 
inorganic polymers | CH activation | phosphaalkenes | radical polymerization | phosphorus | C-H activation
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 04/2019, Volume 25, Issue 19, p. n/a
NHC stabilized phosphinidenide complexes are formed in reactions between the insoluble, NHC stabilized phosphenidenide (SIMesPK) with different soluble... 
phosphinidenides | potassium | phosphaalkenes | carbene ligands | phosphorus | Potassium salts | Gambling | Salts | Tin | Lead | Germanium | Phosphorus | Potassium
Journal Article
Dalton Transactions, ISSN 1477-9226, 2019, Volume 48, Issue 11, pp. 3547 - 3550
Reaction of AsCl3 with Pt(0) complexes [Pt(PCy3)(2)], [Pt(PCy3)(IMes)] and [Pt(IMes)(2)] (IMes = 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene) resulted in... 
D-BLOCK | COMPLEXES | REACTIVITY | CHEMISTRY | COORDINATION | BISMUTH | BOND | PHOSPHAALKENES | ANTIMONY | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Organometallics, ISSN 0276-7333, 11/2010, Volume 29, Issue 21, pp. 4778 - 4780
The lithiated N-heterocyclic carbene−phosphinidene adduct L′:P−H (3; L′: = :C{[N(2,6-Pri 2C6H3)]2CHCLi(THF)3}) unexpectedly resulted from the reaction of... 
DENSITY | PHOSPHORUS | COMPLEXES | CHEMISTRY | CHEMISTRY, ORGANIC | ADDUCTS | N-HETEROCYCLIC CARBENES | PHOSPHAALKENES | DOUBLE-BOND | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
CHEMICAL COMMUNICATIONS, ISSN 1359-7345, 12/2019, Volume 55, Issue 97, pp. 14669 - 14672
The first terminal arsinidene complexes [{(NHC)C(Ph)}As]Fe(CO)(4) (NHC = IPr = C{(NDipp)CH}(2)5, Me-IPr = C{(NDipp)CMe}(2)6; Dipp = 2,6-iPr(2)C(6)H(3)) with a... 
ELEMENTS | SINGLE | REACTIVITY | TUNGSTEN | IRON | METAL-SUBSTITUTED ARSAALKENES | MULTIPLE BONDS | PHOSPHAALKENES | CHROMIUM | CHEMISTRY, MULTIDISCIPLINARY | PHOSPHINIDENE COMPLEXES
Journal Article
Chemical Communications, ISSN 1359-7345, 2017, Volume 53, Issue 45, pp. 6069 - 6072
N-Heterocyclic carbene adducts of the parent arsinidene (AsH) were prepared by two different synthetic routes, either by reaction of As(SiMe3)(3) with... 
PHOSPHINIDENE | ARSAALKENES | PENTACARBONYL | COMPLEXES | MULTIPLE BONDS | PHOSPHAALKENES | MAIN-GROUP ELEMENTS | TRANSITION-METALS | DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY | INDUCED DEGRADATION | Carbenes | Ashes | Chlorides | Parents | Adducts
Journal Article
Macromolecules, ISSN 0024-9297, 04/2018, Volume 51, Issue 7, pp. 2621 - 2629
We report that the anionic polymerization of P-mesityl and m-xylyl-substituted phosphaalkenes follows an unusual addition–isomerization mechanism.... 
MONOMERS | POLYMER SCIENCE | BLOCK-COPOLYMERS | BEHAVIOR | PHOSPHINE POLYMERS | P=C BONDS | ACRYLAMIDE | CARBON-CARBON BONDS | PHOSPHAALKENES | EXCHANGE | HYDROGEN-TRANSFER POLYMERIZATION
Journal Article
Heteroatom Chemistry, ISSN 1042-7163, 12/2018, Volume 29, Issue 5-6, pp. e21474 - n/a
We report the attempted synthesis of a “masked” phosphaalkene by treating MgA·3THF (A = anthracenide) with MesPCl(CH2Cl). Although the desired “masked”... 
“masked” phosphaalkene | polymers | phosphaalkene | phosphorus | DISILENES | ANIONIC-POLYMERIZATION | COMPLEXES | STYRENE | COPOLYMERS | CHEMISTRY, MULTIDISCIPLINARY | RAY CRYSTAL-STRUCTURE | "masked" phosphaalkene | ISOMERIZATION POLYMERIZATION | STABLE COMPOUND | GENERATION | 7-PHOSPHANORBORNADIENES
Journal Article
No results were found for your search.

Cannot display more than 1000 results, please narrow the terms of your search.