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Angewandte Chemie International Edition, ISSN 1433-7851, 04/2017, Volume 56, Issue 18, pp. 4955 - 4959
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 06/2019, Volume 25, Issue 34, pp. 8053 - 8060
Pyran‐2‐ones 3 undergo a novel Pd0‐catalyzed 1,3‐rearrangement to afford isomers 6. The reaction proceeds via an η2‐Pd complex, the pyramidalization of which... 
catalysis | palladium | stereoelectronic effects | quantum chemistry calculations | allylic rearrangement | Palladium | Catalysis | Organic chemistry | Transposition | Recombination | Quantum chemistry | Mathematical analysis | Reaction kinetics | Substitution reactions | Kinetics | Isomers
Journal Article
CHEMISTRY-A EUROPEAN JOURNAL, ISSN 0947-6539, 06/2019, Volume 25, Issue 34, pp. 8053 - 8060
Pyran-2-ones 3 undergo a novel Pd-0-catalyzed 1,3-rearrangement to afford isomers 6. The reaction proceeds via an eta(2)-Pd complex, the pyramidalization of... 
CONVENIENT SYNTHESIS | stereoelectronic effects | COMPLEXES | CORRELATION-ENERGY | catalysis | quantum chemistry calculations | OXIDATIVE ADDITION | CIS | STEREOCHEMICAL INHIBITION | CHEMISTRY, MULTIDISCIPLINARY | allylic rearrangement | CROSS-COUPLING REACTIONS | INTRAMOLECULAR 1,2 SHIFTS | SYN-ANTI DICHOTOMY | palladium | ASYMMETRIC ALLYLATION
Journal Article
Tetrahedron, ISSN 0040-4020, 2007, Volume 63, Issue 28, pp. 6485 - 6492
A novel and efficient synthesis of (−)-8- epi-swainsonine 2 is reported. Stereocontrolled diol formation from the bicyclic alkene 3 followed by a... 
Stereoelectronic | Indolizidine synthesis | Metathesis | Stereoselective | ALCOHOLS | ACID | PYRROLIDINES | ANALOGS | (-)-SWAINSONINE | ALPHA-MANNOSIDASE | SWAINSONINE | PURIFICATION | CHEMISTRY, ORGANIC | INHIBITORS | DEPROTECTION
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 06/2019, Volume 25, Issue 34, pp. 7955 - 7955
A new insight into Pd‐catalyzed allylic substitution shows that it is the pyramidalization of the C−C moiety of the initially formed η2‐palladacycle that plays... 
stereoelectronic effects | catalysis | palladium | quantum chemistry calculations | allylic rearrangement
Journal Article
Synlett, ISSN 0936-5214, 04/2016, Volume 27, Issue 7, pp. 1051 - 1055
Abstract Achieving acyclic conformational control over several bonds has been realized by the strategic installation of a vicinal difluoroethane bridge in a... 
cluster | organocatalysis | stereoelectronic effect | conformational analysis | computation | fluorine | DENSITY | ENANTIOSELECTIVE AZIRIDINATION | ENERGY | PHASE | MODELS | REACTIVITY | CHEMISTRY, ORGANIC
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 04/2011, Volume 52, Issue 15, pp. 1762 - 1765
Interesting norbornane-fused tetrahydrofurans, with an additional synthetically-valuable vicinal dioxy-substitution in the norbornane skeleton, are... 
Domino reactions | Stereoelectronic effects | Rearrangements | 1-Norbornyl cations | RATES | SCOPE | CHEMISTRY, ORGANIC | CAMPHORS | Bromine | Camphor | Tetrahedrons | Tetrahydrofuran | Solvolysis | Derivatives | Cascade chemical reactions
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 01/2018, Volume 83, Issue 1, pp. 203 - 219
The mechanisms of intramolecular cyclization of 3-sulfonyloxyimino-2-methyl-1-phenyl-1-butanones (1) under basic (DABCO and t-BuOK) and acidic (AcOH and TFA)... 
H FUNCTIONALIZATION | RADICAL RING-CLOSURE | ORGANIC-CHEMISTRY | PHOTOCHEMICAL TRANSPOSITION | STEREOELECTRONIC CONTROL | AMBIDENT REACTIVITY | STEREOCHEMICAL CONTROL | TRANSITION STRUCTURES | CHEMISTRY, ORGANIC | ELECTRON-TRANSFER REACTIONS | NEBER REARRANGEMENT | Usage | Ketones | Methyl groups | Ring formation (Chemistry) | Chemical properties | Research | Enolates
Journal Article
高等学校化学研究:英文版, ISSN 1005-9040, 2013, Volume 29, Issue 3, pp. 551 - 555
Journal Article
Tetrahedron, ISSN 0040-4020, 2002, Volume 58, Issue 47, pp. 9559 - 9566
Ring opening of oxazolidines derived from tris(hydroxymethyl)aminomethane, l-serine and l-threonine was investigated. It was shown that n(N)→σ ∗(C–O) electron... 
crystal structure | ring-opening | oxazolidines | stereoelectronic control | Stereoelectronic control | Oxazolidines | Ring-opening | Crystal structure | ASYMMETRIC-SYNTHESIS | ACID | CHEMISTRY, ORGANIC | DERIVATIVES | Polymers | Organic chemistry | Chemical Sciences
Journal Article
JOURNAL OF ORGANIC CHEMISTRY, ISSN 0022-3263, 01/2020, Volume 85, Issue 2, pp. 758 - 773
The glycosylation stereoselectivities for a series of bicyclic furanoside models have been carried out in the presence of weak nucleophiles. These results were... 
SUBSTITUTION | ANOMERIC CENTER | SIMPLE-MODEL | STEREOELECTRONIC CONTROL | ANTIPERIPLANAR HYPOTHESIS | NUCLEOPHILIC ADDITIONS | OXIDATIVE LACTONIZATION | CHEMISTRY, ORGANIC | GAMMA-LACTOLS | BONDS TAU | RING OXOCARBENIUM IONS
Journal Article
CHEMBIOCHEM, ISSN 1439-4227, 04/2019, Volume 20, Issue 7, pp. 963 - 967
The preferred conformations of peptides and proteins are dependent on local interactions that bias the conformational ensemble. The n ->pi* interaction between... 
SYSTEM | conformation analysis | CHEMISTRY, MEDICINAL | stereoelectronic effects | OGLCNACYLATION | PHOSPHORYLATION | STABILITY | BIOCHEMISTRY & MOLECULAR BIOLOGY | amino acids | peptides | ORGANIC FLUORINE | hyperconjugation
Journal Article
Journal of Fluorine Chemistry, ISSN 0022-1139, 09/2015, Volume 177, pp. 29 - 36
The function of liquid crystals for LCD applications depends critically on the presence of fluorine. The effects of fluorination include reliability... 
Hypervalent sulfur fluorides | Electronegativity | Stereoelectronic effects | Liquid crystals | Fluorine effects | Conformation control | PHASE | DIELECTRIC ANISOTROPY | CHEMISTRY, ORGANIC | TRANSITION-TEMPERATURES | CHEMISTRY, INORGANIC & NUCLEAR | Fluorides
Journal Article
Nature Chemistry, ISSN 1755-4330, 2015, Volume 7, Issue 2, pp. 171 - 177
5-Endo-trig cyclizations are generally considered to be kinetically unfavourable, as described by Baldwin's rules. Consequently, observation of this mode of... 
ELECTROCYCLIZATION | STEREOELECTRONIC CONTROL | AMMONIUM BROMIDES | ALPHA-AMINO | ASYMMETRIC-SYNTHESIS | AMBIDENT REACTIVITY | PHASE-TRANSFER CATALYSIS | RULES | CHEMISTRY, MULTIDISCIPLINARY | RING-CLOSURE | MICHAEL ADDITION | Stereoselectivity | Ammonium | Trajectories | Selectivity | Enantiomers | Chemical synthesis | Michael reaction
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 12/2017, Volume 82, Issue 23, pp. 12613 - 12623
Straightforward S–S bond formation via the oxidation of S-acetyl group by iodine was reported here. The reaction was further applied in the synthesis of... 
STEREOELECTRONIC CONTROL | GLYCOSYL DISULFIDES | SPECTROSCOPY | ANALOGS | ACYL GROUP MIGRATION | BIOLOGICAL EVALUATION | CHEMISTRY, ORGANIC | SULFONAMIDES | SULFUR | GLYCOMIMETICS | ELABORATION | Thiols | Chemical properties | Iodides | Chemical synthesis | Analysis
Journal Article
Wiley Interdisciplinary Reviews: Computational Molecular Science, ISSN 1759-0876, 01/2011, Volume 1, Issue 1, pp. 109 - 141
Journal Article