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Journal of the American Chemical Society, ISSN 0002-7863, 12/2018, Volume 140, Issue 51, pp. 18032 - 18038
The functionalization of unactivated C­(sp3)–H bonds of aliphatic amines catalyzed by transition-metal complexes is important because amine-based functionality... 
FUNCTIONALIZATION | ACTIVATION | ENANTIOSELECTIVE SILYLATION | DEHYDROGENATIVE SILYLATION | ARYLATION | NITROGEN | UNACTIVATED C(SP)-H | REGIOSELECTIVE SILYLATION | DIRECTING-GROUP | CHEMISTRY, MULTIDISCIPLINARY | C-H BONDS
Journal Article
Chemistry : a European journal, ISSN 0947-6539, 2019, Volume 25, Issue 10, pp. 2407 - 2422
Journal Article
Organic Letters, ISSN 1523-7060, 05/2013, Volume 15, Issue 10, pp. 2498 - 2501
An efficient method for the synthesis of fused heteroaromatic dihydrosiloles via Ni-catalyzed hydrosilylation/intramolecular Ir-catalyzed dehydrogenative... 
HYDROGEN | ACTIVATION | DEHYDROGENATIVE SILYLATION | HYDROSILANES | ARENES | RUTHENIUM-CATALYZED SILYLATION | CHEMISTRY, ORGANIC | ARYL | BOND | CLEAVAGE | C-H SILYLATION
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 12/2016, Volume 55, Issue 51, pp. 15787 - 15791
Aryl(triethyl)silanes are found to undergo cross‐coupling with iodoarenes in the presence of catalytic amounts of CuBr2 and Ph‐Davephos, as well as cesium... 
cross-coupling | silanes | copper | arenes | C−H silylation | FLUORINATED BENZOTHIADIAZOLE | GENERAL-SOLUTION | INTRAMOLECULAR ACTIVATION | BUILDING-BLOCKS | CHEMISTRY, MULTIDISCIPLINARY | POLYMER SOLAR-CELLS | DEHYDROGENATIVE SILYLATION | CONJUGATED POLYMERS | C-H silylation | ARYL HALIDES | ORGANIC ELECTRONICS
Journal Article
Synthesis (Stuttgart), ISSN 1437-210X, 2015, Volume 47, Issue 16, pp. 2347 - 2366
Abstract Silylation of hydrocarbons is one of the most important transformations due to the diverse application of organosilanes. Continuous progress is being... 
short review | catalytic | C-H activation | silylation | metal-free | siloles | ORGANIC-SYNTHESIS | C(SP)-H BONDS | ACTIVATION | SILICON-CONTAINING COMPOUNDS | IRIDIUM | HYDROSILANES | CHEMISTRY, ORGANIC | CARBON-HYDROGEN BONDS | CLEAVAGE | CATALYZED REGIOSELECTIVE SILYLATION | DEHYDROGENATIVE SILYLATION
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 2016, Volume 55, Issue 9, pp. 3204 - 3207
An electrophilic aromatic substitution (SEAr) with a catalytically generated silicon electrophile is reported. Essentially any commercially available... 
Lewis acids | hydrosilanes | C−H activation | Si−H activation | electrophilic substitution | C-H activation | Si-H activation | ACTIVATION | COMPLEX | BENZENE | MECHANISM | BOND-CLEAVAGE | CATALYZED SILYLATION | CHEMISTRY, MULTIDISCIPLINARY | INDOLES | FUNCTIONALIZATION | N-SILYLATION | Substitution reactions | Lewis acid | Protons | Salts | Catalysts | Aromatic compounds | Metals | Silicon | Crafts
Journal Article
Nature Communications, ISSN 2041-1723, 06/2017, Volume 8, Issue 1, p. 15547
The enantioselective silylation of racemic alcohols, where one enantiomer reacts faster than the other, is an alternative approach to established enzymatic and... 
SILICON-STEREOGENIC SILANES | SECONDARY ALCOHOLS | ENANTIOSELECTIVE SILYLATION | ASYMMETRIC SILYLATION | 1,2-DIOLS | PROTECTION | MULTIDISCIPLINARY SCIENCES | STEREOSELECTIVE SILYLATION | DESYMMETRIZATION
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 2016, Volume 55, Issue 30, pp. 8723 - 8727
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 01/2018, Volume 140, Issue 4, pp. 1460 - 1470
A rhodium-catalyzed intramolecular silylation of alkyl C–H bonds has been developed that occurs with unusual selectivity for the C–H bonds located δ to the... 
C(SP)-H BONDS | ACTIVATION | ENANTIOSELECTIVE SILYLATION | DEHYDROGENATIVE SILYLATION | IRIDIUM | HYDROSILANES | COMPLEXES | ARENES | CARBON-HYDROGEN BONDS | DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY | Alcohols - chemistry | Silanes - chemistry | Stereoisomerism | Alcohols - chemical synthesis | Models, Molecular | Molecular Structure | Catalysis | Rhodium - chemistry
Journal Article
Synlett, ISSN 0936-5214, 11/2017, Volume 28, Issue 18, pp. 2468 - 2472
Journal Article
Science (American Association for the Advancement of Science), ISSN 1095-9203, 2014, Volume 343, Issue 6173, pp. 853 - 857
Regioselective C–H functionalization of arenes has widespread applications in synthetic chemistry. The regioselectivity of these reactions is often controlled... 
Silanes | Reactivity | Catalysts | Rhodium | Hydrogen bonds | Hydrogen | RESEARCH ARTICLES | Reagents | Cyclohexenes | Ligands | Chemical bonding | ACTIVATION | HETEROARENES | DIRECT ARYLATION | DEHYDROGENATIVE SILYLATION | IRIDIUM COMPLEXES | MULTIDISCIPLINARY SCIENCES | BOND FUNCTIONALIZATION | CLEAVAGE | BORYLATION | INSIGHTS | Chemical reactions | Chemical properties | Research | Chemical research | Molecular biology | Catalysis
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 09/2017, Volume 139, Issue 35, pp. 12137 - 12140
We report highly enantio­selective intramolecular, silylations of unactivated, primary C­(sp3)–H bonds. The reactions form dihydro­benzo­siloles in high yields... 
DEHYDROGENATIVE SILYLATION | POT | ACIDS | HYDROSILANES | ARYLATION | ARYL | REGIOSELECTIVE SILYLATION | C(SP)-H | CHEMISTRY, MULTIDISCIPLINARY | DESYMMETRIZATION
Journal Article
Chemistry : a European journal, ISSN 1521-3765, 2019, Volume 25, Issue 40, pp. 9358 - 9365
The non‐enzymatic kinetic resolution of racemic mixtures of alcohols by silylation had been unknown before the turn of the century. This stands in stark... 
organocatalysis | kinetic resolution | copper | desymmetrization | silicon | MECHANISM | HYDROSILANES | STEREOSELECTIVE SILYLATION | COMBINATION | CHEMISTRY, MULTIDISCIPLINARY | SECONDARY ALCOHOLS | SILANES | CATALYTIC ENANTIOSELECTIVE SILYLATION | Alcohols | Stereoselectivity | Coupling (molecular) | Dehydrogenation | Protecting groups | Alcohol | Ethers | Chemical synthesis | Enantiomers | Diols | Acylation
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 2017, Volume 56, Issue 47, pp. 14942 - 14947
Journal Article
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