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Chemistry – A European Journal, ISSN 0947-6539, 10/2012, Volume 18, Issue 42, pp. 13355 - 13360
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 10/2013, Volume 52, Issue 19, pp. 11593 - 11599
Reaction of the donor-stabilized silylene 1 with [Cr(CO)6], [Mo(CO)6], [W(CO)6], or [Fe(CO)5] leads to the formation of the transition-metal silylene complexes... 
CARBONYL-COMPLEXES | BASE-STABILIZED SILYLENE | DIVALENT SILICON | STABLE SILYLENES | COVALENT RADII | N-HETEROCYCLIC SILYLENE | REACTIVITY | STRUCTURAL-CHARACTERIZATION | CRYSTAL-STRUCTURES | BIS(SILYLENE)IRON | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 03/2011, Volume 17, Issue 12, pp. 3490 - 3499
The reactivity of the silylsilylene [{PhC(NtBu)2}SiSi(Cl){(NtBu)2C(H)Ph}] (2) towards diphenylacetylene, azobenzene, 2,6‐diisopropylphenyl azide, sulfur, and... 
carbene homologues | N ligands | silicon | chalcogens | silylenes | EXCITED-STATE | COMPLEXES | ISOLABLE SILYLENE | BASE-STABILIZED DICHLOROSILYLENE | OXIDATIVE ADDITION | CHEMISTRY, MULTIDISCIPLINARY | DOUBLE-BONDS | CHEMISTRY | N-HETEROCYCLIC SILYLENES | THERMALLY STABLE SILYLENE | Equivalence | Toluene | X-rays | Silicon | Formations | Selenium | Sulfur | NMR spectroscopy
Journal Article
Dalton Transactions, ISSN 1477-9226, 10/2017, Volume 46, Issue 4, pp. 13628 - 13659
This article deals with the synthesis and reactivity of the bis(amidinato)silylene [ i PrNC(Ph)N i Pr] 2 Si ( 5 ), the bis(guanidinato)silylene [ i PrNC(N i Pr... 
CARBONYL-COMPLEXES | ACTIVATION | STABLE SILYLENE | LEWIS ACID/BASE REACTIONS | 6-COORDINATE SILICON(IV) COMPLEXES | DOUBLE-BONDS | CHEMISTRY | N-HETEROCYCLIC SILYLENES | DONOR-STABILIZED SILYLENES | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Dalton transactions (Cambridge, England : 2003), ISSN 1477-9226, 10/2017, Volume 46, Issue 40, pp. 13628 - 13659
This article deals with the synthesis and reactivity of the bis(amidinato)silylene [iPrNC(Ph)NiPr] Si (5), the bis(guanidinato)silylene [iPrNC(NiPr )NiPr] Si... 
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 07/2012, Volume 51, Issue 28, pp. 7020 - 7023
Well looked‐after: Reductive HCl elimination of the λ6‐silicon(IV) complex 1 leads to the λ3‐silicon(II) species 2, a novel type of donor‐stabilized silylene.... 
N ligands | tungsten | silicon compounds | coordination chemistry | silylenes | THERMALLY STABLE SILYLENES | CHLOROSILYLENE | N-HETEROCYCLIC SILYLENE | REACTIVITY | STRUCTURAL-CHARACTERIZATION | BASE-STABILIZED DICHLOROSILYLENE | CHEMISTRY, MULTIDISCIPLINARY | CARBONYL-COMPLEXES | CHEMISTRY | HOMOLOGS | SKELETONS | Ligands
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 12/2010, Volume 49, Issue 51, pp. 10002 - 10005
Twice, and faster: Reaction of the zwitterionic silylene 1 with AsH3 occurs stepwise at ambient temperature to give the first crystalline, donor‐stabilized... 
density functional calculations | N‐heterocyclic silylenes | arsanes | zwitterions | phosphanes | STABLE SILYLENE | N-heterocyclic silylenes | SILICON | COMPOUND | N-HETEROCYCLIC SILYLENE | REACTIVITY | SILYLIDENE-PHOSPHANES | CHEMISTRY, MULTIDISCIPLINARY | SUBSTITUTED DISILENES | DERIVATIVES | DOUBLE-BOND | DISILYNE RSISIR
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 10/2011, Volume 50, Issue 41, pp. 9589 - 9592
New ring on the block: A new type of silylene (see scheme) has been synthesized and is stabilized by the ylidic carbon centers which serve as π‐donor... 
density functional calculations | ylides | cyclization | silylenes | aromaticity | DIALKYLSILYLENE | SILICON | REACTIVITY | CHEMISTRY, MULTIDISCIPLINARY | DOUBLE-BONDS | CARBENES | CHEMISTRY | N-HETEROCYCLIC SILYLENES | LIGAND | THERMALLY STABLE SILYLENE | INDEPENDENT CHEMICAL-SHIFTS
Journal Article
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, ISSN 1433-7851, 08/2017, Volume 56, Issue 35, pp. 10549 - 10554
Electropositive boron-based substituent (phosphonium bora-ylide) with an exceptionally strong pi- and sigma electron donating character dramatically increases... 
ligands | STABLE SILYLENES | CARBENE LIGANDS | COMPLEXES | bora-ylides | N-HETEROCYCLIC SILYLENE | REACTIVITY | CHEMISTRY, MULTIDISCIPLINARY | H BOND ACTIVATION | silylium ion | coordination chemistry | silylenes | NHC LIGANDS | CHEMISTRY | CHARACTER | SILICON(II)
Journal Article
Coordination Chemistry Reviews, ISSN 0010-8545, 09/2015, Volume 300, pp. 1 - 28
Journal Article
European Journal of Inorganic Chemistry, ISSN 1434-1948, 10/2016, Volume 2016, Issue 30, pp. 4867 - 4871
The homoleptic transition‐metal bis(silylene) complexes [{{iPrNC(NiPr2)NiPr}2Si}2M] (7: M = Pd; 8: M = Pt) were synthesized by treatment of [PdCl2(SMe2)2] and... 
Silylenes | N ligands | Palladium | Silicon | Platinum | ACTIVATION | REACTIVITY | COORDINATION | CHEMISTRY, INORGANIC & NUCLEAR | 6-COORDINATE SILICON(IV) COMPLEXES | BONDS | N-HETEROCYCLIC SILYLENES | DONOR-STABILIZED SILYLENES | Ligands | Synthesis
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 07/2009, Volume 48, Issue 31, pp. 5683 - 5686
Stable? You can bottle it! The base‐stabilized dichlorosilylene L1SiCl2 (see picture; L1=1,3‐bis(2,6‐diisopropylphenyl)imidazol‐2‐ylidene) is stable at room... 
silicon | X‐ray diffraction | dichlorosilylene | silylenes | carbene ligands | Dichlorosilylene | Silylenes | X-ray diffraction | Carbene ligands | Silicon | ENERGY | STABLE SILYLENE | APPROXIMATION | REACTIVITY | TRICHLOROSILANE | CHEMISTRY, MULTIDISCIPLINARY | GERMANIUM(II) | CHEMISTRY | BOND | HYDROXIDE
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 04/2019, Volume 58, Issue 15, pp. 5135 - 5135
A new class of N‐heterocyclic boryloxy (NHBO) ligand allows access to the first complete series of heavier Group 14 dioxycarbene analogues. Structural studies... 
carbenes | ligands | structure elucidation | heterocycles | silylenes
Journal Article
European Journal of Inorganic Chemistry, ISSN 1434-1948, 05/2013, Volume 2013, Issue 15, pp. 2777 - 2781
The reaction of LSitBu [L = PhC(NtBu)2] (1) with 4,4′‐bis(dimethylamino)thiobenzophenone resulted in the [1+2]‐cycloaddition product silathiacyclopropane 3,... 
Silylenes | Heterocycles | Cycloaddition | Silicon | ACTIVATION | HETEROLEPTIC SILYLENES | STABLE SILYLENE | CHLOROSILYLENE | PHC(NTBU)SIX X | CHEMISTRY, INORGANIC & NUCLEAR | FACILE ACCESS | LIGANDS | N-HETEROCYCLIC SILYLENES | METAL-CARBONYL-COMPLEXES | BOND
Journal Article
Dalton Transactions, ISSN 1477-9226, 2017, Volume 46, Issue 27, pp. 8868 - 8874
A platinum(0) complex bearing a cyclic (alkyl)(amino)silylene and a 1,3-divinyl-1,1,3,3-tetramethyldisiloxane (DVTMS) was synthesized and isolated in the form... 
ACTIVATION | HETEROCYCLIC SILYLENE | PINCER COMPLEXES | BIS(SILYLENE) | PLATINUM SILYLENE COMPLEXES | 2-COORDINATE | REACTIVITY | MULTIPLE BONDS | PAIR | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article