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1. Recent advances in silylene chemistry: Small molecule activation en-route towards metal-free catalysis
by Blom, Burgert and Driess, Matthias
Structure and Bonding, ISSN 0081-5993, 2014, Volume 156, pp. 85 - 124
Previously only known as fleeting, transient laboratory curiosities in the 1960s, silylenes (species of the general type: (SiR)-R-II'R '' where R' and R '' are... 
N-heterocyclic silylenes | π-coordinated silylenes | Acyclic silylenes | Catalysis | Small molecule bond activation | Base-stabilised silylenes | Carbocyclic silylenes | YLIDE-LIKE SILYLENE | STABLE SILYLENE | N-HETEROCYCLIC SILYLENE | GROUP 14 ELEMENTS | REACTIVITY | CHEMISTRY, PHYSICAL | THEORETICAL INVESTIGATIONS | CHEMISTRY, INORGANIC & NUCLEAR | ISOLABLE DIALKYLSILYLENE | CARBENE ANALOGS | pi-coordinated silylenes | STANNYLYNE COMPLEX | INDEPENDENT CHEMICAL-SHIFTS
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2. Full Text Facile Access to Silicon‐Functionalized Bis‐Silylene Titanium(II) Complexes
by Blom, Burgert and Driess, Matthias and Gallego, Daniel and Inoue, Shigeyoshi
Chemistry – A European Journal, ISSN 0947-6539, 10/2012, Volume 18, Issue 42, pp. 13355 - 13360
A series of unprecedented bis‐silylene titanium(II) complexes of the type [(η5‐C5H5)2Ti(LSiX)2] (L=PhC(NtBu)2; X=Cl, CH3, H) has been prepared using a... 
density functional calculations | N‐heterocyclic silylenes | donor–acceptor stabilization | silicon | titanium | N-heterocyclic silylenes | donor-acceptor stabilization | RUTHENIUM-SILYLENE | ACTIVATION | STABLE SILYLENE | HYDROSILYLATION | REACTIVITY | COORDINATION | CHEMISTRY, MULTIDISCIPLINARY | BASE-STABILIZED SILYLENE | CHEMISTRY | METAL-CARBONYL-COMPLEXES | LIGAND | Titanium | Analysis | Silicon | Mineralogy | Diffraction | Crystals
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3. Full Text Five-Coordinate Silicon(II) Compounds with Si–M Bonds (M = Cr, Mo, W, Fe): Bis[N,N′‑diisopropylbenzamidinato(−)]silicon(II) as a Ligand in Transition-Metal Complexes
by Junold, Konstantin and Baus, Johannes A and Burschka, Christian and Vent-Schmidt, Thomas and Riedel, Sebastian and Tacke, Reinhold
Inorganic Chemistry, ISSN 0020-1669, 10/2013, Volume 52, Issue 19, pp. 11593 - 11599
Reaction of the donor-stabilized silylene 1 with [Cr(CO)6], [Mo(CO)6], [W(CO)6], or [Fe(CO)5] leads to the formation of the transition-metal silylene complexes... 
CARBONYL-COMPLEXES | BASE-STABILIZED SILYLENE | DIVALENT SILICON | STABLE SILYLENES | COVALENT RADII | N-HETEROCYCLIC SILYLENE | REACTIVITY | STRUCTURAL-CHARACTERIZATION | CRYSTAL-STRUCTURES | BIS(SILYLENE)IRON | CHEMISTRY, INORGANIC & NUCLEAR
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4. Full Text Reactivity of a Silylsilylene Bearing a Functionalized Diaminochlorosilyl Substituent
by Zhang, Shu‐Hua and Yeong, Hui‐Xian and So, Cheuk‐Wai
Chemistry – A European Journal, ISSN 0947-6539, 03/2011, Volume 17, Issue 12, pp. 3490 - 3499
The reactivity of the silylsilylene [{PhC(NtBu)2}SiSi(Cl){(NtBu)2C(H)Ph}] (2) towards diphenylacetylene, azobenzene, 2,6‐diisopropylphenyl azide, sulfur, and... 
carbene homologues | N ligands | silicon | chalcogens | silylenes | EXCITED-STATE | COMPLEXES | ISOLABLE SILYLENE | BASE-STABILIZED DICHLOROSILYLENE | OXIDATIVE ADDITION | CHEMISTRY, MULTIDISCIPLINARY | DOUBLE-BONDS | CHEMISTRY | N-HETEROCYCLIC SILYLENES | THERMALLY STABLE SILYLENE | Equivalence | Toluene | X-rays | Silicon | Formations | Selenium | Sulfur | NMR spectroscopy
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5. Full Text Bis(amidinato)- and bis(guanidinato)silylenes and silylenes with one sterically demanding amidinato or guanidinato ligand: synthesis and reactivity
by Tacke, Reinhold and Ribbeck, Tatjana
Dalton Transactions, ISSN 1477-9226, 10/2017, Volume 46, Issue 4, pp. 13628 - 13659
This article deals with the synthesis and reactivity of the bis(amidinato)silylene [ i PrNC(Ph)N i Pr] 2 Si ( 5 ), the bis(guanidinato)silylene [ i PrNC(N i Pr... 
CARBONYL-COMPLEXES | ACTIVATION | STABLE SILYLENE | LEWIS ACID/BASE REACTIONS | 6-COORDINATE SILICON(IV) COMPLEXES | DOUBLE-BONDS | CHEMISTRY | N-HETEROCYCLIC SILYLENES | DONOR-STABILIZED SILYLENES | CHEMISTRY, INORGANIC & NUCLEAR
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6. Full Text Bis(amidinato)- and bis(guanidinato)silylenes and silylenes with one sterically demanding amidinato or guanidinato ligand: synthesis and reactivity
by Tacke, Reinhold and Ribbeck, Tatjana
Dalton transactions (Cambridge, England : 2003), ISSN 1477-9226, 10/2017, Volume 46, Issue 40, pp. 13628 - 13659
This article deals with the synthesis and reactivity of the bis(amidinato)silylene [iPrNC(Ph)NiPr] Si (5), the bis(guanidinato)silylene [iPrNC(NiPr )NiPr] Si... 
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7. Full Text Bis[N,N′‐diisopropylbenzamidinato(−)]silicon(II): A Silicon(II) Compound with Both a Bidentate and a Monodentate Amidinato Ligand
by Junold, Konstantin and Baus, Johannes A and Burschka, Christian and Tacke, Reinhold
Angewandte Chemie International Edition, ISSN 1433-7851, 07/2012, Volume 51, Issue 28, pp. 7020 - 7023
Well looked‐after: Reductive HCl elimination of the λ6‐silicon(IV) complex 1 leads to the λ3‐silicon(II) species 2, a novel type of donor‐stabilized silylene.... 
N ligands | tungsten | silicon compounds | coordination chemistry | silylenes | THERMALLY STABLE SILYLENES | CHLOROSILYLENE | N-HETEROCYCLIC SILYLENE | REACTIVITY | STRUCTURAL-CHARACTERIZATION | BASE-STABILIZED DICHLOROSILYLENE | CHEMISTRY, MULTIDISCIPLINARY | CARBONYL-COMPLEXES | CHEMISTRY | HOMOLOGS | SKELETONS | Ligands
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8. Full Text Metal‐Free Activation of EH3 (E=P, As) by an Ylide‐like Silylene and Formation of a Donor‐Stabilized Arsasilene with a HSiAsH Subunit
by Präsang, Carsten and Stoelzel, Miriam and Inoue, Shigeyoshi and Meltzer, Antje and Driess, Matthias
Angewandte Chemie International Edition, ISSN 1433-7851, 12/2010, Volume 49, Issue 51, pp. 10002 - 10005
Twice, and faster: Reaction of the zwitterionic silylene 1 with AsH3 occurs stepwise at ambient temperature to give the first crystalline, donor‐stabilized... 
density functional calculations | N‐heterocyclic silylenes | arsanes | zwitterions | phosphanes | STABLE SILYLENE | N-heterocyclic silylenes | SILICON | COMPOUND | N-HETEROCYCLIC SILYLENE | REACTIVITY | SILYLIDENE-PHOSPHANES | CHEMISTRY, MULTIDISCIPLINARY | SUBSTITUTED DISILENES | DERIVATIVES | DOUBLE-BOND | DISILYNE RSISIR
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9. Full Text Aromatic Ylide‐Stabilized Carbocyclic Silylene
by Asay, Matthew and Inoue, Shigeyoshi and Driess, Matthias
Angewandte Chemie International Edition, ISSN 1433-7851, 10/2011, Volume 50, Issue 41, pp. 9589 - 9592
New ring on the block: A new type of silylene (see scheme) has been synthesized and is stabilized by the ylidic carbon centers which serve as π‐donor... 
density functional calculations | ylides | cyclization | silylenes | aromaticity | DIALKYLSILYLENE | SILICON | REACTIVITY | CHEMISTRY, MULTIDISCIPLINARY | DOUBLE-BONDS | CARBENES | CHEMISTRY | N-HETEROCYCLIC SILYLENES | LIGAND | THERMALLY STABLE SILYLENE | INDEPENDENT CHEMICAL-SHIFTS
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10. Full Text Exceptionally Strong Electron-Donating Ability of Bora-Ylide Substituent vis-a-vis Silylene and Silylium Ion
by Rosas-Sanchez, A and Alvarado-Beltran, I and Baceiredo, A and Saffon-Merceron, N and Massou, S and Branchadell, V and Kato, T
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, ISSN 1433-7851, 08/2017, Volume 56, Issue 35, pp. 10549 - 10554
Electropositive boron-based substituent (phosphonium bora-ylide) with an exceptionally strong pi- and sigma electron donating character dramatically increases... 
ligands | STABLE SILYLENES | CARBENE LIGANDS | COMPLEXES | bora-ylides | N-HETEROCYCLIC SILYLENE | REACTIVITY | CHEMISTRY, MULTIDISCIPLINARY | H BOND ACTIVATION | silylium ion | coordination chemistry | silylenes | NHC LIGANDS | CHEMISTRY | CHARACTER | SILICON(II)
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11. Full Text The transition-metal chemistry of amidinatosilylenes, -germylenes and -stannylenes
by Álvarez-Rodríguez, Lucía and Cabeza, Javier A and García-Álvarez, Pablo and Polo, Diego
Coordination Chemistry Reviews, ISSN 0010-8545, 09/2015, Volume 300, pp. 1 - 28
The transition-metal (TM) chemistry of heavier tetrylenes (HTs), also known as heavier carbene analogs, group 14 metalenes or group 14 metalylenes (compounds... 
Amidinates | Silylene ligands | Transition-metal complexes | Germylene ligands | Stannylene ligands | Heavier tetrylenes as ligands | COORDINATION CHEMISTRY | BIVALENT GERMANIUM | N-HETEROCYCLIC CARBENE | RUTHENIUM CARBONYL | PLATINUM SILYLENE COMPLEXES | UNSUPPORTED SILVER-GERMANIUM | CHEMISTRY, INORGANIC & NUCLEAR | H BOND ACTIVATION | CARBONYL-COMPLEXES | FACILE ACCESS | BRIDGING SILYLENE
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12. Full Text Homoleptic Two‐Coordinate 14‐Electron Palladium and Platinum Complexes with Two Bis(guanidinato)silylene Ligands
by Baus, Johannes A and Mück, Felix M and Bertermann, Rüdiger and Tacke, Reinhold
European Journal of Inorganic Chemistry, ISSN 1434-1948, 10/2016, Volume 2016, Issue 30, pp. 4867 - 4871
The homoleptic transition‐metal bis(silylene) complexes [{{iPrNC(NiPr2)NiPr}2Si}2M] (7: M = Pd; 8: M = Pt) were synthesized by treatment of [PdCl2(SMe2)2] and... 
Silylenes | N ligands | Palladium | Silicon | Platinum | ACTIVATION | REACTIVITY | COORDINATION | CHEMISTRY, INORGANIC & NUCLEAR | 6-COORDINATE SILICON(IV) COMPLEXES | BONDS | N-HETEROCYCLIC SILYLENES | DONOR-STABILIZED SILYLENES | Ligands | Synthesis
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13. Full Text Lewis Base Stabilized Dichlorosilylene
by Ghadwal, Rajendra S and Roesky, Herbert W and Merkel, Sebastian and Henn, Julian and Stalke, Dietmar
Angewandte Chemie International Edition, ISSN 1433-7851, 07/2009, Volume 48, Issue 31, pp. 5683 - 5686
Stable? You can bottle it! The base‐stabilized dichlorosilylene L1SiCl2 (see picture; L1=1,3‐bis(2,6‐diisopropylphenyl)imidazol‐2‐ylidene) is stable at room... 
silicon | X‐ray diffraction | dichlorosilylene | silylenes | carbene ligands | Dichlorosilylene | Silylenes | X-ray diffraction | Carbene ligands | Silicon | ENERGY | STABLE SILYLENE | APPROXIMATION | REACTIVITY | TRICHLOROSILANE | CHEMISTRY, MULTIDISCIPLINARY | GERMANIUM(II) | CHEMISTRY | BOND | HYDROXIDE
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14. Full Text Inside Back Cover: An N‐Heterocyclic Boryloxy Ligand Isoelectronic with N‐Heterocyclic Imines: Access to an Acyclic Dioxysilylene and its Heavier Congeners (Angew. Chem. Int. Ed. 15/2019)
by Loh, Ying Kai and Ying, Lu and Ángeles Fuentes, M and Do, Dinh Cao Huan and Aldridge, Simon
Angewandte Chemie International Edition, ISSN 1433-7851, 04/2019, Volume 58, Issue 15, pp. 5135 - 5135
A new class of N‐heterocyclic boryloxy (NHBO) ligand allows access to the first complete series of heavier Group 14 dioxycarbene analogues. Structural studies... 
carbenes | ligands | structure elucidation | heterocycles | silylenes
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15. Full Text Reaction of the Silylene PhC(NtBu)2SitBu with 4,4′‐Bis(dimethylamino)thiobenzophenone and Treatment of the Silylene PhC(NtBu)2SiC(SiMe3)3 with 3,5‐Di‐tert‐butyl‐o‐benzoquinone
by Azhakar, Ramachandran and Roesky, Herbert W and Holstein, Julian J and Dittrich, Birger
European Journal of Inorganic Chemistry, ISSN 1434-1948, 05/2013, Volume 2013, Issue 15, pp. 2777 - 2781
The reaction of LSitBu [L = PhC(NtBu)2] (1) with 4,4′‐bis(dimethylamino)thiobenzophenone resulted in the [1+2]‐cycloaddition product silathiacyclopropane 3,... 
Silylenes | Heterocycles | Cycloaddition | Silicon | ACTIVATION | HETEROLEPTIC SILYLENES | STABLE SILYLENE | CHLOROSILYLENE | PHC(NTBU)SIX X | CHEMISTRY, INORGANIC & NUCLEAR | FACILE ACCESS | LIGANDS | N-HETEROCYCLIC SILYLENES | METAL-CARBONYL-COMPLEXES | BOND
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16. Full Text A Pt(0) complex with cyclic (alkyl)(amino)silylene and 1,3-divinyl-1,1,3,3-tetramethyldisiloxane ligands: Synthesis, molecular structure, and catalytic hydrosilylation activity
by Iimura, Tomohiro and Akasaka, Naohiko and Kosai, Tomoyuki and Iwamoto, Takeaki
Dalton Transactions, ISSN 1477-9226, 2017, Volume 46, Issue 27, pp. 8868 - 8874
A platinum(0) complex bearing a cyclic (alkyl)(amino)silylene and a 1,3-divinyl-1,1,3,3-tetramethyldisiloxane (DVTMS) was synthesized and isolated in the form... 
ACTIVATION | HETEROCYCLIC SILYLENE | PINCER COMPLEXES | BIS(SILYLENE) | PLATINUM SILYLENE COMPLEXES | 2-COORDINATE | REACTIVITY | MULTIPLE BONDS | PAIR | CHEMISTRY, INORGANIC & NUCLEAR
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