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phosphaalkenes (393) 393
chemistry, inorganic & nuclear (175) 175
chemistry (149) 149
phosphorus (134) 134
chemistry, organic (117) 117
phosphaalkene (115) 115
chemistry, multidisciplinary (109) 109
complexes (90) 90
reactivity (84) 84
coordinated phosphorus-compounds (56) 56
ligands (52) 52
phosphorus-compounds (33) 33
crystal-structure (32) 32
heterocycles (31) 31
iron (30) 30
phosphorus heterocycles (30) 30
coordination chemistry (29) 29
phosphaalkynes (29) 29
tungsten (29) 29
bond (27) 27
derivatives (27) 27
carbenes (26) 26
bonds (25) 25
chemical sciences (23) 23
isomerization (23) 23
organophosphorus compounds (23) 23
crystal structure (22) 22
palladium (22) 22
phosphor (22) 22
diphosphenes (21) 21
density functional calculations (20) 20
natural sciences (20) 20
naturvetenskap (20) 20
bearing diphosphinidenecyclobutene ligands (19) 19
double-bond (19) 19
gold (19) 19
multiple bonds (19) 19
polymers (19) 19
ligand (18) 18
arsaalkenes (17) 17
conjugated polymers (17) 17
coordination (17) 17
kemi (17) 17
adducts (16) 16
molybdenum (16) 16
main-group elements (15) 15
organic chemistry (15) 15
phosphines (15) 15
systems (15) 15
complex (14) 14
insertion (14) 14
route (14) 14
alkenes (13) 13
conjugation (13) 13
highly-active catalysts (13) 13
phosphorus ylides (13) 13
spectroscopy (13) 13
aromaticity (12) 12
carbon (12) 12
catalysis (12) 12
diphosphene (12) 12
inorganic chemistry (12) 12
molecules (12) 12
platinum (12) 12
ylides (12) 12
alkylidenephosphines (11) 11
behavior (11) 11
cycloaddition (11) 11
mathematical analysis (11) 11
nmr spectra (11) 11
phosphaalkyne (11) 11
x-ray (11) 11
x-ray crystallography (11) 11
x-ray diffraction (11) 11
analysis (10) 10
chemical properties (10) 10
chemistry, physical (10) 10
crystallography (10) 10
molecular-structure (10) 10
n-heterocyclic carbenes (10) 10
p pi-systems (10) 10
phosphinidene (10) 10
sulfur (10) 10
ab initio calculations (9) 9
alkynes (9) 9
carben (9) 9
e = cpi-systems (9) 9
elements (9) 9
main group elements (9) 9
molecular structure (9) 9
p=c bond (9) 9
polymerization (9) 9
stabilization (9) 9
alkylation (8) 8
anionic-polymerization (8) 8
chromium (8) 8
crystal (8) 8
cycloadditions (8) 8
density (8) 8
dft calculations (8) 8
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Inorganic Chemistry, ISSN 0020-1669, 07/2013, Volume 52, Issue 13, pp. 7811 - 7816
An atom-economical synthesis of arsaalkenes via a net coupling of aryl arsines with aryl or alkyl isocyanides at zirconium is presented. Reaction of zirconium... 
LIGANDS | CARBON MULTIPLE BONDS | INSERTION REACTIONS | COMPLEXES | PHOSPHORUS-CARBON | REACTIVITY | PHOSPHAALKENES | MAIN-GROUP ELEMENTS | CHEMISTRY, INORGANIC & NUCLEAR | Isocyanates | Zirconium | Chemical properties | Chemical synthesis | Analysis | Olefins
Journal Article
Angewandte Chemie - International Edition in English, ISSN 0570-0833, 09/1981, Volume 20, Issue 9, pp. 731 - 744
Journal Article
Angewandte Chemie International Edition in English, ISSN 0570-0833, 09/1981, Volume 20, Issue 9, pp. 731 - 744
Just as the octet rule had prevented the discovery of the inert‐gas compounds, the systematic search for phosphorus‐carbon‐ and phosphorus‐nitrogen‐compounds... 
Phosphaalkenes | Multiple bonds | Bond theory | Phosphorus–carbon compounds | Phosphaalkynes
Journal Article
Zeitschrift für Naturforschung B, ISSN 0932-0776, 12/1985, Volume 40, Issue 12, pp. 1698 - 1702
Treatment of the cationic complexes [(η -C Me )M(CO) BF (M = Fe, Ru) (1a , b) with the bulky lithium silyl phosphide LiP(Ar')(SiMe ) (Ar' =... 
Iron Com plexes | Metal Substituted Phosphaalkenes | Ruthenium Com plexes
Journal Article
Zeitschrift für Naturforschung B, ISSN 0932-0776, 08/1985, Volume 40, Issue 8, pp. 1077 - 1086
Aliphatic diazo compounds display different reactivity towards the phosphaalkene 9: diazomethane, diazoethane and terf-butyl diazoacetate (10a-c) formally... 
o-Quinones | Cycloaddition to a Phosphaalkene | Phospholes | 1,3-Dipoles
Journal Article
Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences, ISSN 0932-0776, 08/1985, Volume 40, Issue 8, pp. 1077 - 1086
Journal Article
Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences, ISSN 0932-0776, 02/1986, Volume 41, Issue 2, pp. 149 - 161
Journal Article
Zeitschrift für Naturforschung B, ISSN 0932-0776, 02/1986, Volume 41, Issue 2, pp. 149 - 161
The reactions o f the perfluorophosphaalkene F CP = CF (1) with HX compounds proceed via addition to the PC double bond yielding either secondary phosphanes F... 
New Chiral CF3 Substituted Phosphanes | Phosphaalkenes | NMR Spectra | Mass Spectra | HX Addition to F3CP = CF2
Journal Article
Zeitschrift für Naturforschung B, ISSN 0932-0776, 09/1986, Volume 41, Issue 9, pp. 1096 - 1106
Treatment of (η -C Me )(CO)) RuP(SiMe (3) with mesitoyl chloride (MesC(O)Cl) leads to the phosphaalkenyl complex (Z )-(η -C Me )(CO) Ru-P = C (OSiMe )(Mes)... 
Ruthenium Substituted Phosphaalkenes | Diacylphosphido Complexes
Journal Article
Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences, ISSN 0932-0776, 11/1988, Volume 43, Issue 11, pp. 1475 - 1477
Journal Article
Zeitschrift für Naturforschung B, ISSN 0932-0776, 11/1988, Volume 43, Issue 11, pp. 1475 - 1477
Lithium triphenylsilyl-phenylphosphide (3), X = SiPh , reacts with ketones to give tetraphenyl-phospholanes (6). In an initial step a phosphaalkene 5 is... 
Phosphorus Heterocycles | Silyl-and Stannylphosphides Phosphaalkenes | Reversible Nucleophilic Degradation
Journal Article
Chemische Berichte, ISSN 0009-2940, 1990, Volume 123, Issue 12, pp. 2317 - 2320
Reactive EC(p‐p)π‐Systems, XXVI. — Facile Synthesis of Phosphaalkenes of the Type HPC(F)NR2 and the Phosphaalkyne PC‐N(iPr)2 The reaction of... 
Trifluoromethylphosphane/Phosphaalkenes, fluoro‐/Phosphaalkyne, amino
Journal Article
CHEMISCHE BERICHTE, ISSN 0009-2940, 12/1990, Volume 123, Issue 12, pp. 2317 - 2320
The reaction of trifluoromethylphosphane CF3PH2 with secondary amines in a 1:3 molar ratio leads to the novel methylenephosphanes (phosphaalkenes) HP = C(F)NR2... 
PHOSPHAALKENES, FLUOROALKENES | SPECTROSCOPY | CHEMISTRY | TRIFLUOROMETHYLPHOSPHANE | COORDINATION | SYSTEMS | PHOSPHAALKYNE, AMINOALKENES | PHOSPHORUS-COMPOUNDS
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 1991, Volume 32, Issue 30, pp. 3687 - 3690
Journal Article
Chemische Berichte, ISSN 0009-2940, 1991, Volume 124, Issue 3, pp. 417 - 421
Electrochemical investigations on a selection of methylenephosphines 1 and related systems are reported. They are shown to possess an irreversible oxidation... 
Voltammetry, cyclic | Methylenephosphines | OXIDATION | PHOSPHORUS | MOLECULAR-STRUCTURE | CRYSTAL-STRUCTURE | PLATINUM | PHOSPHAALKENES | ETA-2-PHOSPHAALKENE NICKEL-COMPLEX | ACYLPHOSPHINES | VOLTAMMETRY, CYCLIC | CHEMISTRY | SPECTRA | BOND | METHYLENEPHOSPHINES
Journal Article
Chemische Berichte, ISSN 0009-2940, 1991, Volume 124, Issue 3, pp. 493 - 496
New σ2λ3‐PC – O Systems: Stable Non‐Conjugated Phosphaalkene Ethers – Synthesis and Reactivity Non‐conjugated cyclic phosphaalkene ethers (2, 4, 6) are... 
Phosphaalkene ethers | 1,3‐Oxaphosphorines, tetrahydro | 1,3‐Oxaphospholes, dihydro
Journal Article
Phosphorus, Sulfur, and Silicon and the Related Elements, ISSN 1042-6507, 01/1991, Volume 55, Issue 1-4, pp. 133 - 136
C-Trimethylsiloxy substituted phosphaalkene 1 reacts exothermically with diphenylchloroborane. The expected spontaneous 1,3-eIimination of... 
Phosphaalkene | diphenylchloroborane | phosphaalkyne
Journal Article
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