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protodeborylation (14) 14
chemistry (6) 6
derivatives (6) 6
polarization transfer (6) 6
1,1‐vinyloboration, intramolecular (5) 5
chemistry, inorganic & nuclear (5) 5
enhancement (5) 5
organoboration (5) 5
chemistry, organic (4) 4
crystal-structure (4) 4
spirosilanes (4) 4
1,1-vinyloboration, intramolecular (3) 3
1,1‐ethyloboration, intermolecular (3) 3
1,2-hydroboration (3) 3
alkynylstannanes (3) 3
chemistry, multidisciplinary (3) 3
coupling-constants (3) 3
hydroboration (3) 3
magnetic-resonance (3) 3
molecular-structures (3) 3
nmr (3) 3
spirogermanes (3) 3
triethylborane (3) 3
1,1-ethyloboration, intermolecular (2) 2
1,1-organoboration (2) 2
3‐borylsiloles, protodeborylation of (2) 2
acetic acid (2) 2
activation (2) 2
alkynes (2) 2
alkynylsilanes (2) 2
bond activation (2) 2
boron (2) 2
boron-compounds (2) 2
carboboration (2) 2
chemistry, applied (2) 2
cyclisation (2) 2
dialkynylsilanes, intermolecular 1,1‐ethyloboration of (2) 2
esters (2) 2
germanes, tetra‐1‐alkynyl (2) 2
group-14 metalloles (2) 2
hydrogenation (2) 2
magnetic resonance (2) 2
mathematical analysis (2) 2
nmr-spectroscopy (2) 2
nuclear magnetic resonance (2) 2
route (2) 2
sandwich complex, cyclodiastereomers of (2) 2
silacyclopentadiene (2) 2
silanes, tetra‐1‐alkynyl (2) 2
siloles (2) 2
siloles, boryl‐organo‐substituted (2) 2
1,1-ethylboration (1) 1
1,1-vinylboration (1) 1
1,5-enynes (1) 1
1-silacyclobutenes (1) 1
1-silacyclohex-2-enes (1) 1
1-silacyclopent-2-enes (1) 1
1‐complexes of (1) 1
3-borylsiloles, protodeborylation of (1) 1
9-borabicyclo<3.3.1>nonane (1) 1
acetolysis (1) 1
aggregation-induced emission (1) 1
aliphatic-hydrocarbons (1) 1
alkane (1) 1
alkanes (1) 1
alkene (1) 1
alkenes (1) 1
alkine (1) 1
alpha-chiral ketones (1) 1
asymmetric alkylation (1) 1
b-alkylcatecholboranes (1) 1
bearing (1) 1
biochemistry, general (1) 1
biophysics and biological physics (1) 1
bor (1) 1
boronic ester (1) 1
boronic esters (1) 1
c-13 (1) 1
carbon (1) 1
carbonyl-compounds (1) 1
catalysis (1) 1
chemical reactions (1) 1
chemistry/food science, general (1) 1
combination (1) 1
communication (1) 1
communications (1) 1
complexes (1) 1
complexes of (1) 1
coordination chemistry (1) 1
cycloisomerization (1) 1
density-functional theory (1) 1
dft calculations (1) 1
dialkynylsilanes, intermolecular 1,1-ethyloboration of (1) 1
diboroxanes (1) 1
diffraction (1) 1
directed cycloaddition (1) 1
electronic control (1) 1
electrophilic phosphonium cations (1) 1
enynes (1) 1
equivalence (1) 1
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Angewandte Chemie International Edition, ISSN 1433-7851, 03/2016, Volume 55, Issue 13, pp. 4336 - 4339
The first frustrated Lewis pair‐catalyzed cycloisomerization of a series of 1,5‐enynes was developed. The reaction proceeds via the π‐activation of the alkyne... 
kinetic isotope effect | cycloisomerization | 1,5-enynes | protodeborylation | frustrated Lewis pairs | ACTIVATION | HYDROGENATION | MECHANISM | ZETA-VALENCE QUALITY | HYDROAMINATION | ALKYNES | CHEMISTRY, MULTIDISCIPLINARY | CHEMISTRY | GAUSSIAN-BASIS SETS | ENYNES | Organic chemistry | Side reactions | Catalysis | Alkenes | Isomerization | Alkynes
Journal Article
Synlett, ISSN 0936-5214, 07/2016, Volume 27, Issue 11, pp. 1674 - 1676
Abstract We report herein that 3-pinacol boronic esters undergo facile protodeborylation in the presence of palladium catalysts and base, and this contributes... 
letter | palladium | indoles | boronic ester | cyclisation | protodeborylation | ROUTE | ACTIVATION | DIRECTED CYCLOADDITION | ESTERS | CHEMISTRY, ORGANIC
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 02/2018, Volume 57, Issue 9, pp. 2441 - 2444
Vinyl boron ate complexes of enantioenriched secondary alkyl pinacolboronic esters undergo stereospecific radical‐induced 1,2‐migration in radical polar... 
α-chiral ketones | radical polar crossover reactions | boronic esters | protodeborylation | B-ALKYLCATECHOLBORANES | FLUOROALKYLATION | CARBONYL-COMPOUNDS | CHEMISTRY, MULTIDISCIPLINARY | REARRANGEMENT | METHODOLOGY | REDUCTION | ESTERS | ASYMMETRIC ALKYLATION | alpha-chiral ketones | FLUORINE | HOMOLOGATION | Boron | Ketones | Iodides | Migration | Esters | Alkanes | Oxidation | Communications | Communication
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 01/2019, Volume 2019, Issue 2-3, pp. 283 - 294
This review summarizes the principle reaction mechanisms of frustrated Lewis pairs (FLP) in hydrogenations and carbon–nitrogen and carbon–carbon bond forming... 
Lewis acids | Hydrogen activation | Protodeborylation | Frustrated Lewis pair | Hydrogenation | Lewis bases | HETEROLYTIC DIHYDROGEN ACTIVATION | CARBON | ELECTRONIC CONTROL | CHEMISTRY, ORGANIC | H-2 ACTIVATION | STRUCTURAL FEATURES | LONDON DISPERSION | ELECTROPHILIC PHOSPHONIUM CATIONS | CHEMISTRY | METAL-FREE HYDROGENATION | BOND ACTIVATION
Journal Article
Applied Organometallic Chemistry, ISSN 0268-2605, 04/2014, Volume 28, Issue 4, pp. 280 - 285
Journal Article
Applied Organometallic Chemistry, ISSN 0268-2605, 06/2015, Volume 29, Issue 6, pp. 384 - 391
Journal Article
Zeitschrift für Naturforschung B, ISSN 0932-0776, 10/2009, Volume 64, Issue 10, pp. 1098 - 1106
1,1-Organoboration of dialkyn-1-yl(divinyl)silanes, dialkyn-1-yl(organo)(vinyl)silanes and dialkyn- 1-yl(allyl)(methyl)silane using triethylborane, BEt3, or... 
Siloles | Triethylborane | NMR | Protodeborylation | Organoboration | Alkynylsilanes | 1,2-HYDROBORATION | CHEMISTRY, ORGANIC | MOLECULES | CHEMISTRY, INORGANIC & NUCLEAR | 9-BORABICYCLO<3.3.1>NONANE | C-13 | AGGREGATION-INDUCED EMISSION | ENHANCEMENT | POLARIZATION TRANSFER | DERIVATIVES
Journal Article
Central European Journal of Chemistry, ISSN 1895-1066, 10/2012, Volume 10, Issue 5, pp. 1633 - 1639
Journal Article
Zeitschrift für Naturforschung B, ISSN 0932-0776, 03/2008, Volume 63, Issue 3, pp. 275 - 279
Journal Article
Chemische Berichte, ISSN 0009-2940, 06/1993, Volume 126, Issue 6, pp. 1385 - 1396
Organosubstituted 1,1′‐Spirobisiloles and 1,1′‐Spirobigermoles by Fourfold Organoboration of Tetra‐1‐alkynylsilanes and ‐germanes[1] Si(CCR)4 [RMe (A), RPh... 
Transition metals, η41‐complexes of | Spirosilanes | Protodeborylation | 1,1‐Ethyloboration, intermolecular | Spirogermanes | 1,1‐Vinyloboration, intramolecular | Silanes, tetra‐1‐alkynyl | Germanes, tetra‐1‐alkynyl
Journal Article
Chemische Berichte, ISSN 0009-2940, 05/1993, Volume 126, Issue 5, pp. 1107 - 1114
Organo‐Substituted Siloles by Twofold Organoboration of Di‐1‐alkynylsilanes Me2Si(CCR)2 [RMe (A), Bu (B), tBu (C), iPent (D), Ph (E), Me3Si (F)], prepared... 
Siloles, boryl‐organo‐substituted | 3‐Borylsiloles, protodeborylation of | Dialkynylsilanes, intermolecular 1,1‐ethyloboration of | (Ligand)transition metal, η4 complexes of | 1,1‐Vinyloboration, intramolecular | Sandwich complex, cyclodiastereomers of
Journal Article
CHEMISCHE BERICHTE-RECUEIL, ISSN 0009-2940, 05/1993, Volume 126, Issue 5, pp. 1107 - 1114
Journal Article
CHEMISCHE BERICHTE-RECUEIL, ISSN 0009-2940, 06/1993, Volume 126, Issue 6, pp. 1385 - 1396
Journal Article
10/2009, Volume 2009, Issue 29‐30, 9
Various dialkynylsilanes bearing Si–H or SiCl functions in addition to the alkynyl groups react with an excess of triethylborane after heating at 100–110 °C... 
Main group elements | Boron | Silicon | Heterocyclic compounds | Alkynes | 1,1-VINYLBORATION | SOLAR-CELLS | 1,2-HYDROBORATION | CRYSTAL-STRUCTURE | ORGANOBORATION | CHEMISTRY, INORGANIC & NUCLEAR | TRIETHYLBORANE | ENHANCEMENT | PROTODEBORYLATION | POLARIZATION TRANSFER | 1,1-ETHYLBORATION
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