X
Search Filters
Format Format
Subjects Subjects
Subjects Subjects
X
Sort by Item Count (A-Z)
Filter by Count
chemistry, inorganic & nuclear (304) 304
chemistry, multidisciplinary (216) 216
chemistry (195) 195
phosphinidene (186) 186
reactivity (170) 170
chemistry, organic (166) 166
phosphorus (157) 157
phosphinidene complexes (147) 147
ligands (118) 118
phosphinidenes (88) 88
complexes (79) 79
ray crystal-structure (74) 74
crystal-structure (72) 72
terminal phosphinidene complexes (58) 58
tungsten (56) 56
derivatives (50) 50
ligand (50) 50
transition-metal-complexes (49) 49
bond (48) 48
molecular-structure (47) 47
molybdenum (45) 45
terminal-phosphinidene (44) 44
coordination chemistry (43) 43
terminal-phosphinidene complexes (43) 43
terminal phosphinidene (41) 41
chemical properties (40) 40
stabilization (38) 38
analysis (34) 34
carbenes (34) 34
main-group elements (34) 34
activation (33) 33
adducts (32) 32
density functional calculations (32) 32
insertion (31) 31
multiple bonds (31) 31
p ligands (31) 31
phosphorus analogs (31) 31
clusters (29) 29
phosphor (29) 29
ruthenium (29) 29
tungsten complexes (29) 29
phosphinidene complex (28) 28
phosphorus heterocycles (28) 28
bonding (27) 27
generation (27) 27
double-bond (26) 26
heterocycles (26) 26
phosphaalkenes (26) 26
crystal structure (25) 25
research (25) 25
crystal (24) 24
ring (23) 23
electronic-structure (22) 22
carbene-like chemistry (21) 21
catalysis (21) 21
coordination compounds (21) 21
iron (21) 21
crystal-structures (20) 20
index medicus (20) 20
rearrangement (20) 20
terminal phosphinidene complex (20) 20
c-h activation (19) 19
k ec chemistry, inorganic & nuclear (19) 19
zirconium (19) 19
chemical bonds (18) 18
cluster (18) 18
metal-complexes (18) 18
molecular structure (18) 18
p-rich phosphanes (18) 18
carbene (17) 17
chemistry, physical (17) 17
cycloaddition (17) 17
elements (17) 17
n-heterocyclic carbenes (17) 17
diphosphenes (16) 16
phosphido (16) 16
ab-initio (15) 15
actinide phosphinidene complexes (15) 15
aminophosphinidene complexes (15) 15
cleavage (15) 15
cobalt (15) 15
crystallography (15) 15
density-functional theory (15) 15
k ee chemistry, organic (15) 15
molecular-structures (15) 15
nmr spectroscopy (15) 15
organophosphorus compounds (15) 15
phosphido complexes (15) 15
spectroscopy (15) 15
transition-metals (15) 15
chemical synthesis (14) 14
density (14) 14
mathematical analysis (14) 14
nickel (14) 14
p-h (14) 14
phosphorus triple bond (14) 14
ray crystal-structures (14) 14
synthesis (14) 14
titanium complexes (14) 14
x-ray (14) 14
more...
Language Language
Publication Date Publication Date
Click on a bar to filter by decade
Slide to change publication date range


Chemistry – A European Journal, ISSN 0947-6539, 09/2019, Volume 25, Issue 49, pp. 11422 - 11426
Chalcogen‐bonded silicon phosphinidenes LSi(E)−P−MecAAC (E=S (1); Se (2); Te (3); L=PhC(NtBu)2; MecAAC=C(CH2)(CMe2)2N‐2,6‐iPr2C6H3)) were synthesized from the... 
silylene–phosphinidene | phosphinidenes | silicon | chalcogens | phosphorus | CARBENE | SERIES | COMPLEXES | CHEMISTRY | silylene-phosphinidene | CHEMISTRY, MULTIDISCIPLINARY | TERMINAL PHOSPHINIDENE | Analysis | Silicon | Regeneration | Molecular orbitals | Nuclear magnetic resonance--NMR | Chemical synthesis | Tellurium | Communications | Communication
Journal Article
CHEMICAL COMMUNICATIONS, ISSN 1359-7345, 03/2018, Volume 54, Issue 21, pp. 2659 - 2661
Herein, we present the synthesis and characterisation of new group 15 element compounds with low valent phosphorus atoms as substituents. This new series of... 
ELEMENTS | SINGLE | ADDUCTS | CHEMISTRY, MULTIDISCIPLINARY | PHOSPHINIDENE COMPLEXES | TERMINAL PHOSPHINIDENE | QUEST | Bismuth | Antimony | Synthesis
Journal Article
Chemical Communications, ISSN 1359-7345, 2016, Volume 52, Issue 45, pp. 7280 - 7283
A new imine-stabilized carboranyl-phosphinidene has been synthesized and structurally characterized. DFT studies suggest that the imine moiety provides an... 
PHOSPHORUS | X-RAY-STRUCTURE | CHEMISTRY | TERMINAL-PHOSPHINIDENE | CHEMISTRY, MULTIDISCIPLINARY | PHOSPHINIDENE COMPLEXES | ACCESS | HETEROCYCLIC CARBENE ADDUCTS
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 10/2018, Volume 140, Issue 42, pp. 13604 - 13608
A rare oxyphosphinidene (MeOP) has been generated in the triplet ground state through either photolysis (266 nm) or flash-vacuum pyrolysis (FVP, 700 °C) of... 
ELECTRON-SPIN-RESONANCE | PHOSPHINIDENE OXIDE | SPECTROSCOPY | TRIPLET MESITYLPHOSPHINIDENE | COMPLEXES | REACTIVITY | DECOMPOSITION | NUCLEOPHILIC PHOSPHINIDENE | MATRIX-ISOLATION | CHEMISTRY, MULTIDISCIPLINARY | TRANSFER AGENT
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 12/2018, Volume 57, Issue 50, pp. 16329 - 16333
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 06/2018, Volume 140, Issue 24, pp. 7466 - 7470
A room-temperature-stable crystalline phosphanorcaradiene 2 has been synthesized via a C–C bond forming strategy induced by the demetalation of a... 
1ST ISOLATED EXAMPLES | REARRANGEMENT | NORCARADIENE | PHOSPHORUS ANALOGS | AB-INITIO | CHEMISTRY | CARBENE-PHOSPHINIDENE | BENZENE OXIDE | TAUTOMERISM | CHEMISTRY, MULTIDISCIPLINARY | TERMINAL-PHOSPHINIDENE COMPLEXES
Journal Article
Chemical Communications, ISSN 1359-7345, 2018, Volume 54, Issue 97, pp. 13694 - 13697
Here we report the photochemical reactions of triplet phenylphosphinidene with carbon monoxide and nitric oxide. The photolysis of phenylphosphirane in carbon... 
REAGENT | REACTIVITY | GENERATION | ANALOG | CHEMISTRY, MULTIDISCIPLINARY | PHOSPHINIDENE COMPLEXES
Journal Article
Journal Article
Chemical Communications: Chem Comm, ISSN 1359-7345, 05/2016, Volume 52, Issue 45, pp. 7280 - 7283
A new imine-stabilized carboranyl-phosphinidene has been synthesized and structurally characterized. DFT studies suggest that the imine moiety provides an... 
Single crystals | Synthesis | Imines | X-rays | Ligands | Formations | NMR spectroscopy | Dimerization
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 05/2015, Volume 137, Issue 19, pp. 6366 - 6372
The synthesis of the first heteroleptic, two-coordinate Fe-I complex IPr-Fe-N(SiMe3)DIPP (1) (IPr = , 1,3-2bis(2,6-diisopropylphenyl)imidazol-2-ylidene; DIPP =... 
IMIDO COMPLEXES | OXIDATION | PHOSPHINIDENE | NI(I) | AMIDO COMPLEXES | LINEAR IRON(I) | REACTIVITY | CHEMISTRY | CYCLOTRIMERIZATION | COORDINATE | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Coordination Chemistry Reviews, ISSN 0010-8545, 12/2017, Volume 353, pp. 142 - 158
Journal Article
Coordination Chemistry Reviews, ISSN 0010-8545, 01/2017, Volume 330, pp. 1 - 36
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 05/2017, Volume 56, Issue 22, pp. 6236 - 6240
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 06/2016, Volume 52, Issue 55, pp. 8593 - 8595
The synthesis of 1,2-oxaphosphetane complexes and 1,2-oxaphospholane complex bearing only substituents at phosphorus is reported using the reaction of Li/Cl... 
Journal Article
Nature Communications, ISSN 2041-1723, 07/2015, Volume 6, Issue 1, p. 7492
Single-molecule magnets are a type of coordination compound that can retain magnetic information at low temperatures. Single-molecule magnets based on... 
SYMMETRY | CLUSTERS | PHOSPHINIDENE COMPLEX | MULTIDISCIPLINARY SCIENCES | REACTIVITY | ION MAGNETS | RELAXATION | ASTERISK | BLOCKING | ANISOTROPY | SALTS
Journal Article
Angewandte Chemie, ISSN 0044-8249, 06/2017, Volume 129, Issue 26, pp. 7777 - 7781
The reaction of [Zr(TrenDMBS)(Cl)] [Zr1; TrenDMBS=N(CH2CH2NSiMe2But)3] with NaPH2 gave the terminal parent phosphanide complex [Zr(TrenDMBS)(PH2)] [Zr2;... 
Phosphinidene | Röntgenkristallographie | Zirconium | Agostische Wechselwirkungen | Phosphanide | Crown ethers
Journal Article