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Organic Letters, ISSN 1523-7060, 03/2013, Volume 15, Issue 6, pp. 1266 - 1269
An efficient synthesis of enantioenriched α-substituted γ-hydroxy esters via a kinetic resolution event is described. Bulky racemic esters in the presence of a... 
CHEMISTRY, ORGANIC | STEREOSELECTIVE-SYNTHESIS
Journal Article
Synthesis, ISSN 0039-7881, 02/2012, Volume 44, Issue 3, pp. 351 - 361
Abstract This short review describes new developments in palladium-catalyzed aminoarylation reactions between aryl halides and alkenes bearing pendant nitrogen... 
review | heterocycles | stereoselective synthesis | amines | catalysis | palladium | alkenes | arylation | CARBOAMINATION REACTIONS | CHEMISTRY, ORGANIC | (+)-APHANORPHINE | (-)-APHANORPHINE | SPIROOXINDOLES | PYRROLIDINES | CARBOETHERIFICATION | BONDS | STEREOSELECTIVE-SYNTHESIS | DERIVATIVES | ARYL CHLORIDES
Journal Article
Journal of Hazardous Materials, ISSN 0304-3894, 08/2019, Volume 375, pp. 26 - 32
The worldwide environmental occurrence of natural steroid estrogens has drawn increasing concerns. However, the fate of the estrogens, especially the α-isomer... 
Estradiol isomers | C-labelling | Estrogens | Stereoselective synthesis
Journal Article
Organic Letters, ISSN 1523-7060, 11/2017, Volume 19, Issue 21, pp. 5830 - 5832
The first regioselective synthesis of polysubstituted 1,2-oxazetidines, based on the [2 + 1 + 1] radical tandem cycloaddition of styrenes, arylamines, and... 
CHEMISTRY, ORGANIC | KETONES | STEREOSELECTIVE-SYNTHESIS | HETEROCYCLES
Journal Article
Chemical Society Reviews, ISSN 0306-0012, 2011, Volume 40, Issue 11, pp. 5336 - 5346
Homoenolate is a reactive intermediate that possesses an anionic or nucleophilic carbon beta to a carbonyl group or its synthetic equivalent. The recent... 
CARBENE | FORMAL SYNTHESIS | ALPHA,BETA-UNSATURATED ALDEHYDES | ESTERS | EFFICIENT SYNTHESIS | STEREOSELECTIVE-SYNTHESIS | SALINOSPORAMIDE | EQUIVALENTS | CHEMISTRY, MULTIDISCIPLINARY | DIRECT ANNULATIONS | ENALS
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 08/2012, Volume 134, Issue 33, pp. 13565 - 13568
A Rh-catalyzed intermolecular coupling of diazomalonates with arene C–H bonds is reported. The reaction is initiated by electrophilic C–H activation, which is... 
PALLADIUM | ACTIVATION | INSERTION | CROSS-COUPLING REACTION | ARYL | ALDEHYDES | STEREOSELECTIVE-SYNTHESIS | N-CHLOROAMINES | TERT-BUTYL HYDROPEROXIDE | CHEMISTRY, MULTIDISCIPLINARY | DIAZOESTERS
Journal Article
Organic and Biomolecular Chemistry, ISSN 1477-0520, 2018, Volume 16, Issue 36, pp. 6652 - 6654
A three-component synthesis of homoallylic amines is described. The allylboronic species were generated in situ by homologation of vinyl boroxines with... 
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 04/2016, Volume 138, Issue 16, pp. 5210 - 5213
Novel boron-fused double [5]­helicenes were synthesized from hexabromobenzene in two steps via Hart reaction and demethylative cyclization. The parent helicene... 
STEREOSELECTIVE SYNTHESES | PLANAR | ONE HUNDRED YEARS | ANNULATION | CHEMISTRY, MULTIDISCIPLINARY | Chemical synthesis | Boron | Analysis
Journal Article
Organic & biomolecular chemistry, ISSN 1477-0520, 05/2018, Volume 16, Issue 21, pp. 3989 - 3998
The first example of employing a mixed carboxylic-sulfonic anhydride in reaction with imines is reported. Unlike its well-studied isostere homophthalic... 
Journal Article
Chemical Reviews, ISSN 0009-2665, 07/2017, Volume 117, Issue 13, pp. 8754 - 8786
This Review summarizes the advancements in Pd-catalyzed C­(sp3)–H activation via various redox manifolds, including Pd(0)/Pd­(II), Pd­(II)/Pd­(IV), and... 
UNACTIVATED C(SP)-H BONDS | CROSS-COUPLING REACTIONS | DIRECT ARYLATION | BETA-C(SP)-H ARYLATION | INTERMOLECULAR AMINATION | O-ALLYL ETHERS | ALIPHATIC CARBON-ATOMS | ALPHA-AMINO-ACIDS | STEREOSELECTIVE-SYNTHESIS | DIRECTING-GROUP | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Chemical Society Reviews, ISSN 0306-0012, 1/2012, Volume 41, Issue 2, pp. 643 - 665
In this critical review , the ring opening of non-activated 2-substituted aziridines via intermediate aziridinium salts will be dealt with. Emphasis will be... 
TRANSFORMATION | ASYMMETRIC-SYNTHESIS | AMINO-ACIDS | EFFICIENT SYNTHESIS | IONS | STEREOSELECTIVE-SYNTHESIS | CHIRAL AZIRIDINES | CLEAVAGE | DERIVATIVES | SALTS | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Organic Letters, ISSN 1523-7060, 2019, Volume 21, Issue 13, pp. 4950 - 4954
A multicomponent sulfonylation of O-aryl oximes via iminyl radicals with the insertion of sulfur dioxide under photoredox catalysis is achieved. This... 
QUINOLINE N-OXIDES | 2-AZA-21-CARBAPORPHYRIN | NORCORROLE | METABISULFITE | CHEMISTRY | CHEMISTRY, ORGANIC | METAL | STEREOSELECTIVE-SYNTHESIS | DERIVATIVES | AMINOSULFONYLATION | CARBOXYLIC-ACIDS
Journal Article
Tetrahedron, ISSN 0040-4020, 2011, Volume 67, Issue 33, pp. 5851 - 5870
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 1900, Volume 137, Issue 15, pp. 4908 - 4911
The first example of Rh­(III)-catalyzed cyclization of arylnitrones to indolines under external oxidant-free conditions is presented. An intermolecular... 
FUNCTIONALIZATION | QUINOLINE N-OXIDES | PALLADIUM | CYCLOADDITION | AMINATION | NITRONES | BOND FORMATION | STEREOSELECTIVE-SYNTHESIS | ALKYNES | DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Organic Letters, ISSN 1523-7060, 05/2019, Volume 21, Issue 10, pp. 3755 - 3759
Dual photoredox transition-metal catalysis has recently emerged as a powerful tool for making synthetically challenging carbon-carbon bonds under milder... 
ENONES | CHEMISTRY, ORGANIC | ALDEHYDES | STEREOSELECTIVE-SYNTHESIS | ALKYLATION | COBALT
Journal Article
Organic Letters, ISSN 1523-7060, 10/2017, Volume 19, Issue 20, pp. 5681 - 5684
Spurred on by the recent emerging interest from the chemical community for unsaturated four-membered heterocycles, an unprecedented approach to... 
CONVENIENT SYNTHESIS | CYCLOADDITION | AZETIDINES | CHEMISTRY, ORGANIC | STEREOSELECTIVE-SYNTHESIS | ACCESS | SKELETON
Journal Article
Nature Communications, ISSN 2041-1723, 03/2017, Volume 8, Issue 1, p. 14841
Although great success has been achieved in asymmetric fluoroalkylation reactions via nucleophilic or electrophilic processes, the development of asymmetric... 
BRONSTED ACID | VISIBLE-LIGHT | PALLADIUM | DIFLUOROMETHYLATION | MULTIDISCIPLINARY SCIENCES | ARYLATION | FUNCTIONAL-GROUPS | COPPER | STEREOSELECTIVE-SYNTHESIS | DIFLUOROALKYLATION | TRIFLUOROMETHYLTHIOLATION REACTIONS
Journal Article