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silylene (303) 303
chemistry (240) 240
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disilene (25) 25
germylene (25) 25
cycloaddition (23) 23
synthesis (23) 23
inorganic chemistry (22) 22
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poly[methylsilylene] (17) 17
n ligands (16) 16
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silylene complexes (16) 16
technology (16) 16
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potential energy profile (15) 15
silylene complex (15) 15
applied sciences (14) 14
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disilenes (14) 14
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1. Full Text Synthesis of a Phosphine‐Stabilized Silicon(II) Hydride and Its Addition to Olefins: A Catalyst‐Free Hydrosilylation Reaction
by Rodriguez, Ricardo and Gau, David and Contie, Yohan and Kato, Tsuyoshi and Saffon‐Merceron, Nathalie and Baceiredo, Antoine
Angewandte Chemie (International ed.), ISSN 1433-7851, 11/2011, Volume 50, Issue 48, pp. 11492 - 11495
hydrides | hydrosilylation | silicon | silylenes | phosphorus
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2. Full Text Reversible Binding of Ethylene to Silylene–Phosphine Complexes at Room Temperature
by Rodriguez, Ricardo and Gau, David and Kato, Tsuyoshi and Saffon‐Merceron, Nathalie and De Cózar, Abel and Cossío, Fernando P and Baceiredo, Antoine
Angewandte Chemie (International ed.), ISSN 1433-7851, 10/2011, Volume 50, Issue 44, pp. 10414 - 10416
ylides | cycloaddition | silicon | silylenes | phosphorus
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3. Full Text Synthesis and Characterization of [PhC(NtBu)2]SiCl: A Stable Monomeric Chlorosilylene
by So, Cheuk‐Wai and Roesky, Herbert W and Magull, Jörg and Oswald, Rainer B
Angewandte Chemie (International ed.), ISSN 1433-7851, 06/2006, Volume 45, Issue 24, pp. 3948 - 3950
carbene homologues | N ligands | silicon | halides | silylenes | Silylenes | Silicon | Carbene homologues | Halides
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4. Full Text Inside Back Cover: An N‐Heterocyclic Boryloxy Ligand Isoelectronic with N‐Heterocyclic Imines: Access to an Acyclic Dioxysilylene and its Heavier Congeners (Angew. Chem. Int. Ed. 15/2019)
by Loh, Ying Kai and Ying, Lu and Ángeles Fuentes, M and Do, Dinh Cao Huan and Aldridge, Simon
Angewandte Chemie (International ed.), ISSN 1433-7851, 04/2019, Volume 58, Issue 15, pp. 5135 - 5135
carbenes | ligands | structure elucidation | heterocycles | silylenes
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5. Full Text Synthesis of a Stable Disilyne Bisphosphine Adduct and Its Non‐Metal‐Mediated CO2 Reduction to CO
by Gau, David and Rodriguez, Ricardo and Kato, Tsuyoshi and Saffon‐Merceron, Nathalie and de Cózar, Abel and Cossío, Fernando P and Baceiredo, Antoine
Angewandte Chemie (International ed.), ISSN 1433-7851, 02/2011, Volume 50, Issue 5, pp. 1092 - 1096
carbon dioxide | ylides | silicon | silylenes | phosphorus
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6. Full Text A Stable N‐Hetero‐Rh‐Metallacyclic Silylene
by Takahashi, Shintaro and Bellan, Ekaterina and Baceiredo, Antoine and Saffon‐Merceron, Nathalie and Massou, Stéphane and Nakata, Norio and Hashizume, Daisuke and Branchadell, Vicenç and Kato, Tsuyoshi
Angewandte Chemie (International ed.), ISSN 1433-7851, 07/2019, Volume 58, Issue 30, pp. 10310 - 10314
structure elucidation | N-heterocyclic silylenes | silylenes | metallacycles | rhodium | Rhodium | Chemical Sciences
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7. Full Text Aromatic Ylide‐Stabilized Carbocyclic Silylene
by Asay, Matthew and Inoue, Shigeyoshi and Driess, Matthias
Angewandte Chemie (International ed.), ISSN 1433-7851, 10/2011, Volume 50, Issue 41, pp. 9589 - 9592
density functional calculations | ylides | cyclization | silylenes | aromaticity
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8. Full Text Reaction of the Silylene PhC(NtBu)2SitBu with 4,4′‐Bis(dimethylamino)thiobenzophenone and Treatment of the Silylene PhC(NtBu)2SiC(SiMe3)3 with 3,5‐Di‐tert‐butyl‐o‐benzoquinone
by Azhakar, Ramachandran and Roesky, Herbert W and Holstein, Julian J and Dittrich, Birger
European journal of inorganic chemistry, ISSN 1434-1948, 05/2013, Volume 2013, Issue 15, pp. 2777 - 2781
Silylenes | Heterocycles | Cycloaddition | Silicon
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9. Full Text Pushing the σ‐Donor Strength in Iridium Pincer Complexes: Bis(silylene) and Bis(germylene) Ligands Are Stronger Donors than Bis(phosphorus(III)) Ligands
by Brück, Andreas and Gallego, Daniel and Wang, Wenyuan and Irran, Elisabeth and Driess, Matthias and Hartwig, John F
Angewandte Chemie (International ed.), ISSN 1433-7851, 11/2012, Volume 51, Issue 46, pp. 11478 - 11482
iridium | germylene | pincer ligands | rhodium | silylene
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10. Full Text Consecutive Insertion of a Silylene into the P4 Tetrahedron: Facile Access to Strained SiP4 and Si2P4 Cage Compounds
by Xiong, Yun and Yao, Shenglai and Brym, Markus and Driess, Matthias
Angewandte Chemie (International ed.), ISSN 1433-7851, 06/2007, Volume 46, Issue 24, pp. 4511 - 4513
N ligands | silicon | strained molecules | silylenes | phosphorus | Silylenes | Phosphorus | Silicon | Strained molecules
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11. Full Text Low‐Valent Silicon Cations with Two‐Coordinate Silicon and Aromatic Character
by Driess, Matthias and Yao, Shenglai and Brym, Markus and van Wüllen, Christoph
Angewandte Chemie (International ed.), ISSN 1433-7851, 10/2006, Volume 45, Issue 40, pp. 6730 - 6733
cations | N ligands | silicon | silylenes | aromaticity | Silylenes | Cations | Silicon | Aromaticity
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12. Full Text Lewis Base Stabilized Dichlorosilylene
by Ghadwal, Rajendra S and Roesky, Herbert W and Merkel, Sebastian and Henn, Julian and Stalke, Dietmar
Angewandte Chemie (International ed.), ISSN 1433-7851, 07/2009, Volume 48, Issue 31, pp. 5683 - 5686
silicon | X‐ray diffraction | dichlorosilylene | silylenes | carbene ligands | Dichlorosilylene | Silylenes | X-ray diffraction | Carbene ligands | Silicon | Physical Sciences | Chemistry | Chemistry, Multidisciplinary | Science & Technology
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13. Full Text SiBr2(Idipp): A Stable N‐Heterocyclic Carbene Adduct of Dibromosilylene
by Filippou, Alexander C and Chernov, Oleg and Schnakenburg, Gregor
Angewandte Chemie (International ed.), ISSN 1433-7851, 07/2009, Volume 48, Issue 31, pp. 5687 - 5690
donor–acceptor systems | density functional calculations | silicon | silylenes | carbene ligands | Silylenes | Carbene ligands | Density functional calculations | Silicon | Donor-acceptor systems
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14. Full Text A Silacyclopropene with a Six-Coordinate Silicon Atom and an SiN4C2Skeleton: Synthesis and Structural Characterization
by Baus, Johannes A and Laskowski, Nadine and Tacke, Reinhold
European journal of inorganic chemistry, ISSN 1434-1948, 2016, Volume 2016, Issue 33, pp. 5182 - 5184
Silylenes | Cycloaddition | N ligands | Coordination modes | Silacyclopropenes
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15. Full Text A Cyclic Silylone (“Siladicarbene”) with an Electron‐Rich Silicon(0) Atom
by Xiong, Yun and Yao, Shenglai and Inoue, Shigeyoshi and Epping, Jan Dirk and Driess, Matthias
Angewandte Chemie (International ed.), ISSN 1433-7851, 07/2013, Volume 52, Issue 28, pp. 7147 - 7150
silyliumylidenes | silicon | main‐group chemistry | siladicarbenes | silylenes | main-group chemistry | Physical Sciences | Chemistry | Chemistry, Multidisciplinary | Science & Technology | Silicon | Dechlorination | Chelating | Synthesis | Sodium | Mathematical analysis | Basicity
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