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Tetrahedron, ISSN 0040-4020, 08/2019, Volume 75, Issue 31, pp. 4081 - 4085
We report the synthesis and characterization of novel anionic arylfluoroborate, three-coordinate ligated arylcopper(I) and cationic ligated copper(I)... 
Arylcopper(I) | arylboronate | Cationic | Transmetalation | Arylfluoroboronate
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 03/2018, Volume 24, Issue 13, pp. 3069 - 3069
Selective transformation of alkenyllithiums to alkenylmagnesiums via simple transmetalation has been achieved. The synthesis, structure, and mutual... 
1,4-dilithio-1,3-butadienes | lithium | magnesium | metallacycles | transmetalation
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 04/2012, Volume 134, Issue 13, pp. 5794 - 5797
The ability of two common protected forms of amines (carbamates and sulfonamides) to serve as directing groups in Ni-catalyzed Suzuki reactions has been... 
ALKYLBORANES | CHEMISTRY, MULTIDISCIPLINARY | TRANSMETALATION | STEREOCHEMISTRY
Journal Article
ACS Catalysis, ISSN 2155-5435, 2015, Volume 5, Issue 5, pp. 3040 - 3053
The first now-named Stille reaction was published 38 years ago, and the last comprehensive revision of this catalysis was in 2004. Since then, the knowledge of... 
tin | palladium | Stille cross-coupling | reaction mechanism | transmetalation | CHEMISTRY, PHYSICAL | OXIDATIVE ADDITION | STANNYLATED POLYNORBORNENES | REDUCTIVE ELIMINATION | PALLADIUM(II) COMPLEXES | CROSS-COUPLING REACTIONS | ACYL CHLORIDES | ARYL HALIDES | SUPPORTED ORGANOTIN REAGENTS | DENSITY-FUNCTIONAL THEORY | TRANSMETALATION STEP
Journal Article
Chemistry - A European Journal, ISSN 0947-6539, 08/2018, Volume 24, Issue 46, pp. 11895 - 11898
This work describes the employment of discrete "AgCF " complexes as efficient transmetalating agents to Pd to surmount overlooked challenges related to the... 
structural elucidation | silver | trifluoromethylation | organometallic synthesis | transmetalation
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 08/2018, Volume 24, Issue 46, pp. 11805 - 11805
Organosilver(I) species have previously demonstrated their potential as coupling partners in Pd‐catalyzed transformations, but this ability is far from being... 
organometallic synthesis | structural elucidation | silver | trifluoromethylation | transmetalation
Journal Article
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, ISSN 1433-7851, 11/2018, Volume 57, Issue 46, pp. 15081 - 15085
The transmetalation is a key elementary step in cross-coupling reactions. Yet, the precise nature of its mechanism and transition state geometry are frequently... 
COMPLEXES | silanes | stannanes | FORMING REDUCTIVE ELIMINATION | OXIDATIVE ADDITION | CHEMISTRY, MULTIDISCIPLINARY | CROSS-COUPLING REACTIONS | reaction mechanism | COMPUTATIONAL CHARACTERIZATION | FLUORINE | trifluoromethylation | ARYL | STILLE REACTION | transmetalation | TRANSMETALATION STEP | BOND-FORMATION
Journal Article
Chemical Reviews, ISSN 0009-2665, 09/2017, Volume 117, Issue 18, pp. 11796 - 11893
Flow chemistry involves the use of channels or tubing to conduct a reaction in a continuous stream rather than in a flask. Flow equipment provides chemists... 
LUMINESCENT SOLAR CONCENTRATOR | CROSS-COUPLING REACTIONS | ASYMMETRIC ALDOL REACTION | DIELS-ALDER REACTIONS | VISIBLE-LIGHT PHOTOCATALYSIS | SUPERCRITICAL CARBON-DIOXIDE | SUPPORTED PALLADIUM CATALYSTS | FORMAL TOTAL-SYNTHESIS | SINGLE-ELECTRON TRANSMETALATION | IN-SITU GENERATION | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Organic Letters, ISSN 1523-7060, 06/2011, Volume 13, Issue 12, pp. 3040 - 3043
Readily available alkenylalanes, arising from hydroalumination of unprotected terminal alkynes, have been directly employed for the copper-catalyzed asymmetric... 
CHEMISTRY, ORGANIC | ARYL | LIGANDS | ALKYNES | TRANSMETALATION
Journal Article
Journal of Organic Chemistry, ISSN 0022-3263, 08/2015, Volume 80, Issue 16, pp. 7837 - 7848
Over the past two decades, organotrifluoroborates have evolved from being chemical curiosities to important reagents for the elaboration of organic molecules.... 
SUZUKI | SOLVOLYSIS | CROSS-COUPLING REACTIONS | BORONIC ACID | AMINOMETHYLATIONS | SCOPE | POTASSIUM ARYL | CHEMISTRY, ORGANIC | SINGLE-ELECTRON TRANSMETALATION | SALTS | ACCESS
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 09/2010, Volume 132, Issue 38, pp. 13191 - 13193
The first invertive B-alkyl Suzuki−Miyaura coupling has been achieved. The coupling of enantioenriched α-(acylamino)benzylboronic esters with aryl bromides and... 
HALIDES | PALLADIUM | ACID | C-N | RETENTION | TRANSMETALATION | STEREOCHEMISTRY | ALKYLBORANES | ARYL | DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
ACS Catalysis, ISSN 2155-5435, 02/2016, Volume 6, Issue 2, pp. 873 - 877
We describe carbazolyl dicyanobenzene (CDCB)-based donor–acceptor (D–A) fluorophores as a class of cheap, easily accessible, and efficient metal-free... 
cross-coupling | photoredox catalysis | visible light | donor-acceptor fluorophores | nickel catalysis | OXIDATION | HALIDES | MERGING PHOTOREDOX | ACIDS | PHOTOCATALYSIS | CHEMISTRY, PHYSICAL | SINGLE-ELECTRON TRANSMETALATION | SYSTEMS | METAL-FREE | TRANSFORMATIONS
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 03/2013, Volume 135, Issue 9, pp. 3303 - 3306
Stereospecific coupling of benzylic carbamates and pivalates with aryl- and heteroarylboronic esters has been developed. The reaction proceeds with selective... 
PALLADIUM | CARBON | ACIDS | TRIARYLMETHANES | TRANSMETALATION | ARYLATION | BONDS | OXIDATIVE-ADDITION | ALKYLBORANES | CHEMISTRY, MULTIDISCIPLINARY | ALKYL-HALIDES
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 09/2011, Volume 50, Issue 17, pp. 7934 - 7936
We describe a selective and template-controlled synthesis of a series of Zn8 metal complexes based on a bis-nucleating salen ligand scaffold. Our results, a... 
BASE COMPLEX | LIGANDS | SITE-SELECTIVE TRANSMETALATION | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
ACS Catalysis, ISSN 2155-5435, 09/2017, Volume 7, Issue 9, pp. 5643 - 5653
Journal Article
Chemical Communications, ISSN 1359-7345, 2017, Volume 53, Issue 97, pp. 13027 - 13030
We have successfully obtained heterometallic oxides and/or carbides that are calcined from a new bimetallic metal-organic framework (InOF-16,... 
STORAGE | WATER OXIDATION | METAL-ORGANIC FRAMEWORKS | CHEMISTRY, MULTIDISCIPLINARY | TRANSMETALATION | CARBON NANOTUBES
Journal Article
Chemical Reviews, ISSN 0009-2665, 08/2018, Volume 118, Issue 16, pp. 7532 - 7585
Transition metal-catalyzed C–H bond functionalizations have been the focus of intensive research over the last decades for the formation of C–C bonds from... 
H FUNCTIONALIZATION | ROOM-TEMPERATURE | DIRECT ARYLATION | ARYL DIAZONIUM SALTS | VISIBLE-LIGHT PHOTOREDOX | PYRIDINE N-OXIDES | SINGLE-ELECTRON TRANSMETALATION | MEDIATED RADICAL ARYLDIFLUOROACETYLATION | CHEMISTRY, MULTIDISCIPLINARY | METAL-FREE | CARBOXYLIC-ACIDS | Chemical Sciences
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 05/2012, Volume 51, Issue 20, pp. 4917 - 4920
It's the second step that counts: Arylation of Pd by Au takes place through transition states and intermediates featuring strong Au⋅⋅⋅Pd metallophilic... 
gold | reaction mechanisms | palladium | homogeneous catalysis | transmetalation | CATALYSIS | CROSS-COUPLING REACTIONS | DFT | COMPLEXES | CHEMISTRY, MULTIDISCIPLINARY | STILLE REACTION | TRANSMETALATION STEP | Pictures | Gold | Amines | Joining | Palladium | Counting | Organic compounds
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 12/2018, Volume 24, Issue 72, p. n/a
Alkenyl magnesium compounds are frequently used in organic synthesis and they are often proposed as active intermediates in organic synthesis. Currently, there... 
carbenoids | Grignard reagents | magnesium | carbocycles | transmetalation | Magnesium | Magnesium compounds | Reagents | Intermediates
Journal Article
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