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Organic and Biomolecular Chemistry, ISSN 1477-0520, 02/2012, Volume 10, Issue 7, pp. 1396 - 1405
An efficient asymmetric substitution process of O-Boc-protected Morita-Baylis-Hillman adducts with various pyrrole and indole derivatives has been developed in... 
STEREOCONTROLLED CREATION | DIASTEREOSELECTIVE MANNICH REACTIONS | ADJACENT QUATERNARY | ENANTIOSELECTIVE CONJUGATE ADDITION | ALLYLIC ALKYLATION | QUATERNARY STEREOCENTERS | TERTIARY STEREOCENTERS | CHEMISTRY, ORGANIC | DYNAMIC KINETIC RESOLUTION | PALLADIUM-CATALYZED AMINATION | MICHAEL ADDITION
Journal Article
Synthesis, ISSN 0039-7881, 05/2015, Volume 47, Issue 10, pp. 1357 - 1378
Abstract Recent developments in the N-heterocyclic carbene (NHC)-catalyzed umpolung of aldehydes followed by their interception with activated carbon–carbon... 
review | organocatalysis | asymmetric catalysis | Stetter reaction | umpolung | N-heterocyclic carbenes | NHC CATALYSIS | ASYMMETRIC-SYNTHESIS | ENANTIOSELECTIVE SYNTHESIS | ALPHA-KETO ESTERS | EFFICIENT SYNTHESIS | QUATERNARY STEREOCENTERS | CHEMISTRY, ORGANIC | DYNAMIC KINETIC RESOLUTION | CATALYZED BENZOIN CONDENSATION | CARBON-CARBON | ACTIVATED DOUBLE-BONDS
Journal Article
CHEMICAL SCIENCE, ISSN 2041-6520, 05/2019, Volume 10, Issue 19, pp. 5176 - 5182
We describe the development of Pd-PHOX-catalysed enantioselective couplings of internal dienes with malononitrile and other activated C-pronucleophiles.... 
ASYMMETRIC ALLYLIC ALKYLATION | CARBONYL SURROGATES | VICINAL TERTIARY | 1,3-DIENES | INTERMOLECULAR HYDROAMINATION | CONSTRUCTION | ALLYLATION | QUATERNARY STEREOCENTERS | ALLENES | CHEMISTRY, MULTIDISCIPLINARY | DIASTEREO
Journal Article
RSC Advances, ISSN 2046-2069, 06/2015, Volume 5, Issue 65, pp. 52481 - 52496
3-Substituted-3-aminooxindoles have attracted the attention of organic and medicinal chemists because these motifs constitute the core structure of a number of... 
AZA-HENRY REACTION | HIGHLY ENANTIOSELECTIVE SYNTHESIS | MANNICH REACTION | MORITA-BAYLIS-HILLMAN | DIASTEREOSELECTIVE SYNTHESIS | QUATERNARY STEREOCENTERS | EFFICIENT SYNTHESIS | N-HETEROCYCLIC CARBENES | ORGANOCATALYTIC ASYMMETRIC-SYNTHESIS | CHEMISTRY, MULTIDISCIPLINARY | CONJUGATE ADDITION
Journal Article
Chemical science (Cambridge), ISSN 2041-6520, 09/2015, Volume 6, Issue 9, pp. 5164 - 5171
Taddol-based phosphoramidite ligands enable enantioselective palladium(0)-catalyzed C-H arylation of cyclopropanes. The cyclized products are obtained in high... 
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 08/2018, Volume 140, Issue 34, pp. 10687 - 10690
We report an asymmetric synthesis of chiral boryl-functionalized γ-lactams containing all-carbon quaternary stereocenters via a Co-catalyzed enantioselective... 
1,6-ENYNES | RHODIUM | NATURAL-PRODUCTS | STEREOCENTERS | GAMMA-LACTAMS | ENYNE CYCLOISOMERIZATION | ALDEHYDES | ASYMMETRIC HYDROGENATION | C-H FUNCTIONALIZATION | REDUCTIVE CYCLIZATION | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Nature Communications, ISSN 2041-1723, 12/2017, Volume 8, Issue 1, pp. 567 - 9
Although chiral allene preparation via formal S(N)2' nucleophilic substitutions of enantioen-riched propargylic derivatives or metal-catalyzed reactions of... 
BRONSTED ACID | ACTIVATION | ENANTIOSELECTIVE SYNTHESIS | MECHANISM | ALLENOATES | MULTIDISCIPLINARY SCIENCES | CARBON QUATERNARY STEREOCENTERS | ISOMERIZATION | CATALYTIC ASYMMETRIC-SYNTHESIS | DERIVATIVES | DISCOVERY | Construction | Quaternary | Quinone | Chemical reactions | Alcohol | Derivatives | Enantiomers | Alcohols | Allene | Natural products | Chirality | Biocompatibility | Catalysis | Chemical synthesis
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 01/2018, Volume 57, Issue 2, pp. 496 - 500
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 11/2018, Volume 54, Issue 91, pp. 12852 - 12855
A new asymmetric catalytic propargyl- and allylboration of hydrazonoesters is reported. The reactions utilize allenyl- and allylboronic acids in the presence... 
HYDRAZONES | PALLADIUM | QUATERNARY STEREOGENIC CENTERS | ENANTIOSELECTIVE SYNTHESIS | IMINES | STEREOCENTERS | ALLYLATION | CARBONYL-COMPOUNDS | ALLYLBORONIC ACIDS | ALDEHYDES | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Chemical Science, ISSN 2041-6520, 2018, Volume 9, Issue 13, pp. 3276 - 3281
Direct access to pharmaceutically attractive benzo-fused nine-membered heterocyclic alkenes 3 with a trifluoromethyl carbinol moiety was achieved via a... 
CYCLOADDITION | ASYMMETRIC-SYNTHESIS | ENANTIOSELECTIVE SYNTHESIS | VINYLETHYLENE CARBONATES | FLUORINATED HETEROCYCLES | QUATERNARY STEREOCENTERS | HIV-1 REVERSE-TRANSCRIPTASE | INHIBITORS | DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY | GATED CHLORIDE CHANNELS
Journal Article