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Journal of the American Chemical Society, ISSN 0002-7863, 05/2013, Volume 135, Issue 17, pp. 6703 - 6713
The first electron-rich N-heterocyclic silylene (NHSi)–iron(0) complexes are reported. The synthesis of the starting complex is accomplished by reaction of the... 
BERRY PSEUDOROTATION | CARBONYL-COMPLEXES | ORGANIC-SYNTHESIS | BASE-STABILIZED SILYLENE | STABLE SILYLENE | FACILE ACCESS | COORDINATION SPHERE | HYDROSILYLATION | SILICON(II) HYDRIDE | CHEMISTRY, MULTIDISCIPLINARY | METAL COMPLEXES | Usage | Iron compounds | Diffraction | Methyl groups | X-rays | Density functionals | Chemical properties | Structure
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 10/2013, Volume 52, Issue 19, pp. 11593 - 11599
Reaction of the donor-stabilized silylene 1 with [Cr(CO)6], [Mo(CO)6], [W(CO)6], or [Fe(CO)5] leads to the formation of the transition-metal silylene complexes... 
CARBONYL-COMPLEXES | BASE-STABILIZED SILYLENE | DIVALENT SILICON | STABLE SILYLENES | COVALENT RADII | N-HETEROCYCLIC SILYLENE | REACTIVITY | STRUCTURAL-CHARACTERIZATION | CRYSTAL-STRUCTURES | BIS(SILYLENE)IRON | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Chemical Reviews, ISSN 0009-2665, 10/2016, Volume 116, Issue 19, pp. 11291 - 11435
This third review in a series involving reactions of hydrosilanes and transition metal complexes and characterization of the products covers the period 2009... 
H BOND ACTIVATION | SILANE SIGMA-COMPLEXES | SI-C BOND | SILICON-SILICON BONDS | PNP PINCER LIGAND | PALLADIUM-CATALYZED REACTIONS | N-HETEROCYCLIC SILYLENE | X-RAY CRYSTAL | HALF-SANDWICH COMPLEXES | CHEMISTRY, MULTIDISCIPLINARY | HYDRIDE COMPLEXES
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 02/2006, Volume 128, Issue 7, pp. 2176 - 2177
Reactions of hydrido(hydrosilylene)tungsten complexes, Cp‘(CO)2(H)WSi(H)[C(SiMe3)3], with nitriles (MeCN, t BuCN) at 60 °C gave hydrosilylation products,... 
REACTIVITY | CATALYTIC HYDROSILYLATION | CHEMISTRY, MULTIDISCIPLINARY | ETA-2-SILANIMINE COMPLEXES | SILYLENE COMPLEXES
Journal Article
European Journal of Inorganic Chemistry, ISSN 1434-1948, 06/2016, Volume 2016, Issue 17, pp. 2688 - 2691
Reaction of the functionalized tetrel cluster [Ge9R3]– {R = Si(SiMe3)3} with coinage metal N‐heterocyclic carbene (NHC) complexes affords the first Zintl... 
Coinage metals | NHC complexes | Cluster compounds | Zintl anions | SILYLENE | GERMANIUM CLUSTERS | BUILDING-BLOCKS | CHEMISTRY | ISOMERS | CATALYSTS | CHEMISTRY, INORGANIC & NUCLEAR | Heterocyclic compounds | Coins | Solvents | Gold | Silver | Clusters | Transformations | Coordination compounds | Copper | Carbenes
Journal Article
Chemical Communications, ISSN 1359-7345, 2014, Volume 50, Issue 77, pp. 11401 - 11403
Reactions of the chlorosilylene [PhC((NBu)-Bu-t)(2)]SiCl (SiCl) and the aryl and alkyl zincorganyls Zn(C5Me5)(2), ZnPh2 and ZnEt2 resulted in the first... 
HALIDES | REAGENTS | SILICON | N-HETEROCYCLIC SILYLENE | REACTIVITY | ADDUCTS | DECAMETHYLDIZINCOCENE | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
ACS Catalysis, ISSN 2155-5435, 12/2018, Volume 8, Issue 12, pp. 11435 - 11469
Homogeneous catalysis of organic transformations by metal complexes has been mostly based on complexes of noble metals. In recent years, tremendous progress... 
pincer ligand | homogenous catalysis | cobalt | manganese | earth-abundant metal | ACCEPTOR LESS | AMIDE SYNTHESIS | N-HETEROCYCLIC SILYLENE | C(SP)-H BORYLATION | ORGANOMANGANESE(II) COMPLEXES | CHEMISTRY, PHYSICAL | CARBON-DIOXIDE HYDROGENATION | DIRECT ACCESS | AROMATIC-AMINES | SELECTIVE HYDROGENATION | ENANTIOSELECTIVE HYDROGENATION
Journal Article
Organometallics, ISSN 0276-7333, 04/2016, Volume 35, Issue 7, pp. 921 - 924
Treatment of the hydrido hydrosilylene complex Cp*­(CO)2(H)­WSi­(H)­Tsi (1; Tsi = C­(SiMe3)3) with 1 equiv of MeI i Pr (MeI i Pr =... 
TRANSITION-METAL-COMPLEXES | LIGANDS | N-HETEROCYCLIC-CARBENE | SILYLENE COMPLEXES | HYDRIDO(HYDROGERMYLENE)TUNGSTEN COMPLEX | SILICON | REACTIVITY | CHEMISTRY, ORGANIC | STRUCTURAL-CHARACTERIZATION | HYDRIDO(HYDROSILYLENE)TUNGSTEN COMPLEXES | RUTHENIUM COMPLEX | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 10/2012, Volume 18, Issue 42, pp. 13355 - 13360
Journal Article
Chemical Communications: Chem Comm, ISSN 1359-7345, 08/2014, Volume 50, Issue 77, pp. 11401 - 11403
Reactions of the chlorosilylene [PhC(N super(t)Bu) sub(2)]SiCl (SiCl) and the aryl and alkyl zincorganyls Zn(C sub(5)Me sub(5)) sub(2 ), ZnPh sub(2) and ZnEt... 
Exchange | Demand | Aromatic compounds | Chlorine | Chlorides | Zinc
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 05/2017, Volume 56, Issue 22, pp. 5945 - 5945
The reactions described by D. J. H. Emslie et al. in their Communication on page 6223 ff. start with manganese and hydrogen, and sequentially introduce silicon... 
silylene ligands | hydride ligands | silene ligands | ethylene | manganese | Hydrogen storage | Polar environments | Climbing | Teeth | Ethylene | Silicon | Chemical synthesis | Manganese
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 02/2017, Volume 56, Issue 9, pp. 2260 - 2294
Journal Article