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pyrimidyl alkanol (66) 66
enantiomeric excess (57) 57
amplification (41) 41
chemistry, multidisciplinary (41) 41
chemistry, organic (37) 37
asymmetric autocatalysis (29) 29
organic-compound (28) 28
highly enantioselective synthesis (25) 25
enantioselective synthesis (24) 24
soai reaction (24) 24
autocatalysis (22) 22
symmetry-breaking (22) 22
catalysis (21) 21
chemistry, inorganic & nuclear (21) 21
sodium-chlorate (20) 20
chirality (19) 19
conjunction (18) 18
circularly-polarized light (16) 16
analysis (14) 14
homochirality (14) 14
chemistry (12) 12
chemistry, physical (12) 12
origin (12) 12
aldehydes (11) 11
amino-acids (11) 11
chemistry, medicinal (11) 11
chiral-symmetry-breaking (10) 10
index medicus (10) 10
pyrimidyl aldehydes (10) 10
synthesis (10) 10
absolute asymmetric-synthesis (9) 9
alkylation (9) 9
chemical properties (9) 9
complexes (9) 9
asymmetric amplification (8) 8
automultiplication (8) 8
biomolecular homochirality (8) 8
circularly polarized light (8) 8
circularly-polarized-light (8) 8
crystallography (8) 8
enantiomers (8) 8
origin of chirality (8) 8
quartz (8) 8
stereoisomerism (8) 8
absolute asymmetric synthesis (7) 7
alkylzinc additions (7) 7
asymmetric synthesis (7) 7
crystal structure (7) 7
molecules (7) 7
pharmacology & pharmacy (7) 7
pyrimidyl (7) 7
asymmetry (6) 6
chiral autocatalysis (6) 6
isotope chirality (6) 6
organozinc reagents (6) 6
spontaneous emergence (6) 6
asymmetric autocatalytic reaction (5) 5
carbonyl-compounds (5) 5
chemistry, analytical (5) 5
chiralität (5) 5
dialkylzinc (5) 5
diisopropylzinc (5) 5
induction (5) 5
ligands (5) 5
mechanism (5) 5
mirror-symmetry-breaking (5) 5
nucleobase cytosine (5) 5
organic chemistry (5) 5
pyridyl (5) 5
pyrimidines (5) 5
alcohols (4) 4
amino acids (4) 4
amplification of chirality (4) 4
amplification of ee (4) 4
asymmetric autocatalytic alkylation (4) 4
asymmetric catalysis (4) 4
asymmetric-catalysis (4) 4
asymmetrische katalyse (4) 4
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copper (4) 4
crystal structures (4) 4
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dialkylzinc reagents (4) 4
enantioselectivity (4) 4
kinetic resolution (4) 4
metal-complexes (4) 4
organic compounds (4) 4
origin of homochirality (4) 4
polymers (4) 4
pyrimidyl aryl sulfides (4) 4
1,4-dihydro form (3) 3
3,6-bis-1,2,4,5-tetrazine (3) 3
5-pyrimidyl alkanol (3) 3
alcohols - chemical synthesis (3) 3
alcohols - chemistry (3) 3
aldehydes - chemistry (3) 3
alkanols (3) 3
amino acids - chemistry (3) 3
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Chemical Communications, ISSN 1359-7345, 2017, Volume 53, Issue 32, pp. 4441 - 4444
An unusual temperature-dependent autoinductive reversal of enantio-selectivity (TARE) was discovered in an asymmetric palladium-mediated [3+3]-annulation of... 
ALCOHOLS | CATALYSIS | ENANTIOMERIC EXCESS | PYRIMIDYL ALKANOL | AMPLIFICATION | PRODUCT | ALDEHYDES | ADDITIONS | CHEMISTRY, MULTIDISCIPLINARY | ASYMMETRIC AUTOCATALYSIS
Journal Article
CHEMICAL COMMUNICATIONS, ISSN 1359-7345, 05/2019, Volume 55, Issue 36, pp. 5223 - 5226
Among several theories proposed for the origin of homochirality, absolute asymmetric synthesis is unique because it produces chiral compounds without the... 
EXCESS | ORIGIN | PYRIMIDYL ALKANOL | AMPLIFICATION | SELF-DISPROPORTIONATION | HOMOCHIRALITY | AMINO-ACIDS | MOLECULAR CHIRALITY | CHIRAL-SYMMETRY-BREAKING | CHEMISTRY, MULTIDISCIPLINARY | AUTOCATALYSIS
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 09/2015, Volume 137, Issue 34, pp. 10852 - 10866
The use of modern kinetic tools to obtain virtually continuous reaction progress data over the course of a catalytic reaction opens up a vista that provides... 
ENANTIOMERIC EXCESS | TERMINAL EPOXIDES | HYDROGENATION | ALPHA-SELENENYLATION | ARYL HALIDES | RATIONALIZATION | PYRIMIDYL ALDEHYDES | ASYMMETRIC AUTOCATALYTIC ALKYLATION | ALDOL REACTIONS | REACTION CALORIMETRY | CHEMISTRY, MULTIDISCIPLINARY | Usage | Catalysis | Kinetic energy | Analysis
Journal Article
Organic & biomolecular chemistry, ISSN 1477-0520, 04/2019, Volume 17, Issue 17, pp. 4200 - 4203
Chiral crystals of the only achiral proteinogenic α-amino acid, glycine induced the asymmetric autocatalysis with amplification of enantiomeric excess (ee).... 
Journal Article
Organic and Biomolecular Chemistry, ISSN 1477-0520, 2019, Volume 17, Issue 5, pp. 1238 - 1244
Without using chiral sources, the Strecker reaction of achiral hydrogen cyanide, p-tolualdehyde and benzhydrylamine gave enantioenriched L- or... 
CRYSTALLIZATION | ENANTIOMERIC EXCESS | ORIGIN | PYRIMIDYL ALKANOL | AMPLIFICATION | ENANTIOSELECTIVE SYNTHESIS | AMINO-ACIDS | CHEMISTRY, ORGANIC | CHIRAL-SYMMETRY-BREAKING | CONJUNCTION | AUTOCATALYSIS
Journal Article
Chemical Communications: Chem Comm, ISSN 1359-7345, 04/2017, Volume 53, Issue 32, pp. 4441 - 4444
An unusual temperature-dependent autoinductive reversal of enantioselectivity (TARE) was discovered in an asymmetric palladium-mediated [3+3]-annulation of... 
Reaction products | Correlation | Asymmetry | Palladium | Stereochemistry | Catalysis | Acetates | Adducts
Journal Article
ORGANIC & BIOMOLECULAR CHEMISTRY, ISSN 1477-0520, 05/2019, Volume 17, Issue 17, pp. 4200 - 4203
Chiral crystals of the only achiral proteinogenic a-amino acid, glycine induced the asymmetric autocatalysis with amplification of enantiomeric excess (ee).... 
CENTROSYMMETRIC CRYSTALS | ENANTIOMERIC EXCESS | PYRIMIDYL ALKANOL | AMPLIFICATION | ENANTIOSELECTIVE SYNTHESIS | CHEMISTRY, ORGANIC | CHIRAL-SYMMETRY-BREAKING | SOAI REACTION | INDUCTION | CONJUNCTION | ISOTOPOMER
Journal Article
Organic and Biomolecular Chemistry, ISSN 1477-0520, 2017, Volume 15, Issue 6, pp. 1321 - 1324
Reversal of the sense of enantioselectivity was observed between 1-aza[6]helicene 2 and 2-aza[6]helicene 3 employed as chiral inducers of asymmetric... 
ENANTIOMERIC EXCESS | PYRIMIDYL ALKANOL | GOLD-CATALYSIS | CIRCULARLY-POLARIZED LIGHT | CHEMISTRY, ORGANIC | PYRIDINE N-OXIDES | ORGANIC-COMPOUND | STEREOSELECTIVE SYNTHESES | SOAI REACTION | 2+2+2 CYCLOADDITION | ONE HUNDRED YEARS
Journal Article
ORGANIC & BIOMOLECULAR CHEMISTRY, ISSN 1477-0520, 2017, Volume 15, Issue 5, pp. 1321 - 1324
Reversal of the sense of enantioselectivity was observed between 1-aza[6]helicene 2 and 2-aza[6]helicene 3 employed as chiral inducers of asymmetric... 
ENANTIOMERIC EXCESS | PYRIMIDYL ALKANOL | GOLD-CATALYSIS | CIRCULARLY-POLARIZED LIGHT | CHEMISTRY, ORGANIC | PYRIDINE N-OXIDES | ORGANIC-COMPOUND | STEREOSELECTIVE SYNTHESES | SOAI REACTION | 2+2+2 CYCLOADDITION | ONE HUNDRED YEARS
Journal Article
Bulletin of the Chemical Society of Japan, ISSN 0009-2673, 10/2019, Volume 92, Issue 10, pp. 1656 - 1661
Self-replication is one of the essential characteristics of life, therefore, chemical reaction, in which biologically related chiral enantioenriched compounds... 
CRYSTALLIZATION | ENANTIOMERIC EXCESS | PYRIMIDYL ALKANOL | RESOLUTION | MOLECULAR CHIRALITY | Self-replication | SUGARS | CHEMISTRY, MULTIDISCIPLINARY | AUTOCATALYSIS | ORIGIN | NITRILES | CHEMISTRY | Strecker synthesis | Asymmetric amplification
Journal Article
Crystal Growth & Design, ISSN 1528-7483, 06/2012, Volume 12, Issue 6, pp. 3335 - 3341
Solvothermal reactions of thiacalix[4]arene, NaN3, and acetonitrile in the presence of nickel(II)/cobalt(II) salts yielded four discrete complexes sustained by... 
5-(PYRIMIDYL)TETRAZOLE | MATERIALS SCIENCE, MULTIDISCIPLINARY | CRYSTAL-STRUCTURES | VERSATILITY | CRYSTALLOGRAPHY | LUMINESCENT PROPERTIES | CENTERS | CHEMISTRY, MULTIDISCIPLINARY | CHEMISTRY | FRAMEWORK | METAL | MAGNETIC-PROPERTIES | COORDINATION POLYMERS
Journal Article
Coordination Chemistry Reviews, ISSN 0010-8545, 04/2013, Volume 257, Issue 7-8, pp. 1409 - 1435
Journal Article
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, ISSN 1433-7851, 12/2016, Volume 55, Issue 49, pp. 15246 - 15249
Chirality arising from isotope substitution, especially with atoms heavier than the hydrogen isotopes, is usually not considered a source of chirality in a... 
ENANTIOMERIC EXCESS | PYRIMIDYL ALKANOL | chirality | ENANTIOSELECTIVE SYNTHESIS | CHIROPTICAL PROPERTIES | SOAI REACTION | CHEMISTRY, MULTIDISCIPLINARY | nitrogen isotopes | asymmetric amplification | AMPLIFICATION | CHROMATOGRAPHIC-SEPARATION | isotopes | BIOLOGICAL CHIRALITY | AMINO-ACIDS | asymmetric autocatalysis | SYMMETRY-BREAKING
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 10/2015, Volume 51, Issue 76, pp. 14377 - 14380
Without the addition of any chiral substances, the spontaneous formation of an enantioenriched α-amino nitrile (up to 96% ee), which is a chiral precursor for... 
Solid-Phase Synthesis Techniques | Amino Acids - chemistry | Amino Acids - chemical synthesis | Stochastic Processes | Stereoisomerism | Nitriles - chemistry
Journal Article
Chemical Communications, ISSN 1359-7345, 07/2015, Volume 51, Issue 76, pp. 14377 - 14380
Without the addition of any chiral substances, the spontaneous formation of an enantioenriched alpha-amino nitrile (up to 96% ee), which is a chiral precursor... 
ENANTIOMERIC EXCESS | ORIGIN | PYRIMIDYL ALKANOL | ABSOLUTE ASYMMETRIC-SYNTHESIS | SPONTANEOUS RESOLUTION | BIOMOLECULAR HOMOCHIRALITY | STIRRED CRYSTALLIZATION | CHEMISTRY, MULTIDISCIPLINARY | SYMMETRY-BREAKING | AUTOCATALYSIS | MOLECULES | Synthesis | Approximation | Precursors | Spontaneous | Skewed distributions | Nitriles | Amino acids | Formations
Journal Article
Organic Letters, ISSN 1523-7060, 06/2016, Volume 18, Issue 11, pp. 2536 - 2539
Nearly racemic target molecules are enantiomerically enriched through an asymmetric autocatalytic relay for a remote amplification of chirality. Target... 
MIRROR-SYMMETRY-BREAKING | HIGHLY ENANTIOSELECTIVE SYNTHESIS | ENANTIOMERIC EXCESS | SPONTANEOUS EMERGENCE | CIRCULARLY-POLARIZED LIGHT | PYRIMIDYL ALDEHYDES | CHEMISTRY, ORGANIC | CHEMICAL EVOLUTION | ORGANIC-COMPOUND | DYNAMIC CONTROL | SOAI REACTION
Journal Article
The Journal of Physical Chemistry B, ISSN 1520-6106, 08/2016, Volume 120, Issue 30, pp. 7438 - 7445
Solutions of very low concentrations cannot be treated by the usual concept of concentration. Stochastic calculations are performed for the analysis of such... 
WHOLE-GENOME AMPLIFICATION | SUBSTITUTION | SINGLE-MOLECULE DETECTION | PYRIMIDYL ALKANOL | ENANTIOSELECTIVE SYNTHESIS | ABSOLUTE ASYMMETRIC-SYNTHESIS | BIOLOGICAL CHIRALITY | CHEMISTRY | CHEMISTRY, PHYSICAL | CONJUNCTION | AUTOCATALYSIS | Learning models (Stochastic processes) | Usage
Journal Article
Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry, ISSN 0037-9980, 2019, Volume 77, Issue 1, pp. 80 - 83
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 12/2017, Volume 23, Issue 67, pp. 16920 - 16923
Mixing of enantiomers of chiral molecules can have remarkable effects on the properties of their higher order assemblies. This, in turn, may have profound... 
racemic | aggregation | enantiomers | chirality | crystal structures | CRYSTALLIZATION | PYRIMIDYL ALKANOL | RESOLUTION | LESSONS | CHEMISTRY, MULTIDISCIPLINARY | ORIGIN | AMPLIFICATION | PEPTIDES | ASYMMETRIC AUTOCATALYSIS | INSIGHTS | Enantiomers | Deactivation | Catalysis | Inactivation | Crystallography | Structure-function relationships
Journal Article
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