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Angewandte Chemie International Edition, ISSN 1433-7851, 09/2018, Volume 57, Issue 37, pp. 12141 - 12145
A robust method for the preparation of silicon‐based magnesium reagents is reported. The MgBr2 used in the lithium‐to‐magnesium transmetalation step is... 
cross-coupling | radical reactions | magnesium | silicon | synthetic methods | HALIDES | SUBSTITUTION | MECHANISM | COPPER | SILYLMETALATION | CHEMISTRY, MULTIDISCIPLINARY | SILYLATION | SILYLBORONATE | ALKYL ELECTROPHILES | BOND ACTIVATION | METAL | Silicon | Precipitation (Meteorology) | Chemical tests and reagents | Stocks | Cobalt | Borides | Reagents | Bromides | Chemical reactions | Lithium | Iron | High temperature | Magnesium | Coupling | Magnesium compounds
Journal Article
1988, Best synthetic methods., ISBN 0121825604, xxii, 147
Book
Chemistry – A European Journal, ISSN 0947-6539, 01/2015, Volume 21, Issue 2, pp. 893 - 899
The addition of BCl3 to the carbene‐transfer reagent NHC→SiCl4 (NHC=1,3‐dimethylimidazolidin‐2‐ylidene) gave the tetra‐ and pentacoordinate... 
silicon | main group elements | boron | carbene ligands | phosphorus | Carbene ligands | Main group elements | Phosphorus | Boron | Silicon | N-HETEROCYCLIC CARBENE | COMPLEXES | COORDINATION | OXIDATIVE ADDITION | CHEMISTRY, MULTIDISCIPLINARY | CATIONS | IMIDAZOLE DERIVATIVES | DIAMINOCARBENE | CHEMISTRY | PENTACOORDINATE
Journal Article
Science, ISSN 0036-8075, 03/2017, Volume 355, Issue 6332, pp. 1403 - 1407
Over the past 80 years, phenyl cation intermediates have been implicated in a variety of C-H arylation reactions. Although these examples have inspired several... 
BOND-DISSOCIATION ENERGIES | METHANE | CARBON | CARBOCATIONS | PHENYL CATION | MULTIDISCIPLINARY SCIENCES | CHEMISTRY | IONS | ARYL CATIONS | C-H INSERTION | HYDRODEFLUORINATION | Hydrocarbons | Arylation | Research | Chemical properties | Chemical research | Methane | Anions | Fluoride | Hydrogen bonds | Fluorine | Benzene | Reagents | Alkanes | Silicon | Hydrogen bonding | Intermediates | Aromatic compounds | Chemical bonds | Cations
Journal Article
Synthesis, ISSN 0039-7881, 08/2017, Volume 49, Issue 15, pp. 3394 - 3406
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 03/2009, Volume 15, Issue 11, pp. 2476 - 2485
ESi transfer: Anionic compounds capable of transferring a silicon‐containing double bond are reviewed (see figure), particularly reagents with SiSi moieties... 
Si ligands | silicon | Group 14 elements | multiple bonds | anions | conjugation | Anions | Multiple bonds | Silicon | Conjugation | CYCLIC SILENES | GROUP-14 CHEMISTRY | SP-TYPE SILYL ANION | ORGANIC DERIVATIVES | MAIN-GROUP ELEMENTS | CHEMISTRY, MULTIDISCIPLINARY | LOW COORDINATION | HEAVY ALKENES | SI=SI DOUBLE-BOND | SI DOUBLE-BONDS
Journal Article
Analytical Chemistry, ISSN 0003-2700, 02/2000, Volume 72, Issue 3, pp. 585 - 590
A 330-pL chromatographic bed was fabricated on a glass substrate as part of an electroosmotically pumped microfluidic system. Two weirs within a sample channel... 
PERFORMANCE LIQUID-CHROMATOGRAPHY | TRYPTIC DIGEST | CHEMISTRY, ANALYTICAL | MICROCHIP | GROWTH-HORMONE | SILICON CHIP | OPEN-CHANNEL ELECTROCHROMATOGRAPHY | NONAQUEOUS MEDIA | CAPILLARY ZONE ELECTROPHORESIS | GLASS CHIPS | PEPTIDE | Evaluation | Chemistry, Analytic | Chromatographic analysis | Analysis | Research | Capillaries | Silica
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 05/2019, Volume 25, Issue 26, pp. 6505 - 6507
A stereospecific ring opening of various 2‐aryl‐substituted aziridines with silicon Grignard reagents under copper catalysis is reported. The regiochemical... 
aziridines | copper | magnesium | silicon | synthetic methods | SUBSTITUTION | ACTIVATION | 2-ARYLAZIRIDINES | CHEMISTRY, MULTIDISCIPLINARY | Silicon | Catalysis | Chemical tests and reagents | Nitrogen | Copper | Aromatic compounds | Lithium chloride | Reagents | Magnesium | Lithium chlorides | Ring opening
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 08/2018, Volume 24, Issue 44, pp. 11278 - 11282
Journal Article