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Journal of Organometallic Chemistry, ISSN 0022-328X, 02/2020, Volume 907, p. 121070
Half-sandwich organometallic complexes featuring Ru(II), Os(II) and Rh(III) metal centers and naturally occurring bidentate 2-hydroxy-[1,4]-naphthoquinone... 
X-ray crystal structures | Solution stability | Cytotoxicity | Natural ligands | Half-sandwich complexes
Journal Article
Journal of Organometallic Chemistry, ISSN 0022-328X, 01/2020, Volume 906, p. 121061
Cationic cyclopentadienyl iron complexes of substituted phenylenes [CpFe( -CH -C H -Ar)]PF and [CpFe( -Ar-C H -Ar)]PF were obtained in 37–73% yields by... 
Suzuki coupling | Polyarenes | Iron | Sandwich complexes | PYRENE | ARENES | OPTICAL-PROPERTIES | CHEMISTRY, ORGANIC | RUTHENIUM | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 01/2020, Volume 59, Issue 3, pp. 1197 - 1200
The labeling of (bio)molecules with metallic radionuclides such as 99mTc demands conjugated, multidentate chelators. However, this is not always necessary... 
sandwich complexes | screening | rhenium | technetium | molecular imaging | AROMATENKOMPLEXE VON METALLEN | RE | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
ACS OMEGA, ISSN 2470-1343, 12/2019, Volume 4, Issue 27, pp. 22540 - 22548
Half-sandwich arene-metal complexes are commonly used for specific applications. Herein, we report facile arene ligand exchange reactions of two ruthenium(II)... 
ENERGY | ASYMMETRIC-SYNTHESIS | TRANSITION-METAL-COMPLEXES | APPROXIMATION | REACTIVITY | TRANSFER HYDROGENATION | BASIS-SETS | CRYSTAL | HALF-SANDWICH COMPLEXES | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 12/2019, Volume 25, Issue 68, pp. 15687 - 15693
A novel template‐free Cp*Rh‐based molecular Solomon link has been established through selection of the flexible ligand L as a linker and the half‐sandwich... 
sandwich complexes | conformation analysis | dynamic interconversion | self-assembly | solvent effects | macrocycles | Solomon link
Journal Article
JOURNAL OF CHEMICAL SCIENCES, ISSN 0974-3626, 12/2019, Volume 131, Issue 12
Syntheses and structural elucidations of a series of chalcogen stabilized binuclear complexes of group 5 and 6 transition metals have been described. Room... 
CP-ASTERISK | MOLYBDENUM | Chalcogen | REACTIVITY | CRYSTAL-STRUCTURES | HALF-SANDWICH COMPLEXES | TRANSITION-METALS | ANTIFERROMAGNETIC COMPLEXES | CHEMISTRY, MULTIDISCIPLINARY | CLUSTERS | chalcogen-bridged | MOLECULAR-STRUCTURES | binuclear complex | ELECTRONIC-STRUCTURE | Chemical Sciences
Journal Article
ChemMedChem, ISSN 1860-7179, 11/2019, Volume 14, Issue 22, pp. 1887 - 1893
An evaluation of the in vitro cytotoxicity of nine electron‐deficient half‐sandwich metal complexes towards two colorectal cancer cell lines (HCT116 p53+/+,... 
half-sandwich complexes | metallodrugs | colorectal cancer | electron-deficient | gene expression | Biotechnology | Toxicity | p53 Protein | Colorectal carcinoma | Colorectal cancer | Cytotoxicity | Selectivity | Tumor cell lines | Gene expression | Cisplatin | Anticancer properties | Cell lines | Antitumor activity | Coordination compounds | Prostate | Metal complexes | Cancer
Journal Article
ORGANOMETALLICS, ISSN 0276-7333, 11/2019, Volume 38, Issue 21, pp. 4298 - 4306
The complex salt [CpRu(eta(6)-C10H8)][(CpRu)(2)(mu-Cl)(3)] ([1][2]) was synthesized and found to be a useful CpRuCI synthon. The ions [1](+) and [2](-) cleanly... 
ACTIVATION | LIGANDS | BRIDGED COMPLEXES | COUPLING REACTION | REACTIVITY | CHEMISTRY | CHEMISTRY, ORGANIC | ASTERISK | HALF-SANDWICH COMPLEXES | DERIVATIVES | METHYLIDENE | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
JOURNAL OF CHEMISTRY, ISSN 2090-9063, 11/2019, Volume 2019, pp. 1 - 18
Platinum-group (PG) complexes have been used as antibacterial and anticancer agents since the discovery of cisplatin. The science world still requires... 
IN-VITRO | IRIDIUM(III) COMPLEXES | ARENE RUTHENIUM COMPLEXES | CRYSTAL-STRUCTURE | BIOLOGICAL EVALUATION | STRUCTURAL-CHARACTERIZATION | HALF-SANDWICH COMPLEXES | RHODIUM COMPLEXES | OSMIUM | CHEMISTRY, MULTIDISCIPLINARY | CANCER-THERAPY
Journal Article
by Chen, QQ and Wang, Y and Shi, SS and Li, KH and Zhang, L and Gao, J
INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES, 11/2019, Volume 20, Issue 21, p. 5410
Based on the up-regulation of the proviral integration site of the Moloney murine leukemia virus (Pim) kinase family (Pim1, 2, and 3) observed in several types... 
MM | GBSA calculation | PROTEIN | BIOCHEMISTRY & MOLECULAR BIOLOGY | molecular dynamics simulation | AZD1208 | HALF-SANDWICH COMPLEXES | CHEMISTRY, MULTIDISCIPLINARY | DISCOVERY | PIM447 | Pim kinase | POTENT | BINDING | pim kinase | pim447 | mm/gbsa calculation | azd1208
Journal Article
by Paul, B and Maji, M and Kundu, S
ACS CATALYSIS, ISSN 2155-5435, 11/2019, Volume 9, Issue 11, pp. 10469 - 10476
A cobalt complex catalyzed tandem conversion of nitrile to N-methylated amide is described using a methanol and water mixture. Using this protocol, several... 
CATALYSIS | ACTIVATION | mechanistic study | tandem process | methanol activation | nitrile hydration | N-methylated amide | CHEMISTRY, PHYSICAL | TRANSFER HYDROGENATION | cobalt | HYDRATION | ALCOHOLS | FORMYLATION | PEPTIDES | AMINES | HALF-SANDWICH COMPLEX | EFFICIENT
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 10/2019, Volume 58, Issue 43, pp. 15318 - 15323
The ligand‐unsupported accommodation of extra metal moieties in a sandwich complex is reported. Although it has been considered that the metal‐capacity of a... 
sandwich complexes | palladium clusters | cyclononatetraenyl | cyclooctatetraene | Precious metal products | Sheet-metal | Palladium | Platinum | Metal sheets | Metals | Docking | Ligands | Coordination compounds | Unsaturated hydrocarbons
Journal Article
DALTON TRANSACTIONS, ISSN 1477-9226, 10/2019, Volume 48, Issue 37, pp. 13931 - 13942
Redox-active ligands, owing to their electron reservoir capability, are well suited for the generation of coordinatively unsaturated metal complexes. We... 
TRANSITION-METAL-COMPLEXES | DENSITY-FUNCTIONAL CALCULATIONS | CHARGE-DISTRIBUTION | O-AMINOPHENOL | VALENCE TAUTOMERISM | DONOR-ACCEPTOR SYSTEMS | HALF-SANDWICH COMPLEXES | OXIDATIVE ADDITION | IDENTITY APPROXIMATION | ELECTRONIC-STRUCTURE | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, ISSN 0888-5885, 09/2019, Volume 58, Issue 37, pp. 17308 - 17318
In the present work, a novel heterogeneous catalytic system involving copper(I) complex of moisture- and air-stable organoselenium ligand supported on Fe3O4... 
ENGINEERING, CHEMICAL | PALLADIUM(II) COMPLEXES | REUSABLE CATALYST | EFFICIENT CATALYST | ONE-POT SYNTHESIS | STRUCTURAL CHEMISTRY | TRANSFER HYDROGENATION | HALF-SANDWICH COMPLEXES | HETEROGENEOUS CATALYST | FUNCTIONALIZED HALLOYSITE | SEPARABLE CATALYST
Journal Article