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Organic Letters, ISSN 1523-7060, 08/2016, Volume 18, Issue 16, pp. 4012 - 4015
Reductive cross-coupling has emerged as a direct method for the construction of carbon–carbon bonds. Most cobalt-, nickel-, and palladium-catalyzed reductive... 
VISIBLE-LIGHT | ROOM-TEMPERATURE | UNACTIVATED ALKYL | MERGING PHOTOREDOX | ALLYLIC ACETATES | DECARBOXYLATIVE ARYLATION | LIGHT PHOTOREDOX CATALYSIS | CHEMISTRY, ORGANIC | C-H FUNCTIONALIZATION | SINGLE-ELECTRON TRANSMETALATION | DUAL-CATALYSIS
Journal Article
CHEMICAL SCIENCE, ISSN 2041-6520, 09/2019, Volume 10, Issue 33, pp. 7728 - 7733
A divergent strategy for the remote arylation, vinylation and alkylation of nitriles is described. These processes proceed through the photoredox generation of... 
CATALYSIS | ACTIVATION | ACYL OXIMES | GENERATION | SINGLE-ELECTRON TRANSMETALATION | CLEAVAGE | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Organic Letters, ISSN 1523-7060, 07/2017, Volume 19, Issue 14, pp. 3735 - 3738
A phosphorylation of alkenyl and aryl C–O bonds at room temperature via photoredox/nickel dual catalysis is reported. By starting from easily available and... 
H FUNCTIONALIZATION | CROSS-COUPLING REACTIONS | ACTIVATION | NICKEL CATALYSIS | VISIBLE-LIGHT PHOTOREDOX | CHEMISTRY, ORGANIC | SINGLE-ELECTRON TRANSMETALATION | PHOSPHINE OXIDES | FORMING REACTIONS | METAL-FREE | PHENOL DERIVATIVES
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 10/2014, Volume 136, Issue 40, pp. 14027 - 14030
We report the development of a Pd-catalyzed process for the stereospecific cross-coupling of unactivated secondary alkylboron nucleophiles and aryl chlorides.... 
HALIDES | ASYMMETRIC-SYNTHESIS | CONVENIENT PROCEDURE | C-N | TRANSMETALATION | AMINOSTANNANES | STEREOCHEMICAL COURSE | BORONIC ESTERS | INVERSION | SALTS | CHEMISTRY, MULTIDISCIPLINARY | Aromatic compounds | Chlorides | Isomerization | Optical activity | Chemical reactions | Alkylboron | Palladium | Nucleophiles | Communication
Journal Article
Organic Process Research & Development, ISSN 1083-6160, 04/2018, Volume 22, Issue 4, pp. 542 - 550
Photoredox decarboxylative cross-coupling via iridium–nickel dual catalysis has emerged as a valuable method for C­(sp2)–C­(sp3) bond formation. Herein we... 
PLATFORM | MERGING PHOTOREDOX | ACIDS | LIGHT | CHEMISTRY | CHEMISTRY, ORGANIC | PHOTOCHEMISTRY | GENERATION | OPTIMIZATION | SCALE | CHEMISTRY, APPLIED | SINGLE-ELECTRON TRANSMETALATION
Journal Article
Radiology, ISSN 0033-8419, 08/2018, Volume 288, Issue 2, pp. 424 - 433
Purpose: To compare the long-term brain elimination kinetics and gadolinium species in healthy rats after repeated injections of the contrast agents... 
CONTRAST AGENTS | PRODUCTS | TRANSMETALATION | SPECIATION | STABILITY | IRON | MACROCYCLIC-AGENTS | HEALTHY RATS | RADIOLOGY, NUCLEAR MEDICINE & MEDICAL IMAGING | DEEP CEREBELLAR NUCLEI | NEPHROGENIC SYSTEMIC FIBROSIS
Journal Article
Dalton transactions (Cambridge, England : 2003), ISSN 1477-9226, 01/2017, Volume 46, Issue 3, pp. 628 - 631
This report presents the recent advances in the use of copper(i)-NHC (NHC = N-heterocyclic carbene) complexes as transmetallating agents enabling the transfer... 
Journal Article
Accounts of Chemical Research, ISSN 0001-4842, 10/2017, Volume 50, Issue 10, pp. 2598 - 2609
Conspectus Organoboron compounds and heterocycles are powerful building blocks and precursors for organic synthesis, including for drug discovery and... 
FUNCTIONALIZATION | PALLADIUM-CATALYZED BORYLATION | GOLD | PALLADIUM-CATALYZED THIOBORATION | TRANSMETALATION | B(C6F5) | ESTERS | TERMINAL ALKYNES | SIGMA-BONDS | CHEMISTRY, MULTIDISCIPLINARY | CYCLIZATION
Journal Article
Organic Letters, ISSN 1523-7060, 10/2016, Volume 18, Issue 20, pp. 5376 - 5379
In this study we developed a method for the pyridine-directed, rhodium-catalyzed, site-selective C–H alkylation and arylation of pyridones using commercially... 
FUNCTIONALIZATION | CATALYSIS | ARYL BORONIC ACIDS | ARYLBORON REAGENTS | HETEROCYCLES | 2-PYRIDONES | C3-SELECTIVE DIRECT ALKYLATION | CHEMISTRY, ORGANIC | BOND ACTIVATION | SINGLE-ELECTRON TRANSMETALATION | DERIVATIVES
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 10/2016, Volume 138, Issue 39, pp. 12715 - 12718
Journal Article
Nature Communications, ISSN 2041-1723, 09/2016, Volume 7, Issue 1, p. 12937
Cross-coupling is a fundamental reaction in the synthesis of functional molecules, and has been widely applied, for example, to phenols, anilines, alcohols,... 
CROSS-COUPLINGS | MOLECULAR-ORBITAL METHODS | EFFECTIVE CORE POTENTIALS | ARYL MESYLATES | MULTIDISCIPLINARY SCIENCES | CARBON-NITROGEN BOND | DENSITY-FUNCTIONAL THEORY | AMMONIUM-SALTS | ORGANOTIN COMPOUNDS | GRIGNARD-REAGENTS | TRANSMETALATION STEP
Journal Article
Nature Communications, ISSN 2041-1723, 04/2016, Volume 7, Issue 1, p. 11065
The Suzuki-Miyaura cross-coupling is one of the most often utilized reactions in the synthesis of pharmaceutical compounds and conjugated materials. In its... 
ALKENES | ENANTIOSELECTIVE SYNTHESIS | RETENTION | STRATEGY | MULTIDISCIPLINARY SCIENCES | ESTERS | SECONDARY | SINGLE-ELECTRON TRANSMETALATION | INVERSION | DIBORATION | BORYLATION
Journal Article
ChemCatChem, ISSN 1867-3880, 07/2016, Volume 8, Issue 14, pp. 2421 - 2421
The Cover shows a favorable interaction between a Lewis acidic boron atom and a chlorine atom on a palladium complex for boryl transfer. In their... 
palladium | noncovalent interactions | boron | borylation | transmetalation
Journal Article
Chemical Communications, ISSN 1359-7345, 2016, Volume 52, Issue 66, pp. 10163 - 10166
A dual visible light photoredox and gold-catalysed C(sp(2))-C(sp(2)) cross coupling is described. The success of this mild, oxidant-and base-free cross... 
BORONIC ACIDS | CATALYSIS | ALKENES | TRANSMETALATION | VISIBLE-LIGHT PHOTOREDOX | COMPLEXES | REACTIVITY | OXIDATIVE ADDITION | SALTS | CHEMISTRY, MULTIDISCIPLINARY | HIGHLY EFFICIENT | Gold | Cross coupling | Oxidation | Pathways | Catalysts | Cationic
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 07/2017, Volume 139, Issue 29, pp. 9847 - 9850
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 07/2014, Volume 136, Issue 26, pp. 9491 - 9498
Different anionic templates act to give rise to four distinct CdII-based architectures: a Cd2L3 helicate, a Cd8L12 distorted cuboid, a Cd10L15 pentagonal... 
TRANSITION | COORDINATION CAGE | RECOGNITION | TRANSMETALATION | CAPSULE | RECEPTORS | BINDING | METALLACYCLES | CHEMISTRY, MULTIDISCIPLINARY | DYNAMIC INTERCONVERSION | TRANSFORMATIONS | Ion exchange | Analysis
Journal Article