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Chemical communications (Cambridge, England), ISSN 1359-7345, 10/2018, Volume 54, Issue 82, pp. 11515 - 11529
As a powerful synthon, pyrazolone has widely been exploited for the construction of various chiral pyrazoles/pyrazolones which hold great potential in the... 
Journal Article
Organic Letters, ISSN 1523-7060, 11/2015, Volume 17, Issue 21, pp. 5168 - 5171
A highly efficient and practical one-pot sequential process, consisting of an organocatalytic enantioselective Friedel–Crafts-type addition of 4-nonsubstituted... 
ISATIN-DERIVED KETIMINES | HIGHLY ENANTIOSELECTIVE SYNTHESIS | MANNICH REACTION | NATURAL-PRODUCTS | QUATERNARY STEREOCENTERS | TERTIARY STEREOCENTERS | NITROOLEFINS | CHEMISTRY, ORGANIC | N-BOC KETIMINES | 3-SUBSTITUTED OXINDOLES | MICHAEL ADDITION
Journal Article
RSC Advances, ISSN 2046-2069, 08/2015, Volume 5, Issue 92, pp. 75648 - 75652
We report the organocatalyzed asymmetric Mannich reaction of isocyanoacetates with isatin derived ketimines in good yields along with high stereoselectivities.... 
ALPHA-ARYL ISOCYANOESTERS | FORMAL 3+2 CYCLOADDITION | NATURAL-PRODUCTS | ALDOL REACTION | MULTIPLE STEREOCENTERS | QUATERNARY STEREOCENTERS | VICINAL TETRASUBSTITUTED STEREOCENTERS | N-BOC KETIMINES | STEREOSELECTIVE-SYNTHESIS | SPIROCYCLIC OXINDOLES | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 09/2017, Volume 53, Issue 72, pp. 10030 - 10033
A catalytic asymmetric decarboxylative [4+2] cycloaddition of vinyl benzoxazinanones with methyleneindolinones has been established, which provided a series of... 
Journal Article
Chemical Communications, ISSN 1359-7345, 2017, Volume 53, Issue 72, pp. 10030 - 10033
A catalytic asymmetric decarboxylative [4+2] cycloaddition of vinyl benzoxazinanones with methyleneindolinones has been established, which provided a series of... 
CASCADE REACTIONS | MULTIPLE STEREOCENTERS | DIELS-ALDER REACTION | STEREOSELECTIVE CONSTRUCTION | 1,3-DIPOLAR CYCLOADDITION | ALLYLIC ALKYLATION | QUATERNARY STEREOCENTERS | POVAROV REACTION | CHEMISTRY, MULTIDISCIPLINARY | CARBAZOLESPIROOXINDOLE SKELETONS | AZOMETHINE IMINES
Journal Article
Chemical Communications, ISSN 1359-7345, 10/2018, Volume 54, Issue 82, pp. 11515 - 11529
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 05/2013, Volume 2013, Issue 14, pp. 2745 - 2759
All‐carbon quaternary stereocenters have posed significant challenges in the synthesis of complex natural products. These important structural motifs have... 
All‐carbon quaternary stereocenters | Palladium | Natural products | Asymmetric cataly­sis | Total synthesis | Allylation | Asymmetric catalysis | All-carbon quaternary stereocenters | CHEMISTRY, ORGANIC | FORMAL TOTAL-SYNTHESIS | ALPHA | ALDEHYDES | KETONES | LIGANDS | SILYL ENOL ETHERS | ESTERS | ENANTIOSELECTIVE TOTAL-SYNTHESIS | CONCISE SYNTHESIS
Journal Article
Tetrahedron, ISSN 0040-4020, 12/2018, Volume 74, Issue 52, pp. 7399 - 7407
The synthesis of all-carbon quaternary centers remains a challenge. Here we describe studies on the formation of two adjacent all-carbon quaternary centers in... 
Diastereoselective | Stereocenter | Dehaloperophoramidine | Quaternary | PEROPHORAMIDINE | COMMUNESIN F | CHEMISTRY, ORGANIC
Journal Article
Organic Letters, ISSN 1523-7060, 04/2017, Volume 19, Issue 7, pp. 1542 - 1545
The first catalytic asymmetric α-arylation of pyrazol-5-ones has been established by using 2-indolylmethanols as direct electrophilic arylation reagents under... 
BRONSTED ACID | ASYMMETRIC-SYNTHESIS | INDOL-2-YL CARBINOLS | ALLYLIC ALCOHOLS | TERTIARY STEREOCENTERS | CHEMISTRY, ORGANIC | VICINAL TETRASUBSTITUTED STEREOCENTERS | STEREOCONTROLLED CONSTRUCTION | INDOLE-DERIVATIVES | CHIRAL PHOSPHORIC-ACID | MICHAEL ADDITION
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 09/2017, Volume 56, Issue 38, pp. 11545 - 11548
The first highly enantioselective iridium‐catalyzed allylic alkylation that provides access to products bearing an allylic all‐carbon quaternary stereogenic... 
iridium | quaternary stereocenter | carboxylic acid derivatives | allylic alkylation | umpolung | SUBSTITUTION | REAGENTS | CHEMISTRY, MULTIDISCIPLINARY | CARBON STEREOGENIC CENTERS | DIASTEREO | ORIGINS | STEREOCENTERS | CONSTRUCTION | ESTERS | REGIO | ARYL
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 2010, Volume 51, Issue 17, pp. 2329 - 2331
The intramolecular Pauson–Khand reaction of aza-Baylis–Hillman adducts, which were prepared through the thio-Michael/imino-aldol domino reaction of optically... 
STEREOCENTER | CHEMISTRY, ORGANIC | DIYNES
Journal Article
RSC Advances, ISSN 2046-2069, 10/2016, Volume 6, Issue 98, pp. 96154 - 96175
Organocatalytic domino/cascade reactions provide a convenient method for the construction of highly functionalized cyclic molecular structures bearing multiple... 
SULFA-MICHAEL/MICHAEL ADDITION | ASYMMETRIC-SYNTHESIS | QUATERNARY STEREOCENTER | ENANTIOSELECTIVE SYNTHESIS | CONSTRUCTION | EFFICIENT SYNTHESIS | CONTIGUOUS STEREOCENTERS | DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY | DYNAMIC KINETIC RESOLUTION | ACCESS
Journal Article
Organic Letters, ISSN 1523-7060, 09/2018, Volume 20, Issue 17, pp. 5393 - 5397
The first catalytic enantioselective decarboxylative Mannich-type reaction of N-unprotected ketimines is reported, directly providing N-unprotected... 
BETA-AMINO ESTERS | AROMATIC KETIMINES | ASYMMETRIC-SYNTHESIS | TETRASUBSTITUTED STEREOCENTERS | CINCHONA ALKALOID AMIDES | QUATERNARY STEREOCENTERS | CHEMISTRY, ORGANIC | TRIFLUOROMETHYL KETIMINES | STEREOSELECTIVE-SYNTHESIS | ACID HALF THIOESTERS | ALPHA-AMINOALLYLATION
Journal Article
19.