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Angewandte Chemie (International ed.), ISSN 1433-7851, 08/2018, Volume 57, Issue 32, pp. 10127 - 10131
The first synthesis of polyflavanostilbene B (1), which has seven contiguous stereocenters including two quaternary carbon centers, from abundant polymeric... 
iron | radical cyclization | natural product synthesis | spiro compounds | Furans | Synthesis | Resveratrol | Organic compounds | Stereoselectivity | Protecting groups | Substitution reactions | Iron | Chemical synthesis | Epicatechin
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 03/2016, Volume 55, Issue 13, pp. 4332 - 4335
A highly efficient 12‐step synthesis of the marine alkaloid (−)‐nakadomarin A has been... 
natural products | Overman rearrangement | total synthesis | ring-closing metathesis | alkaloids | Carbolines - chemical synthesis | Stereoisomerism | Alkaloids | Synthesis | Organic compounds | Amination | Ketones | Chemical synthesis | Metathesis
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 05/2016, Volume 55, Issue 20, pp. 6067 - 6070
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 03/2017, Volume 56, Issue 11, pp. 3055 - 3058
.... In the presence of a chiral SaBOX ligand, excellent enantioselectivity was realized with up to 94 % ee. This novel synthetic method is applied as a general protocol for the total synthesis... 
cyclobutanes | natural products | diastereoselectivity | annulations | heterocycles | Synthesis | Organic compounds | Organic chemistry | Heterocyclic compounds | Indole | Ligands | Chemical reactions | Strychnine | Catalysis | Indoles | Enantiomers | Chemical synthesis
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 05/2016, Volume 55, Issue 22, pp. 6556 - 6560
A seven‐step enantioselective total synthesis of (−)‐terengganensine A, a complex heptacyclic monoterpene indole alkaloid, was accomplished. Key steps included... 
asymmetric synthesis | domino cyclization | total synthesis | hydroxylation | monoterpene indole alkaloids | Synthesis | Hydroxylation | Enantiomers | Hydrogenation | Organic compounds
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 03/2016, Volume 55, Issue 12, pp. 4064 - 4068
The first total synthesis of the alkaloid (−)‐haliclonin A is reported. The asymmetric synthesis relied on a novel organocatalytic asymmetric conjugate addition of nitromethane with 3‐alkenyl cyclohex‐2... 
natural products | total synthesis | metathesis | macrocycles | alkaloids | Diamines - chemical synthesis | Macrocyclic Compounds - chemical synthesis | Catalysis | Aldehydes | Synthesis | Organic compounds
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 04/2019, Volume 58, Issue 17, pp. 5754 - 5757
Journal Article
Chemistry : a European journal, ISSN 0947-6539, 2015, Volume 21, Issue 14, pp. 5311 - 5316
Macrocyclic natural products (NPs) and analogues thereof often show high affinity, selectivity, and metabolic stability, and methods for the synthesis of NP-like macrocycle collections are of major current interest... 
Research Support, Non-U.S. Gov't | Journal Article | cyclodepsipeptides | natural products | macrocycle | solid‐phase synthesis | relay‐ring‐closing metathesis | relay-ring-closing metathesis | solid-phase synthesis | Solid-Phase Synthesis Techniques | Biological Products - chemical synthesis | Biological Products - chemistry | Cyclization | Depsipeptides - chemical synthesis | Depsipeptides - chemistry
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 2019, Volume 58, Issue 8, pp. 2490 - 2494
The first asymmetric total synthesis of the meroterpenoid (−)‐merochlorin A is described. The route features enantiospecific gold... 
gold | natural products | total synthesis | cascade | aldol | Precious metal products | Synthesis | Organic compounds | Gold | Cycloaddition | Nucleotide sequence | Migration | Absolute configuration | Aldehydes | Resorcinol
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 10/2018, Volume 57, Issue 40, pp. 13313 - 13318
The first and enantioselective total synthesis of (+)‐plumisclerin A, a novel unique complex cytotoxic marine diterpenoid, has been accomplished... 
enantioselective synthesis | plumisclerin A | samarium diiodide | total synthesis | conjugate addition | plumisclerin A | Palladium | Synthesis | Enantiomers | Organic compounds | Organic chemistry | Cytotoxicity | Cyclopentane | Michael reaction | Carbonyls
Journal Article