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Angewandte Chemie International Edition, ISSN 1433-7851, 11/2018, Volume 57, Issue 48, pp. 15841 - 15846
Despite a well‐developed and growing body of work in Cu catalysis, the potential of Cu to serve as a photocatalyst remains underexplored. Reported herein is... 
cross-coupling | copper | peptides | radicals | photochemistry | ENDOMORPHIN-1 ANALOGS | N-HYDROXYPHTHALIMIDE ESTERS | CROSS-COUPLING REACTION | PHOTOREDOX | ALPHA | CHEMISTRY, MULTIDISCIPLINARY | AMINO-ACIDS | ALKYLMAGNESIUM HALIDES | REDOX-ACTIVE ESTERS | GRIGNARD-REAGENTS | N-(ACYLOXY)PHTHALIMIDES | Peptides | Glycine | Copper | Amino acids | Catalysis | Alkylation
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 07/2017, Volume 23, Issue 37, pp. 8814 - 8817
Journal Article
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, ISSN 1433-7851, 03/2019, Volume 58, Issue 12, pp. 4002 - 4006
The synthetic utility of tertiary amines to oxidatively generate a-amino radicals is well established, however, primary amines remain challenging because of... 
radicals | ACIDS | amines | reaction mechanisms | ALPHA-AMINOALKYL RADICALS | CHEMISTRY, MULTIDISCIPLINARY | C-H BONDS | ATOM | FUNCTIONALIZATION | ABSTRACTION | photochemistry | ADDITION-REACTIONS | ARENECARBONITRILES | ALIPHATIC-AMINES | PHOTOCHEMICAL-REACTIONS | synthetic methods | Side reactions | Divergence | Amines | Alkenes | Sulfonamides | Selectivity | Catalysis | Derivatives | Amino radical | Alkylation | Intermediates
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 10/2017, Volume 139, Issue 42, pp. 14897 - 14900
Visible light photoredox catalysis enables direct γ- C­(sp3)–H alkylation of saturated aliphatic carbonyl compounds. Electron-deficient alkenes are used as the... 
FUNCTIONALIZATION | C(SP)-H BONDS | ACTIVATION | AMINATION | OLEFINATION | NITROGEN-CENTERED RADICALS | ARYLATION | CHEMISTRY, MULTIDISCIPLINARY | C-H BONDS
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 05/2014, Volume 136, Issue 19, pp. 6858 - 6861
Direct β-alkylation of saturated aldehydes has been accomplished by synergistically combining photo­redox catalysis and organo­catalysis. Photon-induced... 
OXIDATION | ORGANIC-SYNTHESIS | CATALYSIS | ACTIVATION | ASYMMETRIC CONJUGATE ADDITION | VISIBLE-LIGHT PHOTOCATALYSIS | ARYLATION | CARBOXYLIC ESTERS | RADICALS | MICHAEL ACCEPTORS | CHEMISTRY, MULTIDISCIPLINARY | Activated | Spectroscopy | Pathways | Spectroscopic analysis | Catalysis | Aldehydes | Radicals | Quenching | Communication
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 06/2016, Volume 138, Issue 25, pp. 8019 - 8030
Herein we describe our efforts to elucidate the key mechanistic aspects of the previously reported enantioselective photochemical α-alkylation of aldehydes... 
VISIBLE-LIGHT | SOMO ACTIVATION | COMPLEX | ELECTRON-TRANSFER | ORGANOCATALYSIS | CHEMISTRY | RADICALS | SUBSTITUTION-REACTIONS | CHEMISTRY, MULTIDISCIPLINARY | 2+2 PHOTOCYCLOADDITION REACTIONS | PHOTOREDOX CATALYSIS | Chemical properties | Aldehydes | Analysis | Alkylation | Photochemistry | Trapping | Catalysts | Reaction kinetics | Chain reactions | Chains | Assessments | Radicals
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 12/2015, Volume 21, Issue 49, pp. 17618 - 17622
Journal Article
Organic Letters, ISSN 1523-7060, 10/2018, Volume 20, Issue 20, pp. 6345 - 6348
The first Pd-catalyzed alkylation of (iso)­quinolines and arenes is reported. The readily available and bench-stable 2-acylpyridine compounds were used as an... 
ARYL BROMIDES | DIARYLMETHANES | FREE REGIOSELECTIVE ALKYLATION | PALLADIUM | CROSS-COUPLING REACTIONS | HETEROARENES | ALPHA-ARYLATION | CHEMISTRY, ORGANIC | PYRIDINE N-OXIDES | RADICAL ALKYLATION | ALKYLZINC HALIDES
Journal Article
Chemical Communications, ISSN 1359-7345, 2017, Volume 53, Issue 64, pp. 8964 - 8967
The catalytic asymmetric alkylation of the remote, unactivated delta-position of N-alkyl amides was enabled by the combination of visible-light-induced... 
FUNCTIONALIZATION | ACTIVATION | AMINATION | COMPLEX | STRATEGY | IODINE | RADICALS | CHEMISTRY, MULTIDISCIPLINARY | C-H BONDS | PHOTOREDOX CATALYSIS
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 06/2013, Volume 52, Issue 23, pp. 6080 - 6083
Journal Article
Chemical science, ISSN 2041-6520, 10/2016, Volume 7, Issue 10, pp. 6407 - 6412
A photoredox-mediated Minisci C-H alkylation reaction of -heteroarenes with alkyl boronic acids is reported. A broad range of primary and secondary alkyl... 
Journal Article
Chemical Science, ISSN 2041-6520, 2014, Volume 5, Issue 7, pp. 2893 - 2898
Sunlight-induced direct regioselective beta-alkylation of cyclopentanones with electron-deficient alkenes was accomplished by using tetrabutylammonium... 
FUNCTIONALIZATION | CYCLIC-KETONES | CATALYSIS | ALKENES | PHOTOREDOX | ARYLATION | PEROXYCARBONATE | ARYL KETONES | CHEMISTRY, MULTIDISCIPLINARY | C-H BONDS | RADICAL REACTIONS | Sunlight | Alkenes | Catalysts | Acylation
Journal Article