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Angewandte Chemie International Edition, ISSN 1433-7851, 07/2016, Volume 55, Issue 31, pp. 9084 - 9087
Herein, we report the palladium‐catalyzed direct arylation of unactivated aliphatic C−H bonds in free primary amines. This method takes advantage of an... 
palladium catalysis | C−H activation | directing groups | primary amines | arylation | ROOM-TEMPERATURE | C(SP)-H BONDS | PALLADIUM | NITROGEN-HETEROCYCLES | UNACTIVATED C(SP)-H | CARBON-HYDROGEN BONDS | CHEMISTRY, MULTIDISCIPLINARY | C-H BONDS | FUNCTIONALIZED MOLECULES | C-H activation | ALIPHATIC-AMINES | ETHER SYNTHESIS | Aniline | Palladium | Catalysis
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 12/2018, Volume 24, Issue 67, pp. 17838 - 17843
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 04/2016, Volume 55, Issue 17, pp. 5299 - 5303
Described is a new hydrazone‐based exo‐directing group (DG) strategy developed for the functionalization of unactivated primary β C−H bonds of aliphatic... 
amines | oxidation | palladium | C−H activation | hydrazones | Hydrazones | Oxidation | Palladium | Amines | C-H activation
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 03/2019, Volume 58, Issue 12, pp. 4002 - 4006
Journal Article
Organic Letters, ISSN 1523-7060, 11/2012, Volume 14, Issue 22, pp. 5692 - 5695
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 10/2015, Volume 21, Issue 41, pp. 14319 - 14323
Direct vicinal α,β‐difunctionalization of tertiary cyclic amines is achieved in the presence of ruthenium or iridium transition‐metal complexes featuring... 
alkylation | dehydrogenative hydrolysis | hydrogen | chelate | cyclization | TERTIARY-AMINES | BORROWING HYDROGEN | TRANSFER HYDROGENATION | CHEMISTRY, MULTIDISCIPLINARY | C-H BONDS | PRIMARY ALCOHOLS | IRIDIUM CATALYSTS | SECONDARY ALCOHOLS | SELECTIVE SYNTHESIS | CATALYZED N-ALKYLATION | CYCLIC AMINES | Hydrolysis | Hydrogen storage | Ruthenium | Amines | Dehydrogenation | Amides | Iridium | Chelates | Chemical Sciences
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 12/2017, Volume 56, Issue 49, pp. 15644 - 15648
The direct catalytic C−H amination of arenes is a powerful synthetic strategy with useful applications in pharmaceuticals, agrochemicals, and materials... 
organocatalysis | amines | arenes | photochemistry | synthetic methods | DRUG | ACIDS | FUNCTIONAL MOLECULES | ARYLATION | CHEMISTRY, MULTIDISCIPLINARY | ARENE | HETEROCYCLES | CHEMISTRY | IMIDATION | Usage | Amines | Catalysis | Drugs | Catalysts | Toluene | Amino acids | Biological activity | Aliphatic compounds | Aromatics | Agrochemicals | Amination | Aromatic compounds | Benzene | Chemical bonds | Coupling | Scaffolds
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 12/2012, Volume 134, Issue 50, pp. 20230 - 20233
An efficient Pd-catalyzed cleavage of C(sp3)–N bonds in secondary amines and a consequent C(sp2)–N and C(sp3)–N coupling process was developed. Various... 
REDUCTIVE-ELIMINATION | BENZYLIC SULFONAMIDES | NICKEL-COMPLEXES | PRIMARY ALLYLIC AMINES | HETEROCYCLIC CARBENE | CARBON-NITROGEN | CARBONYLATIVE RING EXPANSION | OXIDATIVE-ADDITION | ETA(N,C)-PYRIDINE COMPLEX | TERMINAL ALKYNES | CHEMISTRY, MULTIDISCIPLINARY | Palladium catalysts | Catalysis | Chemical properties | Cyclopentadiene | Analysis | Pyrrole
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 06/2016, Volume 55, Issue 26, pp. 7487 - 7491
The synthesis of tetranuclear gold complexes, a structurally unprecedented octanuclear complex with a planar [AuI8] core, and pentanuclear [AuI4MI] (M=Cu, Ag)... 
gold | heterometallic complexes | structure elucidation | homogeneous catalysis | carbonylation | Amines | Catalysis | Nanoparticles | Gold | Carbonyl compounds | Bimetals | Ureas | Carbonyls | Communications | Communication
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 05/2018, Volume 83, Issue 9, pp. 4932 - 4947
The catalytic system generated in situ from the tetranuclear Ru–H complex with a catechol ligand (1/L1) was found to be effective for the direct deaminative... 
TRANSITION-METAL CATALYSIS | ROOM-TEMPERATURE | DIRECT REDUCTIVE AMINATION | CHEMOSELECTIVE REDUCTION | PRIMARY ALLYLIC AMINES | HETEROCYCLIC CARBENE | ANILINE DERIVATIVES | CARBON-NITROGEN BOND | CHEMISTRY, ORGANIC | C-N BOND | HECK REACTION | ruthenium catalyst | deamination | secondary amine
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 10/2017, Volume 23, Issue 58, pp. 14416 - 14419
The acetate complex Ru(OAc)2(DiPPF) (2) obtained from Ru(OAc)2(PPh3)2 (1) and 1,1′‐bis(diisopropylphosphino)ferrocene (DiPPF) reacts cleanly with formaldehyde... 
borrowing hydrogen | amines | ruthenium | alcohols | N-alkylation | Alcohol | Amines | Acetic acid | Dipping | Alkylation | Alcohols
Journal Article