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Inorganic Chemistry, ISSN 0020-1669, 09/2018, Volume 57, Issue 17, pp. 11193 - 11200
The protonolysis of C–Au bonds in [AuRL] organometallic complexes has been studied by calorimetry for 12 R groups. The experimental data have been combined... 
Journal Article
Organic Letters, ISSN 1523-7060, 02/2018, Volume 20, Issue 3, pp. 760 - 763
An efficient cross-coupling of sodium or lithium sulfinates with aryl iodides, using a combination of nickel and photoredox catalysis, is described. The dual... 
HALIDES | SODIUM | NICKEL CATALYSIS | SULFUR-DIOXIDE | CHEMISTRY, ORGANIC | SULFONES | INHIBITORS | SINGLE-ELECTRON TRANSMETALATION
Journal Article
ACS Catalysis, ISSN 2155-5435, 10/2019, Volume 9, Issue 10, pp. 9231 - 9236
The development of orthogonal C sp 2 –C sp 2 coupling regimes to the omnipresent Pd-catalysis class would enable an additional dimension of modularity in the... 
cross-coupling | gold catalysis | CH functionalization | organogermanium | transmetalation
Journal Article
Chemical Society Reviews, ISSN 0306-0012, 3/2012, Volume 41, Issue 8, pp. 3129 - 3139
Homogeneous gold catalysis has been one of the most active research fields in organic chemistry for more than a decade, and it has been also among the most... 
PALLADIUM | CROSS-COUPLING REACTIONS | ACTIVATION | GOLD-CATALYSIS | RHODIUM TRANSMETALATION | C BOND | GLYCOSYL ORTHO-ALKYNYLBENZOATES | HYDROAMINATION | ALKYNES | CHEMISTRY, MULTIDISCIPLINARY | ELEMENTARY STEPS
Journal Article
Crystal Growth & Design, ISSN 1528-7483, 04/2017, Volume 17, Issue 4, pp. 1450 - 1455
Emerging as a new family of hybrid crystalline materials, bimetallic porous metal–organic frameworks (MOFs) have received great attention in gas storage and... 
CATION-EXCHANGE | MOF | BUILDING-BLOCKS | MATERIALS SCIENCE, MULTIDISCIPLINARY | CO2 | HYDROGEN ADSORPTION | ION-EXCHANGE | CRYSTALLOGRAPHY | ADSORPTION PROPERTIES | CHEMISTRY, MULTIDISCIPLINARY | ZEOLITIC IMIDAZOLATE FRAMEWORKS | SINGLE-CRYSTAL | TRANSMETALATION
Journal Article
Tetrahedron, ISSN 0040-4020, 2004, Volume 60, Issue 6, pp. 1269 - 1279
Recent progress in the preparation of alkenylzirconocenes, the transmetalation of zirconium to zinc, palladium, and rhodium, and lithium carbenoid insertions... 
Organic synthesis | Alkenylzirconocenes | Transmetalation
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 08/2016, Volume 52, Issue 66, pp. 10163 - 10166
A dual visible light photoredox and gold-catalysed C(sp(2))-C(sp(2)) cross coupling is described. The success of this mild, oxidant- and base-free cross... 
Journal Article
ACS Catalysis, ISSN 2155-5435, 04/2017, Volume 7, Issue 4, pp. 2563 - 2575
Photoredox catalysis has experienced a revitalized interest from the synthesis community during the past decade. For example, photoredox/Ni dual catalysis... 
cross-coupling | nickel | catalysis | dual catalysis | photoredox | radicals | VISIBLE-LIGHT PHOTOCATALYSIS | TRANSITION-METAL-COMPLEXES | CHEMISTRY, PHYSICAL | CARBONYL-COMPOUNDS | SINGLE-ELECTRON TRANSMETALATION | C-H BONDS | PHENOL DERIVATIVES | BIDENTATE-CHELATION ASSISTANCE | CROSS-COUPLING REACTIONS | BORYLATED ARYL BROMIDES
Journal Article
Chemical Science, ISSN 2041-6520, 02/2015, Volume 6, Issue 2, pp. 1115 - 1119
The nickel-catalyzed cross-coupling of aryl halides with alkyl radicals derived from alkyl halides has recently been extended to couplings with carbon radicals... 
STEREOSPECIFIC FORMATION | REAGENTS | TRANSMETALATION | STEREOCHEMISTRY | CHLORIDES | ORGANOBORONIC ESTERS | FUNCTIONAL-GROUP-TOLERANT | BROMIDES | CHEMISTRY, MULTIDISCIPLINARY | ARYLBORONIC ACIDS | ALKYL-HALIDES
Journal Article
Chemical Science, ISSN 2041-6520, 2015, Volume 6, Issue 9, pp. 5105 - 5113
Several research groups have recently developed methods to employ configurationally stable, enantioenriched organometallic nucleophiles in stereospecific... 
Journal Article
Chemical Science, ISSN 2041-6520, 8/2015, Volume 6, Issue 9, pp. 515 - 5113
Several research groups have recently developed methods to employ configurationally stable, enantioenriched organometallic nucleophiles in stereospecific... 
PALLADIUM | HYDROBORATION | ACID | MOLECULAR-STRUCTURE | STEREOCHEMISTRIES | RETENTION | TRANSMETALATION | SECONDARY | STILLE | BORONIC ESTERS | CHEMISTRY, MULTIDISCIPLINARY | Chemistry
Journal Article
Organic Letters, ISSN 1523-7060, 09/2018, Volume 20, Issue 17, pp. 5233 - 5237
An iron-catalyzed cross-coupling reaction between alkyl halides and arylboronic esters was developed that does not involve activation of the boronic ester with... 
ORGANOBORON COMPOUNDS | ARYL GRIGNARD-REAGENTS | CINACALCET HYDROCHLORIDE | PALLADIUM | 1-ALKENYLBORANES | KUMADA | TRANSMETALATION | COMPLEXES | REACTIVITY | CHLORIDES | CHEMISTRY, ORGANIC
Journal Article
Coordination Chemistry Reviews, ISSN 0010-8545, 11/2017, Volume 350, pp. 275 - 284
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 02/2016, Volume 138, Issue 6, pp. 1760 - 1763
Ni-catalyzed cross-couplings of aryl, benzyl, and alkyl thiols with aryl and heteroaryl iodides were accomplished in the presence of an Ir-photoredox catalyst.... 
HALIDES | CONSTANTS | MECHANISM | LIGHT | C-S | STATE | SINGLE-ELECTRON TRANSMETALATION | BOND | CLEAVAGE | EFFICIENT | CHEMISTRY, MULTIDISCIPLINARY | Sulfur compounds | Nickel compounds | Chemical properties | Catalysis | Research
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 06/2012, Volume 51, Issue 25, pp. 6181 - 6186
Gold‐tinted: A gold catalyzed cyclization reaction of 1,6‐diyne‐4‐en‐3‐ols, incorporating an in situ stannyl transfer reaction involving... 
gold | stannanes | domino reactions | alkynes | transmetalation | PALLADIUM | ACTIVATION | CARBON CHAINS | RHODIUM TRANSMETALATION | ISOMERIZATION | COMPLEXES | ORGANOGOLD COMPOUNDS | CHEMISTRY, MULTIDISCIPLINARY | CROSS-COUPLING REACTIONS | C-C | EFFICIENT | Tin | Gold | Furans | Crystallography | X-rays
Journal Article
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, ISSN 1433-7851, 06/2015, Volume 54, Issue 27, pp. 7929 - 7933
The direct decarboxylative arylation of -oxo acids has been achieved by synergistic visible-light-mediated photoredox and nickel catalysis. This method offers... 
decarboxylation | HOMOLYTIC ACYLATION | LIGHT | ALPHA-AMINO-ACIDS | SINGLE-ELECTRON TRANSMETALATION | CHEMISTRY, MULTIDISCIPLINARY | arylation | nickel catalysis | oxo acids | CROSS-COUPLING REACTIONS | C-H ARYLATION | CHEMISTRY | photoredox catalysis | CARBOXYLIC-ACIDS | Nickel | Catalysis | Architecture | Ketones | Acids
Journal Article
Nature Chemistry, ISSN 1755-4330, 02/2016, Volume 8, Issue 3, pp. 209 - 219
Exploiting the reactivity of one functional group within a molecule to generate a reaction at a different position is an ongoing challenge in organic... 
CATALYZED HYDROBORATION | CHAIN-WALKING | ALLYLIC ALCOHOLS | INTERNAL ALKENES | HECK ARYLATIONS | UNSATURATED ALCOHOLS | BIFUNCTIONAL CATALYST | C-H ACTIVATION | NONCONJUGATED DIENES | CHEMISTRY, MULTIDISCIPLINARY | TRANSMETALATION REACTIONS | Organic chemistry | Inorganic chemistry | Chemical Sciences
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 12/2011, Volume 133, Issue 51, pp. 20738 - 20741
The stereochemical course of the stereospecific Suzuki–Miyaura coupling of enantioenriched α-(acetylamino)benzylboronic esters with aryl bromides can be... 
HALIDES | PALLADIUM | CROSS-COUPLINGS | REAGENTS | TRANSITION-METAL-COMPLEXES | TRANSMETALATION | ALPHA-(ACYLAMINO)BENZYLBORONIC ESTERS | ALKYLBORANES | ARYL | CHEMISTRY, MULTIDISCIPLINARY | STEREOCONTROLLED SYNTHESIS
Journal Article
Chemical Science, ISSN 2041-6520, 2016, Volume 8, Issue 1, pp. 530 - 535
The attractive field of iterative cross-coupling has seen numerous advances, although almost exclusively in the union of sp(2)-hybridized partners.... 
SILICATES | MERGING PHOTOREDOX | NICKEL CATALYSIS | ACIDS | STRATEGY | ARYLATION | SINGLE-ELECTRON TRANSMETALATION | EFFICIENT | TECHNOLOGY | CHEMISTRY, MULTIDISCIPLINARY
Journal Article